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Bis[4-amino-N-(pyrimidin-2-yl)benzene­sulfonamidato]-κ(2) N,N′;κN-aqua­bis­(dimethyl­formamide-κO)cadmium(II) monohydrate

In the title compound, [Cd(C(10)H(9)N(4)O(2)S)(2)(C(3)H(7)NO)(2)(H(2)O)]·H(2)O, the Cd(II) ion displays a grossly distorted octa­hedral (or irregular) mer-CdN(3)O(3) coodination polyhdron arising from its coordination by one N,N′-bidentate sulfadiazinate anion, one monodentate sulfadiazinate anion,...

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Detalles Bibliográficos
Autor principal: Hossain, G. M. Golzar
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120478/
https://www.ncbi.nlm.nih.gov/pubmed/21754681
http://dx.doi.org/10.1107/S1600536811019635
Descripción
Sumario:In the title compound, [Cd(C(10)H(9)N(4)O(2)S)(2)(C(3)H(7)NO)(2)(H(2)O)]·H(2)O, the Cd(II) ion displays a grossly distorted octa­hedral (or irregular) mer-CdN(3)O(3) coodination polyhdron arising from its coordination by one N,N′-bidentate sulfadiazinate anion, one monodentate sulfadiazinate anion, two O-bonded dimethyl­formamide molecules and one water mol­ecule. A short Cd⋯N contact [2.890 (3) Å] to the monodentate sulfadiazinate ion also occurs. The dihedral angles between the planes of the aromatic rings of the anions are 86.81 (14) and 68.65 (14)°. The crystal structure features inter­molecular N—H⋯O, O—H⋯O and O—H⋯N hydrogen bonds.