Bis[N,N-bis­(1-allyl-1H-benzimidazol-2-ylmethyl-κN (3))benzyl­amine-κN]cadmium dipicrate

The crystal structure of the title compound, [Cd(C(29)H(29)N(5))(2)](C(6)H(2)N(3)O(7))(2), consists of Cd(II) complex cations and picrate anions. In the complex cation, the Cd(II) ion is chelated by two bis­(1-allyl­benzimidazol-2-ylmeth­yl)benzyl­amine (babb) ligands in a distorted octa­hedral geom...

Descripción completa

Detalles Bibliográficos
Autores principales: Yuan, Jing-Kun, Bai, Ying, Kou, Fan, Jia, Fei, Wu, Hui-Lu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120489/
https://www.ncbi.nlm.nih.gov/pubmed/21754677
http://dx.doi.org/10.1107/S1600536811019180
_version_ 1782206690825863168
author Yuan, Jing-Kun
Bai, Ying
Kou, Fan
Jia, Fei
Wu, Hui-Lu
author_facet Yuan, Jing-Kun
Bai, Ying
Kou, Fan
Jia, Fei
Wu, Hui-Lu
author_sort Yuan, Jing-Kun
collection PubMed
description The crystal structure of the title compound, [Cd(C(29)H(29)N(5))(2)](C(6)H(2)N(3)O(7))(2), consists of Cd(II) complex cations and picrate anions. In the complex cation, the Cd(II) ion is chelated by two bis­(1-allyl­benzimidazol-2-ylmeth­yl)benzyl­amine (babb) ligands in a distorted octa­hedral geometry. Extensive C—H⋯O hydrogen bonding occurs between cations and anions in the crystal structure.
format Online
Article
Text
id pubmed-3120489
institution National Center for Biotechnology Information
language English
publishDate 2011
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-31204892011-07-13 Bis[N,N-bis­(1-allyl-1H-benzimidazol-2-ylmethyl-κN (3))benzyl­amine-κN]cadmium dipicrate Yuan, Jing-Kun Bai, Ying Kou, Fan Jia, Fei Wu, Hui-Lu Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The crystal structure of the title compound, [Cd(C(29)H(29)N(5))(2)](C(6)H(2)N(3)O(7))(2), consists of Cd(II) complex cations and picrate anions. In the complex cation, the Cd(II) ion is chelated by two bis­(1-allyl­benzimidazol-2-ylmeth­yl)benzyl­amine (babb) ligands in a distorted octa­hedral geometry. Extensive C—H⋯O hydrogen bonding occurs between cations and anions in the crystal structure. International Union of Crystallography 2011-05-25 /pmc/articles/PMC3120489/ /pubmed/21754677 http://dx.doi.org/10.1107/S1600536811019180 Text en © Yuan et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Yuan, Jing-Kun
Bai, Ying
Kou, Fan
Jia, Fei
Wu, Hui-Lu
Bis[N,N-bis­(1-allyl-1H-benzimidazol-2-ylmethyl-κN (3))benzyl­amine-κN]cadmium dipicrate
title Bis[N,N-bis­(1-allyl-1H-benzimidazol-2-ylmethyl-κN (3))benzyl­amine-κN]cadmium dipicrate
title_full Bis[N,N-bis­(1-allyl-1H-benzimidazol-2-ylmethyl-κN (3))benzyl­amine-κN]cadmium dipicrate
title_fullStr Bis[N,N-bis­(1-allyl-1H-benzimidazol-2-ylmethyl-κN (3))benzyl­amine-κN]cadmium dipicrate
title_full_unstemmed Bis[N,N-bis­(1-allyl-1H-benzimidazol-2-ylmethyl-κN (3))benzyl­amine-κN]cadmium dipicrate
title_short Bis[N,N-bis­(1-allyl-1H-benzimidazol-2-ylmethyl-κN (3))benzyl­amine-κN]cadmium dipicrate
title_sort bis[n,n-bis­(1-allyl-1h-benzimidazol-2-ylmethyl-κn (3))benzyl­amine-κn]cadmium dipicrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120489/
https://www.ncbi.nlm.nih.gov/pubmed/21754677
http://dx.doi.org/10.1107/S1600536811019180
work_keys_str_mv AT yuanjingkun bisnnbis1allyl1hbenzimidazol2ylmethylkn3benzylaminekncadmiumdipicrate
AT baiying bisnnbis1allyl1hbenzimidazol2ylmethylkn3benzylaminekncadmiumdipicrate
AT koufan bisnnbis1allyl1hbenzimidazol2ylmethylkn3benzylaminekncadmiumdipicrate
AT jiafei bisnnbis1allyl1hbenzimidazol2ylmethylkn3benzylaminekncadmiumdipicrate
AT wuhuilu bisnnbis1allyl1hbenzimidazol2ylmethylkn3benzylaminekncadmiumdipicrate

Ejemplares similares