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Poly[diaqua­(μ(4)-benzene-1,2,4,5-tetra­carboxyl­ato)[μ(2)-1,4-bis­(3-pyridyl­meth­yl)piperazine]dizinc(II)]

In the title compound, [Zn(2)(C(10)H(2)O(8))(C(16)H(20)N(4))(H(2)O)(2)](n), the Zn(II) atom is in a distorted tetra­hedral environment, being coordinated by one N atom from a 1,4-bis­(3-pyridyl­meth­yl)piperazine (3-bpmp) ligand, two O atoms from two carboxyl­ate groups of the pyromellitate anion an...

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Detalles Bibliográficos
Autores principales: Zhang, Hui-Feng, Li, Yan, Zhao, Wen-Xiu, Zhao, Liang-Zhong, Zhang, Duo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120526/
https://www.ncbi.nlm.nih.gov/pubmed/21754666
http://dx.doi.org/10.1107/S1600536811018721
Descripción
Sumario:In the title compound, [Zn(2)(C(10)H(2)O(8))(C(16)H(20)N(4))(H(2)O)(2)](n), the Zn(II) atom is in a distorted tetra­hedral environment, being coordinated by one N atom from a 1,4-bis­(3-pyridyl­meth­yl)piperazine (3-bpmp) ligand, two O atoms from two carboxyl­ate groups of the pyromellitate anion and one water mol­ecule. The distortion of the tetrahedral coordination may be ascribed to the hydrogen bonds between the carboxyl­ate groups and the adjacent water mol­ecules. Each Zn(II) atom links to three organic ligands and each pyromellitate ligand coordinates to four Zn(II) atoms, forming a (3,4)-connected infinite three-dimensional framework. O—H⋯N inter­actions also occur.