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Aqua[1-(4-carboxyphenyl)-1H-imidazole-κN (3)](pyridine-2,6-dicarboxylato-κ(3) O (2),N,O (6))copper(II) monohydrate
In the title complex, [Cu(C(7)H(3)NO(4))(C(10)H(8)N(2)O(2))(H(2)O)]·H(2)O, the Cu(II) ion is in a slightly distorted square-pyramidal geometry. Two carboxylate O atoms and one pyridine N atom from a pyridine-2,6-dicarboxylate ligand chelate the Cu(II) ion, forming two stable five-membered metalla...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120502/ https://www.ncbi.nlm.nih.gov/pubmed/21754665 http://dx.doi.org/10.1107/S1600536811015522 |
Sumario: | In the title complex, [Cu(C(7)H(3)NO(4))(C(10)H(8)N(2)O(2))(H(2)O)]·H(2)O, the Cu(II) ion is in a slightly distorted square-pyramidal geometry. Two carboxylate O atoms and one pyridine N atom from a pyridine-2,6-dicarboxylate ligand chelate the Cu(II) ion, forming two stable five-membered metalla rings. One imidazole N atom from a 1-(4-carboxyphenyl)imidazole ligand and one water molecule complete the five-coordination. O—H⋯O hydrogen bonds involving the coordinated water molecules and carboxylate groups link the complex molecules into chain-containing dinuclear macrocycles. O—H⋯O hydrogen bonds involving the uncoordinated water molecules link the chains into a layer extending parallel to (10[Image: see text]). |
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