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Tetrakis(μ-4-tert-butylbenzoato)-κ(4) O:O′;κ(3) O,O′:O′;κ(3) O:O,O′-bis[aqua(4-tert-butylbenzoato-κ(2) O,O′)(4-tert-butylbenzoic acid-κO)neodymium(III)]
The reaction of neodymium nitrate and 4-tert-butylbenzoic acid (tBBAH) in aqueous solution yielded the dinuclear title complex, [Nd(2)(C(11)H(13)O(2))(6)(C(11)H(14)O(2))(2)(H(2)O)(2)], which has non-crystallographic C(i) symmetry. The two Nd(III) ions are linked by two bridging and two bridging–che...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120497/ https://www.ncbi.nlm.nih.gov/pubmed/21754578 http://dx.doi.org/10.1107/S1600536811015194 |
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author | Yang, Juan Dai, Jun |
author_facet | Yang, Juan Dai, Jun |
author_sort | Yang, Juan |
collection | PubMed |
description | The reaction of neodymium nitrate and 4-tert-butylbenzoic acid (tBBAH) in aqueous solution yielded the dinuclear title complex, [Nd(2)(C(11)H(13)O(2))(6)(C(11)H(14)O(2))(2)(H(2)O)(2)], which has non-crystallographic C(i) symmetry. The two Nd(III) ions are linked by two bridging and two bridging–chelating tBBA ligands with an Nd⋯Nd separation of 4.0624 (5) Å. Moreover, each Nd(III) ion is coordinated by one chelating tBBA ion, one monodentate tBBAH ligand and one water molecule. The nine-coordinated Nd(III) ion is in a distorted tricapped trigonal–prismatic environment. The molecules are linked into infinite chains along the c axis by intermolecular O—H⋯O hydrogen bonds. Three of the tert-butyl groups are disordered over two sets of sites with equal occupancies. |
format | Online Article Text |
id | pubmed-3120497 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-31204972011-07-13 Tetrakis(μ-4-tert-butylbenzoato)-κ(4) O:O′;κ(3) O,O′:O′;κ(3) O:O,O′-bis[aqua(4-tert-butylbenzoato-κ(2) O,O′)(4-tert-butylbenzoic acid-κO)neodymium(III)] Yang, Juan Dai, Jun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The reaction of neodymium nitrate and 4-tert-butylbenzoic acid (tBBAH) in aqueous solution yielded the dinuclear title complex, [Nd(2)(C(11)H(13)O(2))(6)(C(11)H(14)O(2))(2)(H(2)O)(2)], which has non-crystallographic C(i) symmetry. The two Nd(III) ions are linked by two bridging and two bridging–chelating tBBA ligands with an Nd⋯Nd separation of 4.0624 (5) Å. Moreover, each Nd(III) ion is coordinated by one chelating tBBA ion, one monodentate tBBAH ligand and one water molecule. The nine-coordinated Nd(III) ion is in a distorted tricapped trigonal–prismatic environment. The molecules are linked into infinite chains along the c axis by intermolecular O—H⋯O hydrogen bonds. Three of the tert-butyl groups are disordered over two sets of sites with equal occupancies. International Union of Crystallography 2011-05-07 /pmc/articles/PMC3120497/ /pubmed/21754578 http://dx.doi.org/10.1107/S1600536811015194 Text en © Yang and Dai 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Yang, Juan Dai, Jun Tetrakis(μ-4-tert-butylbenzoato)-κ(4) O:O′;κ(3) O,O′:O′;κ(3) O:O,O′-bis[aqua(4-tert-butylbenzoato-κ(2) O,O′)(4-tert-butylbenzoic acid-κO)neodymium(III)] |
title | Tetrakis(μ-4-tert-butylbenzoato)-κ(4)
O:O′;κ(3)
O,O′:O′;κ(3)
O:O,O′-bis[aqua(4-tert-butylbenzoato-κ(2)
O,O′)(4-tert-butylbenzoic acid-κO)neodymium(III)] |
title_full | Tetrakis(μ-4-tert-butylbenzoato)-κ(4)
O:O′;κ(3)
O,O′:O′;κ(3)
O:O,O′-bis[aqua(4-tert-butylbenzoato-κ(2)
O,O′)(4-tert-butylbenzoic acid-κO)neodymium(III)] |
title_fullStr | Tetrakis(μ-4-tert-butylbenzoato)-κ(4)
O:O′;κ(3)
O,O′:O′;κ(3)
O:O,O′-bis[aqua(4-tert-butylbenzoato-κ(2)
O,O′)(4-tert-butylbenzoic acid-κO)neodymium(III)] |
title_full_unstemmed | Tetrakis(μ-4-tert-butylbenzoato)-κ(4)
O:O′;κ(3)
O,O′:O′;κ(3)
O:O,O′-bis[aqua(4-tert-butylbenzoato-κ(2)
O,O′)(4-tert-butylbenzoic acid-κO)neodymium(III)] |
title_short | Tetrakis(μ-4-tert-butylbenzoato)-κ(4)
O:O′;κ(3)
O,O′:O′;κ(3)
O:O,O′-bis[aqua(4-tert-butylbenzoato-κ(2)
O,O′)(4-tert-butylbenzoic acid-κO)neodymium(III)] |
title_sort | tetrakis(μ-4-tert-butylbenzoato)-κ(4)
o:o′;κ(3)
o,o′:o′;κ(3)
o:o,o′-bis[aqua(4-tert-butylbenzoato-κ(2)
o,o′)(4-tert-butylbenzoic acid-κo)neodymium(iii)] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120497/ https://www.ncbi.nlm.nih.gov/pubmed/21754578 http://dx.doi.org/10.1107/S1600536811015194 |
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