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5-Fluoro-3-(2-phenyl­hydrazinyl­idene)indolin-2-one

In the title compound, C(14)H(10)FN(3)O, the six- and five-membered rings of the isatin moiety and the six-membered ring of phenyl­hydrazone are nearly planar with r.m.s. deviations of 0.0003, 0.0004 and 0.007 Å, respectively. The dihedral angle between the phenyl ring and the isatin ring system is...

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Detalles Bibliográficos
Autores principales: Wei, Wen-Bin, Tian, Shuo, Shen, Hong, Sun, Jie, Wang, Hai-Bo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120488/
https://www.ncbi.nlm.nih.gov/pubmed/21754700
http://dx.doi.org/10.1107/S1600536811015285
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author Wei, Wen-Bin
Tian, Shuo
Shen, Hong
Sun, Jie
Wang, Hai-Bo
author_facet Wei, Wen-Bin
Tian, Shuo
Shen, Hong
Sun, Jie
Wang, Hai-Bo
author_sort Wei, Wen-Bin
collection PubMed
description In the title compound, C(14)H(10)FN(3)O, the six- and five-membered rings of the isatin moiety and the six-membered ring of phenyl­hydrazone are nearly planar with r.m.s. deviations of 0.0003, 0.0004 and 0.007 Å, respectively. The dihedral angle between the phenyl ring and the isatin ring system is 6.09 (9)°. The mol­ecular structure is stabilized by a strong intra­molecular N—H⋯O hydrogen bond, leading to the formation of a pseudo-six-membered ring, generating an S(6) ring. The crystal structure features inter­molecular N—H⋯O inter­actions.
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spelling pubmed-31204882011-07-13 5-Fluoro-3-(2-phenyl­hydrazinyl­idene)indolin-2-one Wei, Wen-Bin Tian, Shuo Shen, Hong Sun, Jie Wang, Hai-Bo Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(14)H(10)FN(3)O, the six- and five-membered rings of the isatin moiety and the six-membered ring of phenyl­hydrazone are nearly planar with r.m.s. deviations of 0.0003, 0.0004 and 0.007 Å, respectively. The dihedral angle between the phenyl ring and the isatin ring system is 6.09 (9)°. The mol­ecular structure is stabilized by a strong intra­molecular N—H⋯O hydrogen bond, leading to the formation of a pseudo-six-membered ring, generating an S(6) ring. The crystal structure features inter­molecular N—H⋯O inter­actions. International Union of Crystallography 2011-05-07 /pmc/articles/PMC3120488/ /pubmed/21754700 http://dx.doi.org/10.1107/S1600536811015285 Text en © Wei et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Wei, Wen-Bin
Tian, Shuo
Shen, Hong
Sun, Jie
Wang, Hai-Bo
5-Fluoro-3-(2-phenyl­hydrazinyl­idene)indolin-2-one
title 5-Fluoro-3-(2-phenyl­hydrazinyl­idene)indolin-2-one
title_full 5-Fluoro-3-(2-phenyl­hydrazinyl­idene)indolin-2-one
title_fullStr 5-Fluoro-3-(2-phenyl­hydrazinyl­idene)indolin-2-one
title_full_unstemmed 5-Fluoro-3-(2-phenyl­hydrazinyl­idene)indolin-2-one
title_short 5-Fluoro-3-(2-phenyl­hydrazinyl­idene)indolin-2-one
title_sort 5-fluoro-3-(2-phenyl­hydrazinyl­idene)indolin-2-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120488/
https://www.ncbi.nlm.nih.gov/pubmed/21754700
http://dx.doi.org/10.1107/S1600536811015285
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