Poly[(μ-1H-benzimidazole-5,6-dicarboxyl­ato)lead(II)]

The crystal structure of the two-dimensional polymeric title compound, [Pb(C(9)H(4)N(2)O(4))](n), comprises one crystallo­graphic­ally independent Pb(II) atom and one fully deprotonated 1H-benzimidazole-5,6-dicarboxyl­ate (H(2) L) ligand. The Pb(II) atom is seven-coordinated by six O atoms and one N...

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Detalles Bibliográficos
Autores principales: Chen, Jinhua, Zheng, Chun, Wang, Yuezhu, Yun, Tingting, Luo, Yifan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120506/
https://www.ncbi.nlm.nih.gov/pubmed/21754644
http://dx.doi.org/10.1107/S1600536811017065
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author Chen, Jinhua
Zheng, Chun
Wang, Yuezhu
Yun, Tingting
Luo, Yifan
author_facet Chen, Jinhua
Zheng, Chun
Wang, Yuezhu
Yun, Tingting
Luo, Yifan
author_sort Chen, Jinhua
collection PubMed
description The crystal structure of the two-dimensional polymeric title compound, [Pb(C(9)H(4)N(2)O(4))](n), comprises one crystallo­graphic­ally independent Pb(II) atom and one fully deprotonated 1H-benzimidazole-5,6-dicarboxyl­ate (H(2) L) ligand. The Pb(II) atom is seven-coordinated by six O atoms and one N atom from the H(2) L ligands, giving a capped octa­hedral coordination geometry. The structure is a layered two-dimensional coordination polymer extending parallel to (100) with N—H⋯O hydrogen bonds inter­actions between the layers, stabilizing the crystal structure.
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spelling pubmed-31205062011-07-13 Poly[(μ-1H-benzimidazole-5,6-dicarboxyl­ato)lead(II)] Chen, Jinhua Zheng, Chun Wang, Yuezhu Yun, Tingting Luo, Yifan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The crystal structure of the two-dimensional polymeric title compound, [Pb(C(9)H(4)N(2)O(4))](n), comprises one crystallo­graphic­ally independent Pb(II) atom and one fully deprotonated 1H-benzimidazole-5,6-dicarboxyl­ate (H(2) L) ligand. The Pb(II) atom is seven-coordinated by six O atoms and one N atom from the H(2) L ligands, giving a capped octa­hedral coordination geometry. The structure is a layered two-dimensional coordination polymer extending parallel to (100) with N—H⋯O hydrogen bonds inter­actions between the layers, stabilizing the crystal structure. International Union of Crystallography 2011-05-14 /pmc/articles/PMC3120506/ /pubmed/21754644 http://dx.doi.org/10.1107/S1600536811017065 Text en © Chen et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Chen, Jinhua
Zheng, Chun
Wang, Yuezhu
Yun, Tingting
Luo, Yifan
Poly[(μ-1H-benzimidazole-5,6-dicarboxyl­ato)lead(II)]
title Poly[(μ-1H-benzimidazole-5,6-dicarboxyl­ato)lead(II)]
title_full Poly[(μ-1H-benzimidazole-5,6-dicarboxyl­ato)lead(II)]
title_fullStr Poly[(μ-1H-benzimidazole-5,6-dicarboxyl­ato)lead(II)]
title_full_unstemmed Poly[(μ-1H-benzimidazole-5,6-dicarboxyl­ato)lead(II)]
title_short Poly[(μ-1H-benzimidazole-5,6-dicarboxyl­ato)lead(II)]
title_sort poly[(μ-1h-benzimidazole-5,6-dicarboxyl­ato)lead(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120506/
https://www.ncbi.nlm.nih.gov/pubmed/21754644
http://dx.doi.org/10.1107/S1600536811017065
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