3-Nitro­benzene-1,2-diamine

The mol­ecule of the title compound, C(6)H(7)N(3)O(2), a derivative of o-phenyl­enediamine, nearly shows non-crystallographic C (s) symmetry. C—C—C angles span the range 116.25 (11)–122.35 (11)°. In the crystal, inter­molecular N—H⋯O and N—H⋯N hydrogen bonds connect mol­ecules into undulating sheets...

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Detalles Bibliográficos
Autores principales: Betz, Richard, Gerber, Thomas
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120524/
https://www.ncbi.nlm.nih.gov/pubmed/21754753
http://dx.doi.org/10.1107/S1600536811016825
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author Betz, Richard
Gerber, Thomas
author_facet Betz, Richard
Gerber, Thomas
author_sort Betz, Richard
collection PubMed
description The mol­ecule of the title compound, C(6)H(7)N(3)O(2), a derivative of o-phenyl­enediamine, nearly shows non-crystallographic C (s) symmetry. C—C—C angles span the range 116.25 (11)–122.35 (11)°. In the crystal, inter­molecular N—H⋯O and N—H⋯N hydrogen bonds connect mol­ecules into undulating sheets perpendicular to the crystallographic a axis. A weak intra­molecular N—H⋯O hydrogen bond is also observed. No π-stacking is observed in the crystal structure.
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spelling pubmed-31205242011-07-13 3-Nitro­benzene-1,2-diamine Betz, Richard Gerber, Thomas Acta Crystallogr Sect E Struct Rep Online Organic Papers The mol­ecule of the title compound, C(6)H(7)N(3)O(2), a derivative of o-phenyl­enediamine, nearly shows non-crystallographic C (s) symmetry. C—C—C angles span the range 116.25 (11)–122.35 (11)°. In the crystal, inter­molecular N—H⋯O and N—H⋯N hydrogen bonds connect mol­ecules into undulating sheets perpendicular to the crystallographic a axis. A weak intra­molecular N—H⋯O hydrogen bond is also observed. No π-stacking is observed in the crystal structure. International Union of Crystallography 2011-05-07 /pmc/articles/PMC3120524/ /pubmed/21754753 http://dx.doi.org/10.1107/S1600536811016825 Text en © Betz and Gerber 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Betz, Richard
Gerber, Thomas
3-Nitro­benzene-1,2-diamine
title 3-Nitro­benzene-1,2-diamine
title_full 3-Nitro­benzene-1,2-diamine
title_fullStr 3-Nitro­benzene-1,2-diamine
title_full_unstemmed 3-Nitro­benzene-1,2-diamine
title_short 3-Nitro­benzene-1,2-diamine
title_sort 3-nitro­benzene-1,2-diamine
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120524/
https://www.ncbi.nlm.nih.gov/pubmed/21754753
http://dx.doi.org/10.1107/S1600536811016825
work_keys_str_mv AT betzrichard 3nitrobenzene12diamine
AT gerberthomas 3nitrobenzene12diamine

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