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Diaqua(5-carboxybenzene-1,3-dicarboxylato-κO (1))(4,4′-dimethyl-2,2′-bipyridine-κ(2) N,N′)zinc
In the title compound, [Zn(C(9)H(4)O(6))(C(12)H(12)N(2))(H(2)O)(2)], the Zn(II) atom is five-coordinated by two N atoms from a 4,4′-dimethyl-2,2′-bipyridine ligand, one O atom from a 5-carboxybenzene-1,3-dicarboxylate ligand and two water molecules in a distorted trigonal–bipyramidal geometry. T...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120513/ https://www.ncbi.nlm.nih.gov/pubmed/21754680 http://dx.doi.org/10.1107/S1600536811019519 |
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author | Mei, Chong-Zhen Li, Kai-Hui Shan, Wen-Wen |
author_facet | Mei, Chong-Zhen Li, Kai-Hui Shan, Wen-Wen |
author_sort | Mei, Chong-Zhen |
collection | PubMed |
description | In the title compound, [Zn(C(9)H(4)O(6))(C(12)H(12)N(2))(H(2)O)(2)], the Zn(II) atom is five-coordinated by two N atoms from a 4,4′-dimethyl-2,2′-bipyridine ligand, one O atom from a 5-carboxybenzene-1,3-dicarboxylate ligand and two water molecules in a distorted trigonal–bipyramidal geometry. The complex molecules are linked by intermolecular O—H⋯O hydrogen bonds and partly overlapping π–π interactions [centroid–centroid distance = 4.017 (2) Å] into a three-dimensional supramolecular network. |
format | Online Article Text |
id | pubmed-3120513 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-31205132011-07-13 Diaqua(5-carboxybenzene-1,3-dicarboxylato-κO (1))(4,4′-dimethyl-2,2′-bipyridine-κ(2) N,N′)zinc Mei, Chong-Zhen Li, Kai-Hui Shan, Wen-Wen Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Zn(C(9)H(4)O(6))(C(12)H(12)N(2))(H(2)O)(2)], the Zn(II) atom is five-coordinated by two N atoms from a 4,4′-dimethyl-2,2′-bipyridine ligand, one O atom from a 5-carboxybenzene-1,3-dicarboxylate ligand and two water molecules in a distorted trigonal–bipyramidal geometry. The complex molecules are linked by intermolecular O—H⋯O hydrogen bonds and partly overlapping π–π interactions [centroid–centroid distance = 4.017 (2) Å] into a three-dimensional supramolecular network. International Union of Crystallography 2011-05-28 /pmc/articles/PMC3120513/ /pubmed/21754680 http://dx.doi.org/10.1107/S1600536811019519 Text en © Mei et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Mei, Chong-Zhen Li, Kai-Hui Shan, Wen-Wen Diaqua(5-carboxybenzene-1,3-dicarboxylato-κO (1))(4,4′-dimethyl-2,2′-bipyridine-κ(2) N,N′)zinc |
title | Diaqua(5-carboxybenzene-1,3-dicarboxylato-κO
(1))(4,4′-dimethyl-2,2′-bipyridine-κ(2)
N,N′)zinc |
title_full | Diaqua(5-carboxybenzene-1,3-dicarboxylato-κO
(1))(4,4′-dimethyl-2,2′-bipyridine-κ(2)
N,N′)zinc |
title_fullStr | Diaqua(5-carboxybenzene-1,3-dicarboxylato-κO
(1))(4,4′-dimethyl-2,2′-bipyridine-κ(2)
N,N′)zinc |
title_full_unstemmed | Diaqua(5-carboxybenzene-1,3-dicarboxylato-κO
(1))(4,4′-dimethyl-2,2′-bipyridine-κ(2)
N,N′)zinc |
title_short | Diaqua(5-carboxybenzene-1,3-dicarboxylato-κO
(1))(4,4′-dimethyl-2,2′-bipyridine-κ(2)
N,N′)zinc |
title_sort | diaqua(5-carboxybenzene-1,3-dicarboxylato-κo
(1))(4,4′-dimethyl-2,2′-bipyridine-κ(2)
n,n′)zinc |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120513/ https://www.ncbi.nlm.nih.gov/pubmed/21754680 http://dx.doi.org/10.1107/S1600536811019519 |
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