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Bis[4-amino-N-(pyrimidin-2-yl)benzene­sulfonamidato]-κ(2) N,N′;κN-aqua­bis­(dimethyl­formamide-κO)cadmium(II) monohydrate

In the title compound, [Cd(C(10)H(9)N(4)O(2)S)(2)(C(3)H(7)NO)(2)(H(2)O)]·H(2)O, the Cd(II) ion displays a grossly distorted octa­hedral (or irregular) mer-CdN(3)O(3) coodination polyhdron arising from its coordination by one N,N′-bidentate sulfadiazinate anion, one monodentate sulfadiazinate anion,...

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Autor principal: Hossain, G. M. Golzar
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120478/
https://www.ncbi.nlm.nih.gov/pubmed/21754681
http://dx.doi.org/10.1107/S1600536811019635
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author Hossain, G. M. Golzar
author_facet Hossain, G. M. Golzar
author_sort Hossain, G. M. Golzar
collection PubMed
description In the title compound, [Cd(C(10)H(9)N(4)O(2)S)(2)(C(3)H(7)NO)(2)(H(2)O)]·H(2)O, the Cd(II) ion displays a grossly distorted octa­hedral (or irregular) mer-CdN(3)O(3) coodination polyhdron arising from its coordination by one N,N′-bidentate sulfadiazinate anion, one monodentate sulfadiazinate anion, two O-bonded dimethyl­formamide molecules and one water mol­ecule. A short Cd⋯N contact [2.890 (3) Å] to the monodentate sulfadiazinate ion also occurs. The dihedral angles between the planes of the aromatic rings of the anions are 86.81 (14) and 68.65 (14)°. The crystal structure features inter­molecular N—H⋯O, O—H⋯O and O—H⋯N hydrogen bonds.
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spelling pubmed-31204782011-07-13 Bis[4-amino-N-(pyrimidin-2-yl)benzene­sulfonamidato]-κ(2) N,N′;κN-aqua­bis­(dimethyl­formamide-κO)cadmium(II) monohydrate Hossain, G. M. Golzar Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cd(C(10)H(9)N(4)O(2)S)(2)(C(3)H(7)NO)(2)(H(2)O)]·H(2)O, the Cd(II) ion displays a grossly distorted octa­hedral (or irregular) mer-CdN(3)O(3) coodination polyhdron arising from its coordination by one N,N′-bidentate sulfadiazinate anion, one monodentate sulfadiazinate anion, two O-bonded dimethyl­formamide molecules and one water mol­ecule. A short Cd⋯N contact [2.890 (3) Å] to the monodentate sulfadiazinate ion also occurs. The dihedral angles between the planes of the aromatic rings of the anions are 86.81 (14) and 68.65 (14)°. The crystal structure features inter­molecular N—H⋯O, O—H⋯O and O—H⋯N hydrogen bonds. International Union of Crystallography 2011-05-28 /pmc/articles/PMC3120478/ /pubmed/21754681 http://dx.doi.org/10.1107/S1600536811019635 Text en © G. M. Golzar Hossain 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Hossain, G. M. Golzar
Bis[4-amino-N-(pyrimidin-2-yl)benzene­sulfonamidato]-κ(2) N,N′;κN-aqua­bis­(dimethyl­formamide-κO)cadmium(II) monohydrate
title Bis[4-amino-N-(pyrimidin-2-yl)benzene­sulfonamidato]-κ(2) N,N′;κN-aqua­bis­(dimethyl­formamide-κO)cadmium(II) monohydrate
title_full Bis[4-amino-N-(pyrimidin-2-yl)benzene­sulfonamidato]-κ(2) N,N′;κN-aqua­bis­(dimethyl­formamide-κO)cadmium(II) monohydrate
title_fullStr Bis[4-amino-N-(pyrimidin-2-yl)benzene­sulfonamidato]-κ(2) N,N′;κN-aqua­bis­(dimethyl­formamide-κO)cadmium(II) monohydrate
title_full_unstemmed Bis[4-amino-N-(pyrimidin-2-yl)benzene­sulfonamidato]-κ(2) N,N′;κN-aqua­bis­(dimethyl­formamide-κO)cadmium(II) monohydrate
title_short Bis[4-amino-N-(pyrimidin-2-yl)benzene­sulfonamidato]-κ(2) N,N′;κN-aqua­bis­(dimethyl­formamide-κO)cadmium(II) monohydrate
title_sort bis[4-amino-n-(pyrimidin-2-yl)benzene­sulfonamidato]-κ(2) n,n′;κn-aqua­bis­(dimethyl­formamide-κo)cadmium(ii) monohydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120478/
https://www.ncbi.nlm.nih.gov/pubmed/21754681
http://dx.doi.org/10.1107/S1600536811019635
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