[η(5)-(Phenyl­ethyn­yl)cyclo­penta­dien­yl](η(4)-tetra­phenyl­cyclo­butadiene)cobalt(I)

In the title compound, [Co(C(13)H(9))(C(28)H(20))], the Co atom is sandwiched between cyclo­penta­dienyl and cyclo­butadienyl rings that are inclined at a dihedral angle of 2.6 (3)°. The four phenyl rings are tilted with respect to the cyclo­butadienyl plane so that the C(4)Ph(4) unit constitutes a...

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Detalles Bibliográficos
Autores principales: Courtney, Donagh, Manning, Anthony R., McAdam, C. John, Simpson, Jim
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120504/
https://www.ncbi.nlm.nih.gov/pubmed/21754635
http://dx.doi.org/10.1107/S1600536811016928
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author Courtney, Donagh
Manning, Anthony R.
McAdam, C. John
Simpson, Jim
author_facet Courtney, Donagh
Manning, Anthony R.
McAdam, C. John
Simpson, Jim
author_sort Courtney, Donagh
collection PubMed
description In the title compound, [Co(C(13)H(9))(C(28)H(20))], the Co atom is sandwiched between cyclo­penta­dienyl and cyclo­butadienyl rings that are inclined at a dihedral angle of 2.6 (3)°. The four phenyl rings are tilted with respect to the cyclo­butadienyl plane so that the C(4)Ph(4) unit constitutes a four-bladed propeller. The phenyl ring of the phenyl-alkyne substituent is inclined to the cyclo­penta­dienyl ring at an angle of 34.92 (18)°. The crystal structure is stabilized solely by C—H⋯π inter­actions which generate a three-dimensional network.
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spelling pubmed-31205042011-07-13 [η(5)-(Phenyl­ethyn­yl)cyclo­penta­dien­yl](η(4)-tetra­phenyl­cyclo­butadiene)cobalt(I) Courtney, Donagh Manning, Anthony R. McAdam, C. John Simpson, Jim Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Co(C(13)H(9))(C(28)H(20))], the Co atom is sandwiched between cyclo­penta­dienyl and cyclo­butadienyl rings that are inclined at a dihedral angle of 2.6 (3)°. The four phenyl rings are tilted with respect to the cyclo­butadienyl plane so that the C(4)Ph(4) unit constitutes a four-bladed propeller. The phenyl ring of the phenyl-alkyne substituent is inclined to the cyclo­penta­dienyl ring at an angle of 34.92 (18)°. The crystal structure is stabilized solely by C—H⋯π inter­actions which generate a three-dimensional network. International Union of Crystallography 2011-05-14 /pmc/articles/PMC3120504/ /pubmed/21754635 http://dx.doi.org/10.1107/S1600536811016928 Text en © Courtney et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Courtney, Donagh
Manning, Anthony R.
McAdam, C. John
Simpson, Jim
[η(5)-(Phenyl­ethyn­yl)cyclo­penta­dien­yl](η(4)-tetra­phenyl­cyclo­butadiene)cobalt(I)
title [η(5)-(Phenyl­ethyn­yl)cyclo­penta­dien­yl](η(4)-tetra­phenyl­cyclo­butadiene)cobalt(I)
title_full [η(5)-(Phenyl­ethyn­yl)cyclo­penta­dien­yl](η(4)-tetra­phenyl­cyclo­butadiene)cobalt(I)
title_fullStr [η(5)-(Phenyl­ethyn­yl)cyclo­penta­dien­yl](η(4)-tetra­phenyl­cyclo­butadiene)cobalt(I)
title_full_unstemmed [η(5)-(Phenyl­ethyn­yl)cyclo­penta­dien­yl](η(4)-tetra­phenyl­cyclo­butadiene)cobalt(I)
title_short [η(5)-(Phenyl­ethyn­yl)cyclo­penta­dien­yl](η(4)-tetra­phenyl­cyclo­butadiene)cobalt(I)
title_sort [η(5)-(phenyl­ethyn­yl)cyclo­penta­dien­yl](η(4)-tetra­phenyl­cyclo­butadiene)cobalt(i)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120504/
https://www.ncbi.nlm.nih.gov/pubmed/21754635
http://dx.doi.org/10.1107/S1600536811016928
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