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Aquatrinitrato[2,4,6-tris(pyridin-2-yl)-1,3,5-triazine]neodymium(III) dihydrate
In the title compound, [Nd(NO(3))(3)(C(18)H(12)N(6))(H(2)O)]·2H(2)O, the Nd(3+) ion is in a distorted bicapped square-antiprismatic geometry formed by three N atoms from the 2,4,6-tris(pyridin-2-yl)-1,3,5-triazine (TPTZ) ligand, six O atoms from the three nitrate anions and one O atom from the aqu...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120505/ https://www.ncbi.nlm.nih.gov/pubmed/21754603 http://dx.doi.org/10.1107/S1600536811014589 |
| _version_ | 1782206694386827264 |
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| author | Zhou, Jin Lu, Gan-Xiao Zhang, Yan-Guang Wei, Dan-Yi |
| author_facet | Zhou, Jin Lu, Gan-Xiao Zhang, Yan-Guang Wei, Dan-Yi |
| author_sort | Zhou, Jin |
| collection | PubMed |
| description | In the title compound, [Nd(NO(3))(3)(C(18)H(12)N(6))(H(2)O)]·2H(2)O, the Nd(3+) ion is in a distorted bicapped square-antiprismatic geometry formed by three N atoms from the 2,4,6-tris(pyridin-2-yl)-1,3,5-triazine (TPTZ) ligand, six O atoms from the three nitrate anions and one O atom from the aqua ligand. The molecules are linked by O—H⋯O and O—H⋯N hydrogen bonds. Two types of π–π stacking interactions occur between the TPTZ ligands of adjacent complexes [centroid-to-centroid distances = 3.760 (4) and 3.870 (3) Å]. |
| format | Online Article Text |
| id | pubmed-3120505 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-31205052011-07-13 Aquatrinitrato[2,4,6-tris(pyridin-2-yl)-1,3,5-triazine]neodymium(III) dihydrate Zhou, Jin Lu, Gan-Xiao Zhang, Yan-Guang Wei, Dan-Yi Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Nd(NO(3))(3)(C(18)H(12)N(6))(H(2)O)]·2H(2)O, the Nd(3+) ion is in a distorted bicapped square-antiprismatic geometry formed by three N atoms from the 2,4,6-tris(pyridin-2-yl)-1,3,5-triazine (TPTZ) ligand, six O atoms from the three nitrate anions and one O atom from the aqua ligand. The molecules are linked by O—H⋯O and O—H⋯N hydrogen bonds. Two types of π–π stacking interactions occur between the TPTZ ligands of adjacent complexes [centroid-to-centroid distances = 3.760 (4) and 3.870 (3) Å]. International Union of Crystallography 2011-05-07 /pmc/articles/PMC3120505/ /pubmed/21754603 http://dx.doi.org/10.1107/S1600536811014589 Text en © Zhou et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Zhou, Jin Lu, Gan-Xiao Zhang, Yan-Guang Wei, Dan-Yi Aquatrinitrato[2,4,6-tris(pyridin-2-yl)-1,3,5-triazine]neodymium(III) dihydrate |
| title | Aquatrinitrato[2,4,6-tris(pyridin-2-yl)-1,3,5-triazine]neodymium(III) dihydrate |
| title_full | Aquatrinitrato[2,4,6-tris(pyridin-2-yl)-1,3,5-triazine]neodymium(III) dihydrate |
| title_fullStr | Aquatrinitrato[2,4,6-tris(pyridin-2-yl)-1,3,5-triazine]neodymium(III) dihydrate |
| title_full_unstemmed | Aquatrinitrato[2,4,6-tris(pyridin-2-yl)-1,3,5-triazine]neodymium(III) dihydrate |
| title_short | Aquatrinitrato[2,4,6-tris(pyridin-2-yl)-1,3,5-triazine]neodymium(III) dihydrate |
| title_sort | aquatrinitrato[2,4,6-tris(pyridin-2-yl)-1,3,5-triazine]neodymium(iii) dihydrate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120505/ https://www.ncbi.nlm.nih.gov/pubmed/21754603 http://dx.doi.org/10.1107/S1600536811014589 |
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