Cargando…

Tetra­kis(μ-4-tert-butyl­benzoato)-κ(4) O:O′;κ(3) O,O′:O′;κ(3) O:O,O′-bis­[aqua­(4-tert-butyl­benzoato-κ(2) O,O′)(4-tert-butyl­benzoic acid-κO)neodymium(III)]

The reaction of neodymium nitrate and 4-tert-butyl­benzoic acid (tBBAH) in aqueous solution yielded the dinuclear title complex, [Nd(2)(C(11)H(13)O(2))(6)(C(11)H(14)O(2))(2)(H(2)O)(2)], which has non-crystallographic C(i) symmetry. The two Nd(III) ions are linked by two bridging and two bridging–che...

Descripción completa

Detalles Bibliográficos
Autores principales: Yang, Juan, Dai, Jun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120497/
https://www.ncbi.nlm.nih.gov/pubmed/21754578
http://dx.doi.org/10.1107/S1600536811015194
_version_ 1782206692607393792
author Yang, Juan
Dai, Jun
author_facet Yang, Juan
Dai, Jun
author_sort Yang, Juan
collection PubMed
description The reaction of neodymium nitrate and 4-tert-butyl­benzoic acid (tBBAH) in aqueous solution yielded the dinuclear title complex, [Nd(2)(C(11)H(13)O(2))(6)(C(11)H(14)O(2))(2)(H(2)O)(2)], which has non-crystallographic C(i) symmetry. The two Nd(III) ions are linked by two bridging and two bridging–chelating tBBA ligands with an Nd⋯Nd separation of 4.0624 (5) Å. Moreover, each Nd(III) ion is coordinated by one chelating tBBA ion, one monodentate tBBAH ligand and one water mol­ecule. The nine-coordinated Nd(III) ion is in a distorted tricapped trigonal–prismatic environment. The mol­ecules are linked into infinite chains along the c axis by inter­molecular O—H⋯O hydrogen bonds. Three of the tert-butyl groups are disordered over two sets of sites with equal occupancies.
format Online
Article
Text
id pubmed-3120497
institution National Center for Biotechnology Information
language English
publishDate 2011
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-31204972011-07-13 Tetra­kis(μ-4-tert-butyl­benzoato)-κ(4) O:O′;κ(3) O,O′:O′;κ(3) O:O,O′-bis­[aqua­(4-tert-butyl­benzoato-κ(2) O,O′)(4-tert-butyl­benzoic acid-κO)neodymium(III)] Yang, Juan Dai, Jun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The reaction of neodymium nitrate and 4-tert-butyl­benzoic acid (tBBAH) in aqueous solution yielded the dinuclear title complex, [Nd(2)(C(11)H(13)O(2))(6)(C(11)H(14)O(2))(2)(H(2)O)(2)], which has non-crystallographic C(i) symmetry. The two Nd(III) ions are linked by two bridging and two bridging–chelating tBBA ligands with an Nd⋯Nd separation of 4.0624 (5) Å. Moreover, each Nd(III) ion is coordinated by one chelating tBBA ion, one monodentate tBBAH ligand and one water mol­ecule. The nine-coordinated Nd(III) ion is in a distorted tricapped trigonal–prismatic environment. The mol­ecules are linked into infinite chains along the c axis by inter­molecular O—H⋯O hydrogen bonds. Three of the tert-butyl groups are disordered over two sets of sites with equal occupancies. International Union of Crystallography 2011-05-07 /pmc/articles/PMC3120497/ /pubmed/21754578 http://dx.doi.org/10.1107/S1600536811015194 Text en © Yang and Dai 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Yang, Juan
Dai, Jun
Tetra­kis(μ-4-tert-butyl­benzoato)-κ(4) O:O′;κ(3) O,O′:O′;κ(3) O:O,O′-bis­[aqua­(4-tert-butyl­benzoato-κ(2) O,O′)(4-tert-butyl­benzoic acid-κO)neodymium(III)]
title Tetra­kis(μ-4-tert-butyl­benzoato)-κ(4) O:O′;κ(3) O,O′:O′;κ(3) O:O,O′-bis­[aqua­(4-tert-butyl­benzoato-κ(2) O,O′)(4-tert-butyl­benzoic acid-κO)neodymium(III)]
title_full Tetra­kis(μ-4-tert-butyl­benzoato)-κ(4) O:O′;κ(3) O,O′:O′;κ(3) O:O,O′-bis­[aqua­(4-tert-butyl­benzoato-κ(2) O,O′)(4-tert-butyl­benzoic acid-κO)neodymium(III)]
title_fullStr Tetra­kis(μ-4-tert-butyl­benzoato)-κ(4) O:O′;κ(3) O,O′:O′;κ(3) O:O,O′-bis­[aqua­(4-tert-butyl­benzoato-κ(2) O,O′)(4-tert-butyl­benzoic acid-κO)neodymium(III)]
title_full_unstemmed Tetra­kis(μ-4-tert-butyl­benzoato)-κ(4) O:O′;κ(3) O,O′:O′;κ(3) O:O,O′-bis­[aqua­(4-tert-butyl­benzoato-κ(2) O,O′)(4-tert-butyl­benzoic acid-κO)neodymium(III)]
title_short Tetra­kis(μ-4-tert-butyl­benzoato)-κ(4) O:O′;κ(3) O,O′:O′;κ(3) O:O,O′-bis­[aqua­(4-tert-butyl­benzoato-κ(2) O,O′)(4-tert-butyl­benzoic acid-κO)neodymium(III)]
title_sort tetra­kis(μ-4-tert-butyl­benzoato)-κ(4) o:o′;κ(3) o,o′:o′;κ(3) o:o,o′-bis­[aqua­(4-tert-butyl­benzoato-κ(2) o,o′)(4-tert-butyl­benzoic acid-κo)neodymium(iii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120497/
https://www.ncbi.nlm.nih.gov/pubmed/21754578
http://dx.doi.org/10.1107/S1600536811015194
work_keys_str_mv AT yangjuan tetrakism4tertbutylbenzoatok4ook3oook3ooobisaqua4tertbutylbenzoatok2oo4tertbutylbenzoicacidkoneodymiumiii
AT daijun tetrakism4tertbutylbenzoatok4ook3oook3ooobisaqua4tertbutylbenzoatok2oo4tertbutylbenzoicacidkoneodymiumiii