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Poly[μ-aqua-aqua(μ-benzene-1,2,4,5-tetracarboxylato)gadolinate(III)potassium(I)]
In the title compound, [KGd(C(10)H(2)O(8))(H(2)O)(2)](n), the Gd(3+) ion is nine-coordinated by eight O atoms from five individual benzene-1,2,4,5-tetracarboxylate (btec) ligands and one water molecule, and the K(+) ion is eight-coordinated by six O atoms from five individual btec ligands and two...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120476/ https://www.ncbi.nlm.nih.gov/pubmed/21754630 http://dx.doi.org/10.1107/S1600536811016254 |
Sumario: | In the title compound, [KGd(C(10)H(2)O(8))(H(2)O)(2)](n), the Gd(3+) ion is nine-coordinated by eight O atoms from five individual benzene-1,2,4,5-tetracarboxylate (btec) ligands and one water molecule, and the K(+) ion is eight-coordinated by six O atoms from five individual btec ligands and two water molecules. In the crystal, the btec half-molecules are completed by crystallographic inversion symmetry. GdO(9) and KO(8) polyhedra are connected, forming layers in the ab plane, which are further interconnected by μ(8)- or μ(12)-bridging btec ligands, forming a three-dimensional structure. |
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