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Poly[diaqua­(μ(4)-benzene-1,2,4,5-tetra­carboxyl­ato)[μ(2)-1,4-bis­(3-pyridyl­meth­yl)piperazine]dizinc(II)]

In the title compound, [Zn(2)(C(10)H(2)O(8))(C(16)H(20)N(4))(H(2)O)(2)](n), the Zn(II) atom is in a distorted tetra­hedral environment, being coordinated by one N atom from a 1,4-bis­(3-pyridyl­meth­yl)piperazine (3-bpmp) ligand, two O atoms from two carboxyl­ate groups of the pyromellitate anion an...

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Autores principales: Zhang, Hui-Feng, Li, Yan, Zhao, Wen-Xiu, Zhao, Liang-Zhong, Zhang, Duo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120526/
https://www.ncbi.nlm.nih.gov/pubmed/21754666
http://dx.doi.org/10.1107/S1600536811018721
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author Zhang, Hui-Feng
Li, Yan
Zhao, Wen-Xiu
Zhao, Liang-Zhong
Zhang, Duo
author_facet Zhang, Hui-Feng
Li, Yan
Zhao, Wen-Xiu
Zhao, Liang-Zhong
Zhang, Duo
author_sort Zhang, Hui-Feng
collection PubMed
description In the title compound, [Zn(2)(C(10)H(2)O(8))(C(16)H(20)N(4))(H(2)O)(2)](n), the Zn(II) atom is in a distorted tetra­hedral environment, being coordinated by one N atom from a 1,4-bis­(3-pyridyl­meth­yl)piperazine (3-bpmp) ligand, two O atoms from two carboxyl­ate groups of the pyromellitate anion and one water mol­ecule. The distortion of the tetrahedral coordination may be ascribed to the hydrogen bonds between the carboxyl­ate groups and the adjacent water mol­ecules. Each Zn(II) atom links to three organic ligands and each pyromellitate ligand coordinates to four Zn(II) atoms, forming a (3,4)-connected infinite three-dimensional framework. O—H⋯N inter­actions also occur.
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spelling pubmed-31205262011-07-13 Poly[diaqua­(μ(4)-benzene-1,2,4,5-tetra­carboxyl­ato)[μ(2)-1,4-bis­(3-pyridyl­meth­yl)piperazine]dizinc(II)] Zhang, Hui-Feng Li, Yan Zhao, Wen-Xiu Zhao, Liang-Zhong Zhang, Duo Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Zn(2)(C(10)H(2)O(8))(C(16)H(20)N(4))(H(2)O)(2)](n), the Zn(II) atom is in a distorted tetra­hedral environment, being coordinated by one N atom from a 1,4-bis­(3-pyridyl­meth­yl)piperazine (3-bpmp) ligand, two O atoms from two carboxyl­ate groups of the pyromellitate anion and one water mol­ecule. The distortion of the tetrahedral coordination may be ascribed to the hydrogen bonds between the carboxyl­ate groups and the adjacent water mol­ecules. Each Zn(II) atom links to three organic ligands and each pyromellitate ligand coordinates to four Zn(II) atoms, forming a (3,4)-connected infinite three-dimensional framework. O—H⋯N inter­actions also occur. International Union of Crystallography 2011-05-25 /pmc/articles/PMC3120526/ /pubmed/21754666 http://dx.doi.org/10.1107/S1600536811018721 Text en © Zhang et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhang, Hui-Feng
Li, Yan
Zhao, Wen-Xiu
Zhao, Liang-Zhong
Zhang, Duo
Poly[diaqua­(μ(4)-benzene-1,2,4,5-tetra­carboxyl­ato)[μ(2)-1,4-bis­(3-pyridyl­meth­yl)piperazine]dizinc(II)]
title Poly[diaqua­(μ(4)-benzene-1,2,4,5-tetra­carboxyl­ato)[μ(2)-1,4-bis­(3-pyridyl­meth­yl)piperazine]dizinc(II)]
title_full Poly[diaqua­(μ(4)-benzene-1,2,4,5-tetra­carboxyl­ato)[μ(2)-1,4-bis­(3-pyridyl­meth­yl)piperazine]dizinc(II)]
title_fullStr Poly[diaqua­(μ(4)-benzene-1,2,4,5-tetra­carboxyl­ato)[μ(2)-1,4-bis­(3-pyridyl­meth­yl)piperazine]dizinc(II)]
title_full_unstemmed Poly[diaqua­(μ(4)-benzene-1,2,4,5-tetra­carboxyl­ato)[μ(2)-1,4-bis­(3-pyridyl­meth­yl)piperazine]dizinc(II)]
title_short Poly[diaqua­(μ(4)-benzene-1,2,4,5-tetra­carboxyl­ato)[μ(2)-1,4-bis­(3-pyridyl­meth­yl)piperazine]dizinc(II)]
title_sort poly[diaqua­(μ(4)-benzene-1,2,4,5-tetra­carboxyl­ato)[μ(2)-1,4-bis­(3-pyridyl­meth­yl)piperazine]dizinc(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120526/
https://www.ncbi.nlm.nih.gov/pubmed/21754666
http://dx.doi.org/10.1107/S1600536811018721
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