Ethyl 8-amino-6-bromoimidazo[1,2-a]pyridine-2-carb­oxy­late

There are two independent mol­ecules in the asymmetric unit of the title compound, C(10)H(10)BrN(3)O(2), which are linked by N—H⋯O and C—H⋯O hydrogen bonds. The fused ring systems in both mol­ecules are nearly planar with maximum deviations of 0.001 (3) and 0.029 (3) Å. All non-H atoms of the first...

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Autores principales: Dahmani, Siham, Kandri Rodi, Youssef, Luis, Santiago V., Essassi, El Mokhtar, El Ammari, Lahcen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120515/
https://www.ncbi.nlm.nih.gov/pubmed/21754778
http://dx.doi.org/10.1107/S1600536811017077
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author Dahmani, Siham
Kandri Rodi, Youssef
Luis, Santiago V.
Essassi, El Mokhtar
El Ammari, Lahcen
author_facet Dahmani, Siham
Kandri Rodi, Youssef
Luis, Santiago V.
Essassi, El Mokhtar
El Ammari, Lahcen
author_sort Dahmani, Siham
collection PubMed
description There are two independent mol­ecules in the asymmetric unit of the title compound, C(10)H(10)BrN(3)O(2), which are linked by N—H⋯O and C—H⋯O hydrogen bonds. The fused ring systems in both mol­ecules are nearly planar with maximum deviations of 0.001 (3) and 0.029 (3) Å. All non-H atoms of the first mol­ecule are approximately co-planar whereas in the second mol­ecule, the ethyl group is almost perpendicular to the imidazo[1,2-a]pyridine system, the C—O—C—C torsion angles in the carb­oxy­lic acid ethyl group being −179.8 (4) and 112.1 (5)°, respectively.
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spelling pubmed-31205152011-07-13 Ethyl 8-amino-6-bromoimidazo[1,2-a]pyridine-2-carb­oxy­late Dahmani, Siham Kandri Rodi, Youssef Luis, Santiago V. Essassi, El Mokhtar El Ammari, Lahcen Acta Crystallogr Sect E Struct Rep Online Organic Papers There are two independent mol­ecules in the asymmetric unit of the title compound, C(10)H(10)BrN(3)O(2), which are linked by N—H⋯O and C—H⋯O hydrogen bonds. The fused ring systems in both mol­ecules are nearly planar with maximum deviations of 0.001 (3) and 0.029 (3) Å. All non-H atoms of the first mol­ecule are approximately co-planar whereas in the second mol­ecule, the ethyl group is almost perpendicular to the imidazo[1,2-a]pyridine system, the C—O—C—C torsion angles in the carb­oxy­lic acid ethyl group being −179.8 (4) and 112.1 (5)°, respectively. International Union of Crystallography 2011-05-11 /pmc/articles/PMC3120515/ /pubmed/21754778 http://dx.doi.org/10.1107/S1600536811017077 Text en © Dahmani et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Dahmani, Siham
Kandri Rodi, Youssef
Luis, Santiago V.
Essassi, El Mokhtar
El Ammari, Lahcen
Ethyl 8-amino-6-bromoimidazo[1,2-a]pyridine-2-carb­oxy­late
title Ethyl 8-amino-6-bromoimidazo[1,2-a]pyridine-2-carb­oxy­late
title_full Ethyl 8-amino-6-bromoimidazo[1,2-a]pyridine-2-carb­oxy­late
title_fullStr Ethyl 8-amino-6-bromoimidazo[1,2-a]pyridine-2-carb­oxy­late
title_full_unstemmed Ethyl 8-amino-6-bromoimidazo[1,2-a]pyridine-2-carb­oxy­late
title_short Ethyl 8-amino-6-bromoimidazo[1,2-a]pyridine-2-carb­oxy­late
title_sort ethyl 8-amino-6-bromoimidazo[1,2-a]pyridine-2-carb­oxy­late
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120515/
https://www.ncbi.nlm.nih.gov/pubmed/21754778
http://dx.doi.org/10.1107/S1600536811017077
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AT luissantiagov ethyl8amino6bromoimidazo12apyridine2carboxylate
AT essassielmokhtar ethyl8amino6bromoimidazo12apyridine2carboxylate
AT elammarilahcen ethyl8amino6bromoimidazo12apyridine2carboxylate

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