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Bis[4-amino-N-(pyrimidin-2-yl)benzenesulfonamidato]-κ(2) N,N′;κN-aquabis(dimethylformamide-κO)cadmium(II) monohydrate
In the title compound, [Cd(C(10)H(9)N(4)O(2)S)(2)(C(3)H(7)NO)(2)(H(2)O)]·H(2)O, the Cd(II) ion displays a grossly distorted octahedral (or irregular) mer-CdN(3)O(3) coodination polyhdron arising from its coordination by one N,N′-bidentate sulfadiazinate anion, one monodentate sulfadiazinate anion,...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
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International Union of Crystallography
2011
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120478/ https://www.ncbi.nlm.nih.gov/pubmed/21754681 http://dx.doi.org/10.1107/S1600536811019635 |
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author | Hossain, G. M. Golzar |
author_facet | Hossain, G. M. Golzar |
author_sort | Hossain, G. M. Golzar |
collection | PubMed |
description | In the title compound, [Cd(C(10)H(9)N(4)O(2)S)(2)(C(3)H(7)NO)(2)(H(2)O)]·H(2)O, the Cd(II) ion displays a grossly distorted octahedral (or irregular) mer-CdN(3)O(3) coodination polyhdron arising from its coordination by one N,N′-bidentate sulfadiazinate anion, one monodentate sulfadiazinate anion, two O-bonded dimethylformamide molecules and one water molecule. A short Cd⋯N contact [2.890 (3) Å] to the monodentate sulfadiazinate ion also occurs. The dihedral angles between the planes of the aromatic rings of the anions are 86.81 (14) and 68.65 (14)°. The crystal structure features intermolecular N—H⋯O, O—H⋯O and O—H⋯N hydrogen bonds. |
format | Online Article Text |
id | pubmed-3120478 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-31204782011-07-13 Bis[4-amino-N-(pyrimidin-2-yl)benzenesulfonamidato]-κ(2) N,N′;κN-aquabis(dimethylformamide-κO)cadmium(II) monohydrate Hossain, G. M. Golzar Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cd(C(10)H(9)N(4)O(2)S)(2)(C(3)H(7)NO)(2)(H(2)O)]·H(2)O, the Cd(II) ion displays a grossly distorted octahedral (or irregular) mer-CdN(3)O(3) coodination polyhdron arising from its coordination by one N,N′-bidentate sulfadiazinate anion, one monodentate sulfadiazinate anion, two O-bonded dimethylformamide molecules and one water molecule. A short Cd⋯N contact [2.890 (3) Å] to the monodentate sulfadiazinate ion also occurs. The dihedral angles between the planes of the aromatic rings of the anions are 86.81 (14) and 68.65 (14)°. The crystal structure features intermolecular N—H⋯O, O—H⋯O and O—H⋯N hydrogen bonds. International Union of Crystallography 2011-05-28 /pmc/articles/PMC3120478/ /pubmed/21754681 http://dx.doi.org/10.1107/S1600536811019635 Text en © G. M. Golzar Hossain 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Hossain, G. M. Golzar Bis[4-amino-N-(pyrimidin-2-yl)benzenesulfonamidato]-κ(2) N,N′;κN-aquabis(dimethylformamide-κO)cadmium(II) monohydrate |
title | Bis[4-amino-N-(pyrimidin-2-yl)benzenesulfonamidato]-κ(2)
N,N′;κN-aquabis(dimethylformamide-κO)cadmium(II) monohydrate |
title_full | Bis[4-amino-N-(pyrimidin-2-yl)benzenesulfonamidato]-κ(2)
N,N′;κN-aquabis(dimethylformamide-κO)cadmium(II) monohydrate |
title_fullStr | Bis[4-amino-N-(pyrimidin-2-yl)benzenesulfonamidato]-κ(2)
N,N′;κN-aquabis(dimethylformamide-κO)cadmium(II) monohydrate |
title_full_unstemmed | Bis[4-amino-N-(pyrimidin-2-yl)benzenesulfonamidato]-κ(2)
N,N′;κN-aquabis(dimethylformamide-κO)cadmium(II) monohydrate |
title_short | Bis[4-amino-N-(pyrimidin-2-yl)benzenesulfonamidato]-κ(2)
N,N′;κN-aquabis(dimethylformamide-κO)cadmium(II) monohydrate |
title_sort | bis[4-amino-n-(pyrimidin-2-yl)benzenesulfonamidato]-κ(2)
n,n′;κn-aquabis(dimethylformamide-κo)cadmium(ii) monohydrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120478/ https://www.ncbi.nlm.nih.gov/pubmed/21754681 http://dx.doi.org/10.1107/S1600536811019635 |
work_keys_str_mv | AT hossaingmgolzar bis4aminonpyrimidin2ylbenzenesulfonamidatok2nnknaquabisdimethylformamidekocadmiumiimonohydrate |