catena-Poly[[bis­(dimethyl sulfoxide-κO)cerium(III)]tris­(μ(2)-3,5-dinitro­benzoato-κ(2) O:O′)]

The polymeric title compound, [Ce(C(7)H(3)N(2)O(6))(3)(C(2)H(6)OS)(2)](n), exists as a linear chain along [111] as the three dinitro­benzoate anions each engages in bridging adjacent dimethyl sulfoxide (DMSO) coordinated Ce(III) atoms. The metal atoms are surrounded by eight O atoms in a square-anti...

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Detalles Bibliográficos
Autores principales: Zhou, Fu-Lin, Du, Zhi-Hua, Ng, Seik Weng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120519/
https://www.ncbi.nlm.nih.gov/pubmed/21754582
http://dx.doi.org/10.1107/S1600536811015947
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author Zhou, Fu-Lin
Du, Zhi-Hua
Ng, Seik Weng
author_facet Zhou, Fu-Lin
Du, Zhi-Hua
Ng, Seik Weng
author_sort Zhou, Fu-Lin
collection PubMed
description The polymeric title compound, [Ce(C(7)H(3)N(2)O(6))(3)(C(2)H(6)OS)(2)](n), exists as a linear chain along [111] as the three dinitro­benzoate anions each engages in bridging adjacent dimethyl sulfoxide (DMSO) coordinated Ce(III) atoms. The metal atoms are surrounded by eight O atoms in a square-anti­prismatic environment. There are two independent formula units in the asymmetric unit. The S atoms of two of the four DMSO mol­ecules are disordered in a 0.926 (3):0.074 (3) ratio.
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spelling pubmed-31205192011-07-13 catena-Poly[[bis­(dimethyl sulfoxide-κO)cerium(III)]tris­(μ(2)-3,5-dinitro­benzoato-κ(2) O:O′)] Zhou, Fu-Lin Du, Zhi-Hua Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The polymeric title compound, [Ce(C(7)H(3)N(2)O(6))(3)(C(2)H(6)OS)(2)](n), exists as a linear chain along [111] as the three dinitro­benzoate anions each engages in bridging adjacent dimethyl sulfoxide (DMSO) coordinated Ce(III) atoms. The metal atoms are surrounded by eight O atoms in a square-anti­prismatic environment. There are two independent formula units in the asymmetric unit. The S atoms of two of the four DMSO mol­ecules are disordered in a 0.926 (3):0.074 (3) ratio. International Union of Crystallography 2011-05-07 /pmc/articles/PMC3120519/ /pubmed/21754582 http://dx.doi.org/10.1107/S1600536811015947 Text en © Zhou et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhou, Fu-Lin
Du, Zhi-Hua
Ng, Seik Weng
catena-Poly[[bis­(dimethyl sulfoxide-κO)cerium(III)]tris­(μ(2)-3,5-dinitro­benzoato-κ(2) O:O′)]
title catena-Poly[[bis­(dimethyl sulfoxide-κO)cerium(III)]tris­(μ(2)-3,5-dinitro­benzoato-κ(2) O:O′)]
title_full catena-Poly[[bis­(dimethyl sulfoxide-κO)cerium(III)]tris­(μ(2)-3,5-dinitro­benzoato-κ(2) O:O′)]
title_fullStr catena-Poly[[bis­(dimethyl sulfoxide-κO)cerium(III)]tris­(μ(2)-3,5-dinitro­benzoato-κ(2) O:O′)]
title_full_unstemmed catena-Poly[[bis­(dimethyl sulfoxide-κO)cerium(III)]tris­(μ(2)-3,5-dinitro­benzoato-κ(2) O:O′)]
title_short catena-Poly[[bis­(dimethyl sulfoxide-κO)cerium(III)]tris­(μ(2)-3,5-dinitro­benzoato-κ(2) O:O′)]
title_sort catena-poly[[bis­(dimethyl sulfoxide-κo)cerium(iii)]tris­(μ(2)-3,5-dinitro­benzoato-κ(2) o:o′)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120519/
https://www.ncbi.nlm.nih.gov/pubmed/21754582
http://dx.doi.org/10.1107/S1600536811015947
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