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Diaqua­(5-carb­oxy­benzene-1,3-di­carboxyl­ato-κO (1))(4,4′-dimethyl-2,2′-bipyridine-κ(2) N,N′)zinc

In the title compound, [Zn(C(9)H(4)O(6))(C(12)H(12)N(2))(H(2)O)(2)], the Zn(II) atom is five-coordinated by two N atoms from a 4,4′-dimethyl-2,2′-bipyridine ligand, one O atom from a 5-carb­oxy­benzene-1,3-dicarboxyl­ate ligand and two water mol­ecules in a distorted trigonal–bipyramidal geometry. T...

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Detalles Bibliográficos
Autores principales: Mei, Chong-Zhen, Li, Kai-Hui, Shan, Wen-Wen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120513/
https://www.ncbi.nlm.nih.gov/pubmed/21754680
http://dx.doi.org/10.1107/S1600536811019519
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author Mei, Chong-Zhen
Li, Kai-Hui
Shan, Wen-Wen
author_facet Mei, Chong-Zhen
Li, Kai-Hui
Shan, Wen-Wen
author_sort Mei, Chong-Zhen
collection PubMed
description In the title compound, [Zn(C(9)H(4)O(6))(C(12)H(12)N(2))(H(2)O)(2)], the Zn(II) atom is five-coordinated by two N atoms from a 4,4′-dimethyl-2,2′-bipyridine ligand, one O atom from a 5-carb­oxy­benzene-1,3-dicarboxyl­ate ligand and two water mol­ecules in a distorted trigonal–bipyramidal geometry. The complex mol­ecules are linked by inter­molecular O—H⋯O hydrogen bonds and partly overlapping π–π inter­actions [centroid–centroid distance = 4.017 (2) Å] into a three-dimensional supra­molecular network.
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spelling pubmed-31205132011-07-13 Diaqua­(5-carb­oxy­benzene-1,3-di­carboxyl­ato-κO (1))(4,4′-dimethyl-2,2′-bipyridine-κ(2) N,N′)zinc Mei, Chong-Zhen Li, Kai-Hui Shan, Wen-Wen Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Zn(C(9)H(4)O(6))(C(12)H(12)N(2))(H(2)O)(2)], the Zn(II) atom is five-coordinated by two N atoms from a 4,4′-dimethyl-2,2′-bipyridine ligand, one O atom from a 5-carb­oxy­benzene-1,3-dicarboxyl­ate ligand and two water mol­ecules in a distorted trigonal–bipyramidal geometry. The complex mol­ecules are linked by inter­molecular O—H⋯O hydrogen bonds and partly overlapping π–π inter­actions [centroid–centroid distance = 4.017 (2) Å] into a three-dimensional supra­molecular network. International Union of Crystallography 2011-05-28 /pmc/articles/PMC3120513/ /pubmed/21754680 http://dx.doi.org/10.1107/S1600536811019519 Text en © Mei et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Mei, Chong-Zhen
Li, Kai-Hui
Shan, Wen-Wen
Diaqua­(5-carb­oxy­benzene-1,3-di­carboxyl­ato-κO (1))(4,4′-dimethyl-2,2′-bipyridine-κ(2) N,N′)zinc
title Diaqua­(5-carb­oxy­benzene-1,3-di­carboxyl­ato-κO (1))(4,4′-dimethyl-2,2′-bipyridine-κ(2) N,N′)zinc
title_full Diaqua­(5-carb­oxy­benzene-1,3-di­carboxyl­ato-κO (1))(4,4′-dimethyl-2,2′-bipyridine-κ(2) N,N′)zinc
title_fullStr Diaqua­(5-carb­oxy­benzene-1,3-di­carboxyl­ato-κO (1))(4,4′-dimethyl-2,2′-bipyridine-κ(2) N,N′)zinc
title_full_unstemmed Diaqua­(5-carb­oxy­benzene-1,3-di­carboxyl­ato-κO (1))(4,4′-dimethyl-2,2′-bipyridine-κ(2) N,N′)zinc
title_short Diaqua­(5-carb­oxy­benzene-1,3-di­carboxyl­ato-κO (1))(4,4′-dimethyl-2,2′-bipyridine-κ(2) N,N′)zinc
title_sort diaqua­(5-carb­oxy­benzene-1,3-di­carboxyl­ato-κo (1))(4,4′-dimethyl-2,2′-bipyridine-κ(2) n,n′)zinc
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120513/
https://www.ncbi.nlm.nih.gov/pubmed/21754680
http://dx.doi.org/10.1107/S1600536811019519
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