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Aqua­[1-(4-carb­oxy­phen­yl)-1H-imidazole-κN (3)](pyridine-2,6-dicarboxyl­ato-κ(3) O (2),N,O (6))copper(II) monohydrate

In the title complex, [Cu(C(7)H(3)NO(4))(C(10)H(8)N(2)O(2))(H(2)O)]·H(2)O, the Cu(II) ion is in a slightly distorted square-pyramidal geometry. Two carboxyl­ate O atoms and one pyridine N atom from a pyridine-2,6-dicarboxyl­ate ligand chelate the Cu(II) ion, forming two stable five-membered metalla...

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Detalles Bibliográficos
Autores principales: Kong, Fanzhen, Yu, Zhangyu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120502/
https://www.ncbi.nlm.nih.gov/pubmed/21754665
http://dx.doi.org/10.1107/S1600536811015522
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author Kong, Fanzhen
Yu, Zhangyu
author_facet Kong, Fanzhen
Yu, Zhangyu
author_sort Kong, Fanzhen
collection PubMed
description In the title complex, [Cu(C(7)H(3)NO(4))(C(10)H(8)N(2)O(2))(H(2)O)]·H(2)O, the Cu(II) ion is in a slightly distorted square-pyramidal geometry. Two carboxyl­ate O atoms and one pyridine N atom from a pyridine-2,6-dicarboxyl­ate ligand chelate the Cu(II) ion, forming two stable five-membered metalla rings. One imidazole N atom from a 1-(4-carb­oxy­phen­yl)imidazole ligand and one water mol­ecule complete the five-coordination. O—H⋯O hydrogen bonds involving the coordinated water mol­ecules and carboxyl­ate groups link the complex mol­ecules into chain-containing dinuclear macrocycles. O—H⋯O hydrogen bonds involving the uncoordinated water mol­ecules link the chains into a layer extending parallel to (10[Image: see text]).
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spelling pubmed-31205022011-07-13 Aqua­[1-(4-carb­oxy­phen­yl)-1H-imidazole-κN (3)](pyridine-2,6-dicarboxyl­ato-κ(3) O (2),N,O (6))copper(II) monohydrate Kong, Fanzhen Yu, Zhangyu Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Cu(C(7)H(3)NO(4))(C(10)H(8)N(2)O(2))(H(2)O)]·H(2)O, the Cu(II) ion is in a slightly distorted square-pyramidal geometry. Two carboxyl­ate O atoms and one pyridine N atom from a pyridine-2,6-dicarboxyl­ate ligand chelate the Cu(II) ion, forming two stable five-membered metalla rings. One imidazole N atom from a 1-(4-carb­oxy­phen­yl)imidazole ligand and one water mol­ecule complete the five-coordination. O—H⋯O hydrogen bonds involving the coordinated water mol­ecules and carboxyl­ate groups link the complex mol­ecules into chain-containing dinuclear macrocycles. O—H⋯O hydrogen bonds involving the uncoordinated water mol­ecules link the chains into a layer extending parallel to (10[Image: see text]). International Union of Crystallography 2011-05-20 /pmc/articles/PMC3120502/ /pubmed/21754665 http://dx.doi.org/10.1107/S1600536811015522 Text en © Kong and Yu 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Kong, Fanzhen
Yu, Zhangyu
Aqua­[1-(4-carb­oxy­phen­yl)-1H-imidazole-κN (3)](pyridine-2,6-dicarboxyl­ato-κ(3) O (2),N,O (6))copper(II) monohydrate
title Aqua­[1-(4-carb­oxy­phen­yl)-1H-imidazole-κN (3)](pyridine-2,6-dicarboxyl­ato-κ(3) O (2),N,O (6))copper(II) monohydrate
title_full Aqua­[1-(4-carb­oxy­phen­yl)-1H-imidazole-κN (3)](pyridine-2,6-dicarboxyl­ato-κ(3) O (2),N,O (6))copper(II) monohydrate
title_fullStr Aqua­[1-(4-carb­oxy­phen­yl)-1H-imidazole-κN (3)](pyridine-2,6-dicarboxyl­ato-κ(3) O (2),N,O (6))copper(II) monohydrate
title_full_unstemmed Aqua­[1-(4-carb­oxy­phen­yl)-1H-imidazole-κN (3)](pyridine-2,6-dicarboxyl­ato-κ(3) O (2),N,O (6))copper(II) monohydrate
title_short Aqua­[1-(4-carb­oxy­phen­yl)-1H-imidazole-κN (3)](pyridine-2,6-dicarboxyl­ato-κ(3) O (2),N,O (6))copper(II) monohydrate
title_sort aqua­[1-(4-carb­oxy­phen­yl)-1h-imidazole-κn (3)](pyridine-2,6-dicarboxyl­ato-κ(3) o (2),n,o (6))copper(ii) monohydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120502/
https://www.ncbi.nlm.nih.gov/pubmed/21754665
http://dx.doi.org/10.1107/S1600536811015522
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