Tetra­kis(1H-benzimidazole-κN (3))(nitrato-κO)copper(II) nitrate

In the title salt, [Cu(NO(3))(C(7)H(6)N(2))(4)]NO(3), one nitrate anion is coordinated to the Cu(II) atom, which is also coordinated by the N atoms of four N-heterocycles. The geometry at the metal atom is a square pyramid in which the O atom of the anion occupies the apical position [Cu—O = 2.468 (...

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Detalles Bibliográficos
Autores principales: Zhou, Fu-Lin, Ng, Seik Weng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120510/
https://www.ncbi.nlm.nih.gov/pubmed/21754671
http://dx.doi.org/10.1107/S1600536811018885
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author Zhou, Fu-Lin
Ng, Seik Weng
author_facet Zhou, Fu-Lin
Ng, Seik Weng
author_sort Zhou, Fu-Lin
collection PubMed
description In the title salt, [Cu(NO(3))(C(7)H(6)N(2))(4)]NO(3), one nitrate anion is coordinated to the Cu(II) atom, which is also coordinated by the N atoms of four N-heterocycles. The geometry at the metal atom is a square pyramid in which the O atom of the anion occupies the apical position [Cu—O = 2.468 (5) and 2.590 (7) Å in the two independent formula units]. The cation lies on a twofold rotation axis; the coordinated nitrate anion is also disordered about this symmetry element. The lattice anion is also disordered about a twofold rotation axis. In the crystal, the cations are linked to the coordinated and free anions by N—H⋯O hydrogen bonds.
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spelling pubmed-31205102011-07-13 Tetra­kis(1H-benzimidazole-κN (3))(nitrato-κO)copper(II) nitrate Zhou, Fu-Lin Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title salt, [Cu(NO(3))(C(7)H(6)N(2))(4)]NO(3), one nitrate anion is coordinated to the Cu(II) atom, which is also coordinated by the N atoms of four N-heterocycles. The geometry at the metal atom is a square pyramid in which the O atom of the anion occupies the apical position [Cu—O = 2.468 (5) and 2.590 (7) Å in the two independent formula units]. The cation lies on a twofold rotation axis; the coordinated nitrate anion is also disordered about this symmetry element. The lattice anion is also disordered about a twofold rotation axis. In the crystal, the cations are linked to the coordinated and free anions by N—H⋯O hydrogen bonds. International Union of Crystallography 2011-05-25 /pmc/articles/PMC3120510/ /pubmed/21754671 http://dx.doi.org/10.1107/S1600536811018885 Text en © Zhou and Ng 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhou, Fu-Lin
Ng, Seik Weng
Tetra­kis(1H-benzimidazole-κN (3))(nitrato-κO)copper(II) nitrate
title Tetra­kis(1H-benzimidazole-κN (3))(nitrato-κO)copper(II) nitrate
title_full Tetra­kis(1H-benzimidazole-κN (3))(nitrato-κO)copper(II) nitrate
title_fullStr Tetra­kis(1H-benzimidazole-κN (3))(nitrato-κO)copper(II) nitrate
title_full_unstemmed Tetra­kis(1H-benzimidazole-κN (3))(nitrato-κO)copper(II) nitrate
title_short Tetra­kis(1H-benzimidazole-κN (3))(nitrato-κO)copper(II) nitrate
title_sort tetra­kis(1h-benzimidazole-κn (3))(nitrato-κo)copper(ii) nitrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120510/
https://www.ncbi.nlm.nih.gov/pubmed/21754671
http://dx.doi.org/10.1107/S1600536811018885
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