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Poly[μ-aqua-aqua(μ-benzene-1,2,4,5-tetracarboxylato)gadolinate(III)potassium(I)]
In the title compound, [KGd(C(10)H(2)O(8))(H(2)O)(2)](n), the Gd(3+) ion is nine-coordinated by eight O atoms from five individual benzene-1,2,4,5-tetracarboxylate (btec) ligands and one water molecule, and the K(+) ion is eight-coordinated by six O atoms from five individual btec ligands and two...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120476/ https://www.ncbi.nlm.nih.gov/pubmed/21754630 http://dx.doi.org/10.1107/S1600536811016254 |
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author | Gong, Xue Yun Zhang, Lei |
author_facet | Gong, Xue Yun Zhang, Lei |
author_sort | Gong, Xue Yun |
collection | PubMed |
description | In the title compound, [KGd(C(10)H(2)O(8))(H(2)O)(2)](n), the Gd(3+) ion is nine-coordinated by eight O atoms from five individual benzene-1,2,4,5-tetracarboxylate (btec) ligands and one water molecule, and the K(+) ion is eight-coordinated by six O atoms from five individual btec ligands and two water molecules. In the crystal, the btec half-molecules are completed by crystallographic inversion symmetry. GdO(9) and KO(8) polyhedra are connected, forming layers in the ab plane, which are further interconnected by μ(8)- or μ(12)-bridging btec ligands, forming a three-dimensional structure. |
format | Online Article Text |
id | pubmed-3120476 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-31204762011-07-13 Poly[μ-aqua-aqua(μ-benzene-1,2,4,5-tetracarboxylato)gadolinate(III)potassium(I)] Gong, Xue Yun Zhang, Lei Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [KGd(C(10)H(2)O(8))(H(2)O)(2)](n), the Gd(3+) ion is nine-coordinated by eight O atoms from five individual benzene-1,2,4,5-tetracarboxylate (btec) ligands and one water molecule, and the K(+) ion is eight-coordinated by six O atoms from five individual btec ligands and two water molecules. In the crystal, the btec half-molecules are completed by crystallographic inversion symmetry. GdO(9) and KO(8) polyhedra are connected, forming layers in the ab plane, which are further interconnected by μ(8)- or μ(12)-bridging btec ligands, forming a three-dimensional structure. International Union of Crystallography 2011-05-11 /pmc/articles/PMC3120476/ /pubmed/21754630 http://dx.doi.org/10.1107/S1600536811016254 Text en © Gong and Zhang 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Gong, Xue Yun Zhang, Lei Poly[μ-aqua-aqua(μ-benzene-1,2,4,5-tetracarboxylato)gadolinate(III)potassium(I)] |
title | Poly[μ-aqua-aqua(μ-benzene-1,2,4,5-tetracarboxylato)gadolinate(III)potassium(I)] |
title_full | Poly[μ-aqua-aqua(μ-benzene-1,2,4,5-tetracarboxylato)gadolinate(III)potassium(I)] |
title_fullStr | Poly[μ-aqua-aqua(μ-benzene-1,2,4,5-tetracarboxylato)gadolinate(III)potassium(I)] |
title_full_unstemmed | Poly[μ-aqua-aqua(μ-benzene-1,2,4,5-tetracarboxylato)gadolinate(III)potassium(I)] |
title_short | Poly[μ-aqua-aqua(μ-benzene-1,2,4,5-tetracarboxylato)gadolinate(III)potassium(I)] |
title_sort | poly[μ-aqua-aqua(μ-benzene-1,2,4,5-tetracarboxylato)gadolinate(iii)potassium(i)] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120476/ https://www.ncbi.nlm.nih.gov/pubmed/21754630 http://dx.doi.org/10.1107/S1600536811016254 |
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