Cargando…

Poly[μ-aqua-aqua­(μ-benzene-1,2,4,5-tetra­carboxyl­ato)gadolinate(III)potassium(I)]

In the title compound, [KGd(C(10)H(2)O(8))(H(2)O)(2)](n), the Gd(3+) ion is nine-coordinated by eight O atoms from five individual benzene-1,2,4,5-tetra­carboxyl­ate (btec) ligands and one water mol­ecule, and the K(+) ion is eight-coordinated by six O atoms from five individual btec ligands and two...

Descripción completa

Detalles Bibliográficos
Autores principales: Gong, Xue Yun, Zhang, Lei
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120476/
https://www.ncbi.nlm.nih.gov/pubmed/21754630
http://dx.doi.org/10.1107/S1600536811016254
_version_ 1782206687931793408
author Gong, Xue Yun
Zhang, Lei
author_facet Gong, Xue Yun
Zhang, Lei
author_sort Gong, Xue Yun
collection PubMed
description In the title compound, [KGd(C(10)H(2)O(8))(H(2)O)(2)](n), the Gd(3+) ion is nine-coordinated by eight O atoms from five individual benzene-1,2,4,5-tetra­carboxyl­ate (btec) ligands and one water mol­ecule, and the K(+) ion is eight-coordinated by six O atoms from five individual btec ligands and two water mol­ecules. In the crystal, the btec half-mol­ecules are completed by crystallographic inversion symmetry. GdO(9) and KO(8) polyhedra are connected, forming layers in the ab plane, which are further inter­connected by μ(8)- or μ(12)-bridging btec ligands, forming a three-dimensional structure.
format Online
Article
Text
id pubmed-3120476
institution National Center for Biotechnology Information
language English
publishDate 2011
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-31204762011-07-13 Poly[μ-aqua-aqua­(μ-benzene-1,2,4,5-tetra­carboxyl­ato)gadolinate(III)potassium(I)] Gong, Xue Yun Zhang, Lei Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [KGd(C(10)H(2)O(8))(H(2)O)(2)](n), the Gd(3+) ion is nine-coordinated by eight O atoms from five individual benzene-1,2,4,5-tetra­carboxyl­ate (btec) ligands and one water mol­ecule, and the K(+) ion is eight-coordinated by six O atoms from five individual btec ligands and two water mol­ecules. In the crystal, the btec half-mol­ecules are completed by crystallographic inversion symmetry. GdO(9) and KO(8) polyhedra are connected, forming layers in the ab plane, which are further inter­connected by μ(8)- or μ(12)-bridging btec ligands, forming a three-dimensional structure. International Union of Crystallography 2011-05-11 /pmc/articles/PMC3120476/ /pubmed/21754630 http://dx.doi.org/10.1107/S1600536811016254 Text en © Gong and Zhang 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Gong, Xue Yun
Zhang, Lei
Poly[μ-aqua-aqua­(μ-benzene-1,2,4,5-tetra­carboxyl­ato)gadolinate(III)potassium(I)]
title Poly[μ-aqua-aqua­(μ-benzene-1,2,4,5-tetra­carboxyl­ato)gadolinate(III)potassium(I)]
title_full Poly[μ-aqua-aqua­(μ-benzene-1,2,4,5-tetra­carboxyl­ato)gadolinate(III)potassium(I)]
title_fullStr Poly[μ-aqua-aqua­(μ-benzene-1,2,4,5-tetra­carboxyl­ato)gadolinate(III)potassium(I)]
title_full_unstemmed Poly[μ-aqua-aqua­(μ-benzene-1,2,4,5-tetra­carboxyl­ato)gadolinate(III)potassium(I)]
title_short Poly[μ-aqua-aqua­(μ-benzene-1,2,4,5-tetra­carboxyl­ato)gadolinate(III)potassium(I)]
title_sort poly[μ-aqua-aqua­(μ-benzene-1,2,4,5-tetra­carboxyl­ato)gadolinate(iii)potassium(i)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120476/
https://www.ncbi.nlm.nih.gov/pubmed/21754630
http://dx.doi.org/10.1107/S1600536811016254
work_keys_str_mv AT gongxueyun polymaquaaquambenzene1245tetracarboxylatogadolinateiiipotassiumi
AT zhanglei polymaquaaquambenzene1245tetracarboxylatogadolinateiiipotassiumi