1-Benzyl-3,5-bis­(4-methyl­benzyl­idene)-4-oxopiperidin-1-ium chloride acetic acid monosolvate

In the title solvated mol­ecular salt, C(28)H(28)NO(+)·Cl(−)·C(2)H(4)O(2), the central piperidinium ring of the cation adopts an envelope conformation with the N atom displaced by 0.798 (2) Å from the mean plane of the five C atoms. In the crystal, the components are linked by N—H⋯Cl and O—H⋯Cl hydr...

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Detalles Bibliográficos
Autores principales: Sun, Ju-feng, Xing, Juan, Han, Jing-tian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120477/
https://www.ncbi.nlm.nih.gov/pubmed/21754744
http://dx.doi.org/10.1107/S1600536811016138
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author Sun, Ju-feng
Xing, Juan
Han, Jing-tian
author_facet Sun, Ju-feng
Xing, Juan
Han, Jing-tian
author_sort Sun, Ju-feng
collection PubMed
description In the title solvated mol­ecular salt, C(28)H(28)NO(+)·Cl(−)·C(2)H(4)O(2), the central piperidinium ring of the cation adopts an envelope conformation with the N atom displaced by 0.798 (2) Å from the mean plane of the five C atoms. In the crystal, the components are linked by N—H⋯Cl and O—H⋯Cl hydrogen bonds into trimeric assemblies. C—H⋯Cl and C—H⋯π inter­actions further consolidate the packing.
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spelling pubmed-31204772011-07-13 1-Benzyl-3,5-bis­(4-methyl­benzyl­idene)-4-oxopiperidin-1-ium chloride acetic acid monosolvate Sun, Ju-feng Xing, Juan Han, Jing-tian Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title solvated mol­ecular salt, C(28)H(28)NO(+)·Cl(−)·C(2)H(4)O(2), the central piperidinium ring of the cation adopts an envelope conformation with the N atom displaced by 0.798 (2) Å from the mean plane of the five C atoms. In the crystal, the components are linked by N—H⋯Cl and O—H⋯Cl hydrogen bonds into trimeric assemblies. C—H⋯Cl and C—H⋯π inter­actions further consolidate the packing. International Union of Crystallography 2011-05-07 /pmc/articles/PMC3120477/ /pubmed/21754744 http://dx.doi.org/10.1107/S1600536811016138 Text en © Sun et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Sun, Ju-feng
Xing, Juan
Han, Jing-tian
1-Benzyl-3,5-bis­(4-methyl­benzyl­idene)-4-oxopiperidin-1-ium chloride acetic acid monosolvate
title 1-Benzyl-3,5-bis­(4-methyl­benzyl­idene)-4-oxopiperidin-1-ium chloride acetic acid monosolvate
title_full 1-Benzyl-3,5-bis­(4-methyl­benzyl­idene)-4-oxopiperidin-1-ium chloride acetic acid monosolvate
title_fullStr 1-Benzyl-3,5-bis­(4-methyl­benzyl­idene)-4-oxopiperidin-1-ium chloride acetic acid monosolvate
title_full_unstemmed 1-Benzyl-3,5-bis­(4-methyl­benzyl­idene)-4-oxopiperidin-1-ium chloride acetic acid monosolvate
title_short 1-Benzyl-3,5-bis­(4-methyl­benzyl­idene)-4-oxopiperidin-1-ium chloride acetic acid monosolvate
title_sort 1-benzyl-3,5-bis­(4-methyl­benzyl­idene)-4-oxopiperidin-1-ium chloride acetic acid monosolvate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120477/
https://www.ncbi.nlm.nih.gov/pubmed/21754744
http://dx.doi.org/10.1107/S1600536811016138
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AT hanjingtian 1benzyl35bis4methylbenzylidene4oxopiperidin1iumchlorideaceticacidmonosolvate

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