3-Allyl-1-{[3-(4-nitro­phen­yl)-4,5-dihydro-1,3-oxazol-5-yl]meth­yl}-1H-anthra[1,2-d]imidazole-2,6,11(3H)-trione

The mol­ecular structure of the title compound, C(28)H(20)N(4)O(6), consists of three fused six-membered rings (A,B,C) and one five-membered ring (D). The latter is linked to an isoxazole ring (E) via a methyl­ene unit. A 4-nitro-phenyl substituent (F) is attached to the isoxazole. The fused five an...

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Autores principales: Afrakssou, Zahra, Haoudi, Amal, Capet, Frédéric, Rolando, Christian, El Ammari, Lahcen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120525/
https://www.ncbi.nlm.nih.gov/pubmed/21754757
http://dx.doi.org/10.1107/S1600536811016606
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author Afrakssou, Zahra
Haoudi, Amal
Capet, Frédéric
Rolando, Christian
El Ammari, Lahcen
author_facet Afrakssou, Zahra
Haoudi, Amal
Capet, Frédéric
Rolando, Christian
El Ammari, Lahcen
author_sort Afrakssou, Zahra
collection PubMed
description The mol­ecular structure of the title compound, C(28)H(20)N(4)O(6), consists of three fused six-membered rings (A,B,C) and one five-membered ring (D). The latter is linked to an isoxazole ring (E) via a methyl­ene unit. A 4-nitro-phenyl substituent (F) is attached to the isoxazole. The fused five and six-membered rings (C,D) are almost coplanar with an r.m.s. deviation of 0.0345 Å and make a dihedral angle of 9.40 (8)° with ring A. The isoxazole and 4-nitro-phenyl rings (E,F) are also almost coplanar with the imidazole and the fused adjacent ring (C,D), forming a dihedral angle of 11.4 (6)°. The crystal packing displays inter­molecular C—H⋯O hydrogen bonding. An intra­molecular C—H⋯O inter­action also occurs.
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spelling pubmed-31205252011-07-13 3-Allyl-1-{[3-(4-nitro­phen­yl)-4,5-dihydro-1,3-oxazol-5-yl]meth­yl}-1H-anthra[1,2-d]imidazole-2,6,11(3H)-trione Afrakssou, Zahra Haoudi, Amal Capet, Frédéric Rolando, Christian El Ammari, Lahcen Acta Crystallogr Sect E Struct Rep Online Organic Papers The mol­ecular structure of the title compound, C(28)H(20)N(4)O(6), consists of three fused six-membered rings (A,B,C) and one five-membered ring (D). The latter is linked to an isoxazole ring (E) via a methyl­ene unit. A 4-nitro-phenyl substituent (F) is attached to the isoxazole. The fused five and six-membered rings (C,D) are almost coplanar with an r.m.s. deviation of 0.0345 Å and make a dihedral angle of 9.40 (8)° with ring A. The isoxazole and 4-nitro-phenyl rings (E,F) are also almost coplanar with the imidazole and the fused adjacent ring (C,D), forming a dihedral angle of 11.4 (6)°. The crystal packing displays inter­molecular C—H⋯O hydrogen bonding. An intra­molecular C—H⋯O inter­action also occurs. International Union of Crystallography 2011-05-07 /pmc/articles/PMC3120525/ /pubmed/21754757 http://dx.doi.org/10.1107/S1600536811016606 Text en © Afrakssou et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Afrakssou, Zahra
Haoudi, Amal
Capet, Frédéric
Rolando, Christian
El Ammari, Lahcen
3-Allyl-1-{[3-(4-nitro­phen­yl)-4,5-dihydro-1,3-oxazol-5-yl]meth­yl}-1H-anthra[1,2-d]imidazole-2,6,11(3H)-trione
title 3-Allyl-1-{[3-(4-nitro­phen­yl)-4,5-dihydro-1,3-oxazol-5-yl]meth­yl}-1H-anthra[1,2-d]imidazole-2,6,11(3H)-trione
title_full 3-Allyl-1-{[3-(4-nitro­phen­yl)-4,5-dihydro-1,3-oxazol-5-yl]meth­yl}-1H-anthra[1,2-d]imidazole-2,6,11(3H)-trione
title_fullStr 3-Allyl-1-{[3-(4-nitro­phen­yl)-4,5-dihydro-1,3-oxazol-5-yl]meth­yl}-1H-anthra[1,2-d]imidazole-2,6,11(3H)-trione
title_full_unstemmed 3-Allyl-1-{[3-(4-nitro­phen­yl)-4,5-dihydro-1,3-oxazol-5-yl]meth­yl}-1H-anthra[1,2-d]imidazole-2,6,11(3H)-trione
title_short 3-Allyl-1-{[3-(4-nitro­phen­yl)-4,5-dihydro-1,3-oxazol-5-yl]meth­yl}-1H-anthra[1,2-d]imidazole-2,6,11(3H)-trione
title_sort 3-allyl-1-{[3-(4-nitro­phen­yl)-4,5-dihydro-1,3-oxazol-5-yl]meth­yl}-1h-anthra[1,2-d]imidazole-2,6,11(3h)-trione
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120525/
https://www.ncbi.nlm.nih.gov/pubmed/21754757
http://dx.doi.org/10.1107/S1600536811016606
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