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Poly[diaqua(μ(4)-benzene-1,2,4,5-tetracarboxylato)[μ(2)-1,4-bis(3-pyridylmethyl)piperazine]dizinc(II)]
In the title compound, [Zn(2)(C(10)H(2)O(8))(C(16)H(20)N(4))(H(2)O)(2)](n), the Zn(II) atom is in a distorted tetrahedral environment, being coordinated by one N atom from a 1,4-bis(3-pyridylmethyl)piperazine (3-bpmp) ligand, two O atoms from two carboxylate groups of the pyromellitate anion an...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120526/ https://www.ncbi.nlm.nih.gov/pubmed/21754666 http://dx.doi.org/10.1107/S1600536811018721 |
Sumario: | In the title compound, [Zn(2)(C(10)H(2)O(8))(C(16)H(20)N(4))(H(2)O)(2)](n), the Zn(II) atom is in a distorted tetrahedral environment, being coordinated by one N atom from a 1,4-bis(3-pyridylmethyl)piperazine (3-bpmp) ligand, two O atoms from two carboxylate groups of the pyromellitate anion and one water molecule. The distortion of the tetrahedral coordination may be ascribed to the hydrogen bonds between the carboxylate groups and the adjacent water molecules. Each Zn(II) atom links to three organic ligands and each pyromellitate ligand coordinates to four Zn(II) atoms, forming a (3,4)-connected infinite three-dimensional framework. O—H⋯N interactions also occur. |
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