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4-{2-[2-(4-Formyl­phen­oxy)eth­oxy]eth­oxy}benzaldehyde

The title compound, C(18)H(18)O(5), was obtained by the reaction of 4-hy­droxy­benzaldehyde with bis­(2,2-dichloro­eth­yl) ether in dimethyl­formamide. In the crystal, the mol­ecule lies on a twofold rotation axis that passes through the central O atom of the aliphatic chain, thus leading to one hal...

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Detalles Bibliográficos
Autores principales: Ma, Zhen, Cao, Yiqun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120494/
https://www.ncbi.nlm.nih.gov/pubmed/21754870
http://dx.doi.org/10.1107/S1600536811018150
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author Ma, Zhen
Cao, Yiqun
author_facet Ma, Zhen
Cao, Yiqun
author_sort Ma, Zhen
collection PubMed
description The title compound, C(18)H(18)O(5), was obtained by the reaction of 4-hy­droxy­benzaldehyde with bis­(2,2-dichloro­eth­yl) ether in dimethyl­formamide. In the crystal, the mol­ecule lies on a twofold rotation axis that passes through the central O atom of the aliphatic chain, thus leading to one half-mol­ecule being present per asymmetric unit. The carbonyl, aryl and O—CH(2)—CH(2) groups are almost coplanar, with an r.m.s. deviation of 0.030 Å. The aromatic rings are approximately perpendicular to each other, forming a dihedral angle of 78.31 sh;H⋯O hydrogen bonds and C—H⋯π inter­actions help to consolidate the three-dimensional network.
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spelling pubmed-31204942011-07-13 4-{2-[2-(4-Formyl­phen­oxy)eth­oxy]eth­oxy}benzaldehyde Ma, Zhen Cao, Yiqun Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(18)H(18)O(5), was obtained by the reaction of 4-hy­droxy­benzaldehyde with bis­(2,2-dichloro­eth­yl) ether in dimethyl­formamide. In the crystal, the mol­ecule lies on a twofold rotation axis that passes through the central O atom of the aliphatic chain, thus leading to one half-mol­ecule being present per asymmetric unit. The carbonyl, aryl and O—CH(2)—CH(2) groups are almost coplanar, with an r.m.s. deviation of 0.030 Å. The aromatic rings are approximately perpendicular to each other, forming a dihedral angle of 78.31 sh;H⋯O hydrogen bonds and C—H⋯π inter­actions help to consolidate the three-dimensional network. International Union of Crystallography 2011-05-25 /pmc/articles/PMC3120494/ /pubmed/21754870 http://dx.doi.org/10.1107/S1600536811018150 Text en © Ma and Cao 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Ma, Zhen
Cao, Yiqun
4-{2-[2-(4-Formyl­phen­oxy)eth­oxy]eth­oxy}benzaldehyde
title 4-{2-[2-(4-Formyl­phen­oxy)eth­oxy]eth­oxy}benzaldehyde
title_full 4-{2-[2-(4-Formyl­phen­oxy)eth­oxy]eth­oxy}benzaldehyde
title_fullStr 4-{2-[2-(4-Formyl­phen­oxy)eth­oxy]eth­oxy}benzaldehyde
title_full_unstemmed 4-{2-[2-(4-Formyl­phen­oxy)eth­oxy]eth­oxy}benzaldehyde
title_short 4-{2-[2-(4-Formyl­phen­oxy)eth­oxy]eth­oxy}benzaldehyde
title_sort 4-{2-[2-(4-formyl­phen­oxy)eth­oxy]eth­oxy}benzaldehyde
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120494/
https://www.ncbi.nlm.nih.gov/pubmed/21754870
http://dx.doi.org/10.1107/S1600536811018150
work_keys_str_mv AT mazhen 4224formylphenoxyethoxyethoxybenzaldehyde
AT caoyiqun 4224formylphenoxyethoxyethoxybenzaldehyde