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4-{2-[2-(4-Formylphenoxy)ethoxy]ethoxy}benzaldehyde
The title compound, C(18)H(18)O(5), was obtained by the reaction of 4-hydroxybenzaldehyde with bis(2,2-dichloroethyl) ether in dimethylformamide. In the crystal, the molecule lies on a twofold rotation axis that passes through the central O atom of the aliphatic chain, thus leading to one hal...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120494/ https://www.ncbi.nlm.nih.gov/pubmed/21754870 http://dx.doi.org/10.1107/S1600536811018150 |
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author | Ma, Zhen Cao, Yiqun |
author_facet | Ma, Zhen Cao, Yiqun |
author_sort | Ma, Zhen |
collection | PubMed |
description | The title compound, C(18)H(18)O(5), was obtained by the reaction of 4-hydroxybenzaldehyde with bis(2,2-dichloroethyl) ether in dimethylformamide. In the crystal, the molecule lies on a twofold rotation axis that passes through the central O atom of the aliphatic chain, thus leading to one half-molecule being present per asymmetric unit. The carbonyl, aryl and O—CH(2)—CH(2) groups are almost coplanar, with an r.m.s. deviation of 0.030 Å. The aromatic rings are approximately perpendicular to each other, forming a dihedral angle of 78.31 sh;H⋯O hydrogen bonds and C—H⋯π interactions help to consolidate the three-dimensional network. |
format | Online Article Text |
id | pubmed-3120494 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-31204942011-07-13 4-{2-[2-(4-Formylphenoxy)ethoxy]ethoxy}benzaldehyde Ma, Zhen Cao, Yiqun Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(18)H(18)O(5), was obtained by the reaction of 4-hydroxybenzaldehyde with bis(2,2-dichloroethyl) ether in dimethylformamide. In the crystal, the molecule lies on a twofold rotation axis that passes through the central O atom of the aliphatic chain, thus leading to one half-molecule being present per asymmetric unit. The carbonyl, aryl and O—CH(2)—CH(2) groups are almost coplanar, with an r.m.s. deviation of 0.030 Å. The aromatic rings are approximately perpendicular to each other, forming a dihedral angle of 78.31 sh;H⋯O hydrogen bonds and C—H⋯π interactions help to consolidate the three-dimensional network. International Union of Crystallography 2011-05-25 /pmc/articles/PMC3120494/ /pubmed/21754870 http://dx.doi.org/10.1107/S1600536811018150 Text en © Ma and Cao 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Ma, Zhen Cao, Yiqun 4-{2-[2-(4-Formylphenoxy)ethoxy]ethoxy}benzaldehyde |
title | 4-{2-[2-(4-Formylphenoxy)ethoxy]ethoxy}benzaldehyde |
title_full | 4-{2-[2-(4-Formylphenoxy)ethoxy]ethoxy}benzaldehyde |
title_fullStr | 4-{2-[2-(4-Formylphenoxy)ethoxy]ethoxy}benzaldehyde |
title_full_unstemmed | 4-{2-[2-(4-Formylphenoxy)ethoxy]ethoxy}benzaldehyde |
title_short | 4-{2-[2-(4-Formylphenoxy)ethoxy]ethoxy}benzaldehyde |
title_sort | 4-{2-[2-(4-formylphenoxy)ethoxy]ethoxy}benzaldehyde |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120494/ https://www.ncbi.nlm.nih.gov/pubmed/21754870 http://dx.doi.org/10.1107/S1600536811018150 |
work_keys_str_mv | AT mazhen 4224formylphenoxyethoxyethoxybenzaldehyde AT caoyiqun 4224formylphenoxyethoxyethoxybenzaldehyde |