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5-Fluoro-3-(2-phenylhydrazinylidene)indolin-2-one
In the title compound, C(14)H(10)FN(3)O, the six- and five-membered rings of the isatin moiety and the six-membered ring of phenylhydrazone are nearly planar with r.m.s. deviations of 0.0003, 0.0004 and 0.007 Å, respectively. The dihedral angle between the phenyl ring and the isatin ring system is...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120488/ https://www.ncbi.nlm.nih.gov/pubmed/21754700 http://dx.doi.org/10.1107/S1600536811015285 |
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author | Wei, Wen-Bin Tian, Shuo Shen, Hong Sun, Jie Wang, Hai-Bo |
author_facet | Wei, Wen-Bin Tian, Shuo Shen, Hong Sun, Jie Wang, Hai-Bo |
author_sort | Wei, Wen-Bin |
collection | PubMed |
description | In the title compound, C(14)H(10)FN(3)O, the six- and five-membered rings of the isatin moiety and the six-membered ring of phenylhydrazone are nearly planar with r.m.s. deviations of 0.0003, 0.0004 and 0.007 Å, respectively. The dihedral angle between the phenyl ring and the isatin ring system is 6.09 (9)°. The molecular structure is stabilized by a strong intramolecular N—H⋯O hydrogen bond, leading to the formation of a pseudo-six-membered ring, generating an S(6) ring. The crystal structure features intermolecular N—H⋯O interactions. |
format | Online Article Text |
id | pubmed-3120488 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-31204882011-07-13 5-Fluoro-3-(2-phenylhydrazinylidene)indolin-2-one Wei, Wen-Bin Tian, Shuo Shen, Hong Sun, Jie Wang, Hai-Bo Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(14)H(10)FN(3)O, the six- and five-membered rings of the isatin moiety and the six-membered ring of phenylhydrazone are nearly planar with r.m.s. deviations of 0.0003, 0.0004 and 0.007 Å, respectively. The dihedral angle between the phenyl ring and the isatin ring system is 6.09 (9)°. The molecular structure is stabilized by a strong intramolecular N—H⋯O hydrogen bond, leading to the formation of a pseudo-six-membered ring, generating an S(6) ring. The crystal structure features intermolecular N—H⋯O interactions. International Union of Crystallography 2011-05-07 /pmc/articles/PMC3120488/ /pubmed/21754700 http://dx.doi.org/10.1107/S1600536811015285 Text en © Wei et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Wei, Wen-Bin Tian, Shuo Shen, Hong Sun, Jie Wang, Hai-Bo 5-Fluoro-3-(2-phenylhydrazinylidene)indolin-2-one |
title | 5-Fluoro-3-(2-phenylhydrazinylidene)indolin-2-one |
title_full | 5-Fluoro-3-(2-phenylhydrazinylidene)indolin-2-one |
title_fullStr | 5-Fluoro-3-(2-phenylhydrazinylidene)indolin-2-one |
title_full_unstemmed | 5-Fluoro-3-(2-phenylhydrazinylidene)indolin-2-one |
title_short | 5-Fluoro-3-(2-phenylhydrazinylidene)indolin-2-one |
title_sort | 5-fluoro-3-(2-phenylhydrazinylidene)indolin-2-one |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120488/ https://www.ncbi.nlm.nih.gov/pubmed/21754700 http://dx.doi.org/10.1107/S1600536811015285 |
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