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Tetrakis(μ-4-tert-butylbenzoato)-κ(4) O:O′;κ(3) O,O′:O′;κ(3) O:O,O′-bis[aqua(4-tert-butylbenzoato-κ(2) O,O′)(4-tert-butylbenzoic acid-κO)neodymium(III)]
The reaction of neodymium nitrate and 4-tert-butylbenzoic acid (tBBAH) in aqueous solution yielded the dinuclear title complex, [Nd(2)(C(11)H(13)O(2))(6)(C(11)H(14)O(2))(2)(H(2)O)(2)], which has non-crystallographic C(i) symmetry. The two Nd(III) ions are linked by two bridging and two bridging–che...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120497/ https://www.ncbi.nlm.nih.gov/pubmed/21754578 http://dx.doi.org/10.1107/S1600536811015194 |
Sumario: | The reaction of neodymium nitrate and 4-tert-butylbenzoic acid (tBBAH) in aqueous solution yielded the dinuclear title complex, [Nd(2)(C(11)H(13)O(2))(6)(C(11)H(14)O(2))(2)(H(2)O)(2)], which has non-crystallographic C(i) symmetry. The two Nd(III) ions are linked by two bridging and two bridging–chelating tBBA ligands with an Nd⋯Nd separation of 4.0624 (5) Å. Moreover, each Nd(III) ion is coordinated by one chelating tBBA ion, one monodentate tBBAH ligand and one water molecule. The nine-coordinated Nd(III) ion is in a distorted tricapped trigonal–prismatic environment. The molecules are linked into infinite chains along the c axis by intermolecular O—H⋯O hydrogen bonds. Three of the tert-butyl groups are disordered over two sets of sites with equal occupancies. |
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