[η(5)-(Phenyl­ethyn­yl)cyclo­penta­dien­yl](η(4)-tetra­phenyl­cyclo­butadiene)cobalt(I)

In the title compound, [Co(C(13)H(9))(C(28)H(20))], the Co atom is sandwiched between cyclo­penta­dienyl and cyclo­butadienyl rings that are inclined at a dihedral angle of 2.6 (3)°. The four phenyl rings are tilted with respect to the cyclo­butadienyl plane so that the C(4)Ph(4) unit constitutes a...

Descripción completa

Detalles Bibliográficos
Autores principales: Courtney, Donagh, Manning, Anthony R., McAdam, C. John, Simpson, Jim
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120504/
https://www.ncbi.nlm.nih.gov/pubmed/21754635
http://dx.doi.org/10.1107/S1600536811016928
Descripción
Sumario:In the title compound, [Co(C(13)H(9))(C(28)H(20))], the Co atom is sandwiched between cyclo­penta­dienyl and cyclo­butadienyl rings that are inclined at a dihedral angle of 2.6 (3)°. The four phenyl rings are tilted with respect to the cyclo­butadienyl plane so that the C(4)Ph(4) unit constitutes a four-bladed propeller. The phenyl ring of the phenyl-alkyne substituent is inclined to the cyclo­penta­dienyl ring at an angle of 34.92 (18)°. The crystal structure is stabilized solely by C—H⋯π inter­actions which generate a three-dimensional network.

Ejemplares similares