Trichlorido(4-methyl­benz­yl)bis­(1H-pyrazole-κN (2))tin(IV)

The six-coordinate Sn(IV) atom in the title compound, [Sn(C(8)H(9))Cl(3)(C(3)H(4)N(2))(2)], shows an octa­hedral coordination. The N atoms of the N-heterocycle are cis to each other. The Sn—N bond that is trans to the Sn—C bond is shorter than the Sn—N bond trans to the Sn—Cl bond. Weak N—H⋯Cl hydro...

Descripción completa

Detalles Bibliográficos
Autores principales: Keng, Thy Chun, Lo, Kong Mun, Ng, Seik Weng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120481/
https://www.ncbi.nlm.nih.gov/pubmed/21754571
http://dx.doi.org/10.1107/S1600536811015698
_version_ 1782206689039089664
author Keng, Thy Chun
Lo, Kong Mun
Ng, Seik Weng
author_facet Keng, Thy Chun
Lo, Kong Mun
Ng, Seik Weng
author_sort Keng, Thy Chun
collection PubMed
description The six-coordinate Sn(IV) atom in the title compound, [Sn(C(8)H(9))Cl(3)(C(3)H(4)N(2))(2)], shows an octa­hedral coordination. The N atoms of the N-heterocycle are cis to each other. The Sn—N bond that is trans to the Sn—C bond is shorter than the Sn—N bond trans to the Sn—Cl bond. Weak N—H⋯Cl hydrogen bonds link adjacent mol­ecules, generating a double chain running along the c axis.
format Online
Article
Text
id pubmed-3120481
institution National Center for Biotechnology Information
language English
publishDate 2011
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-31204812011-07-13 Trichlorido(4-methyl­benz­yl)bis­(1H-pyrazole-κN (2))tin(IV) Keng, Thy Chun Lo, Kong Mun Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The six-coordinate Sn(IV) atom in the title compound, [Sn(C(8)H(9))Cl(3)(C(3)H(4)N(2))(2)], shows an octa­hedral coordination. The N atoms of the N-heterocycle are cis to each other. The Sn—N bond that is trans to the Sn—C bond is shorter than the Sn—N bond trans to the Sn—Cl bond. Weak N—H⋯Cl hydrogen bonds link adjacent mol­ecules, generating a double chain running along the c axis. International Union of Crystallography 2011-05-07 /pmc/articles/PMC3120481/ /pubmed/21754571 http://dx.doi.org/10.1107/S1600536811015698 Text en © Keng et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Keng, Thy Chun
Lo, Kong Mun
Ng, Seik Weng
Trichlorido(4-methyl­benz­yl)bis­(1H-pyrazole-κN (2))tin(IV)
title Trichlorido(4-methyl­benz­yl)bis­(1H-pyrazole-κN (2))tin(IV)
title_full Trichlorido(4-methyl­benz­yl)bis­(1H-pyrazole-κN (2))tin(IV)
title_fullStr Trichlorido(4-methyl­benz­yl)bis­(1H-pyrazole-κN (2))tin(IV)
title_full_unstemmed Trichlorido(4-methyl­benz­yl)bis­(1H-pyrazole-κN (2))tin(IV)
title_short Trichlorido(4-methyl­benz­yl)bis­(1H-pyrazole-κN (2))tin(IV)
title_sort trichlorido(4-methyl­benz­yl)bis­(1h-pyrazole-κn (2))tin(iv)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120481/
https://www.ncbi.nlm.nih.gov/pubmed/21754571
http://dx.doi.org/10.1107/S1600536811015698
work_keys_str_mv AT kengthychun trichlorido4methylbenzylbis1hpyrazolekn2tiniv
AT lokongmun trichlorido4methylbenzylbis1hpyrazolekn2tiniv
AT ngseikweng trichlorido4methylbenzylbis1hpyrazolekn2tiniv

Ejemplares similares