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Bis[4-amino-N-(pyrimidin-2-yl)benzenesulfonamidato]-κ(2) N,N′;κN-aquabis(dimethylformamide-κO)cadmium(II) monohydrate
In the title compound, [Cd(C(10)H(9)N(4)O(2)S)(2)(C(3)H(7)NO)(2)(H(2)O)]·H(2)O, the Cd(II) ion displays a grossly distorted octahedral (or irregular) mer-CdN(3)O(3) coodination polyhdron arising from its coordination by one N,N′-bidentate sulfadiazinate anion, one monodentate sulfadiazinate anion,...
Autor principal: | |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120478/ https://www.ncbi.nlm.nih.gov/pubmed/21754681 http://dx.doi.org/10.1107/S1600536811019635 |
Sumario: | In the title compound, [Cd(C(10)H(9)N(4)O(2)S)(2)(C(3)H(7)NO)(2)(H(2)O)]·H(2)O, the Cd(II) ion displays a grossly distorted octahedral (or irregular) mer-CdN(3)O(3) coodination polyhdron arising from its coordination by one N,N′-bidentate sulfadiazinate anion, one monodentate sulfadiazinate anion, two O-bonded dimethylformamide molecules and one water molecule. A short Cd⋯N contact [2.890 (3) Å] to the monodentate sulfadiazinate ion also occurs. The dihedral angles between the planes of the aromatic rings of the anions are 86.81 (14) and 68.65 (14)°. The crystal structure features intermolecular N—H⋯O, O—H⋯O and O—H⋯N hydrogen bonds. |
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