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Poly[diaqua(μ(4)-benzene-1,2,4,5-tetracarboxylato)[μ(2)-1,4-bis(3-pyridylmethyl)piperazine]dizinc(II)]
In the title compound, [Zn(2)(C(10)H(2)O(8))(C(16)H(20)N(4))(H(2)O)(2)](n), the Zn(II) atom is in a distorted tetrahedral environment, being coordinated by one N atom from a 1,4-bis(3-pyridylmethyl)piperazine (3-bpmp) ligand, two O atoms from two carboxylate groups of the pyromellitate anion an...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120526/ https://www.ncbi.nlm.nih.gov/pubmed/21754666 http://dx.doi.org/10.1107/S1600536811018721 |
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author | Zhang, Hui-Feng Li, Yan Zhao, Wen-Xiu Zhao, Liang-Zhong Zhang, Duo |
author_facet | Zhang, Hui-Feng Li, Yan Zhao, Wen-Xiu Zhao, Liang-Zhong Zhang, Duo |
author_sort | Zhang, Hui-Feng |
collection | PubMed |
description | In the title compound, [Zn(2)(C(10)H(2)O(8))(C(16)H(20)N(4))(H(2)O)(2)](n), the Zn(II) atom is in a distorted tetrahedral environment, being coordinated by one N atom from a 1,4-bis(3-pyridylmethyl)piperazine (3-bpmp) ligand, two O atoms from two carboxylate groups of the pyromellitate anion and one water molecule. The distortion of the tetrahedral coordination may be ascribed to the hydrogen bonds between the carboxylate groups and the adjacent water molecules. Each Zn(II) atom links to three organic ligands and each pyromellitate ligand coordinates to four Zn(II) atoms, forming a (3,4)-connected infinite three-dimensional framework. O—H⋯N interactions also occur. |
format | Online Article Text |
id | pubmed-3120526 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-31205262011-07-13 Poly[diaqua(μ(4)-benzene-1,2,4,5-tetracarboxylato)[μ(2)-1,4-bis(3-pyridylmethyl)piperazine]dizinc(II)] Zhang, Hui-Feng Li, Yan Zhao, Wen-Xiu Zhao, Liang-Zhong Zhang, Duo Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Zn(2)(C(10)H(2)O(8))(C(16)H(20)N(4))(H(2)O)(2)](n), the Zn(II) atom is in a distorted tetrahedral environment, being coordinated by one N atom from a 1,4-bis(3-pyridylmethyl)piperazine (3-bpmp) ligand, two O atoms from two carboxylate groups of the pyromellitate anion and one water molecule. The distortion of the tetrahedral coordination may be ascribed to the hydrogen bonds between the carboxylate groups and the adjacent water molecules. Each Zn(II) atom links to three organic ligands and each pyromellitate ligand coordinates to four Zn(II) atoms, forming a (3,4)-connected infinite three-dimensional framework. O—H⋯N interactions also occur. International Union of Crystallography 2011-05-25 /pmc/articles/PMC3120526/ /pubmed/21754666 http://dx.doi.org/10.1107/S1600536811018721 Text en © Zhang et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Zhang, Hui-Feng Li, Yan Zhao, Wen-Xiu Zhao, Liang-Zhong Zhang, Duo Poly[diaqua(μ(4)-benzene-1,2,4,5-tetracarboxylato)[μ(2)-1,4-bis(3-pyridylmethyl)piperazine]dizinc(II)] |
title | Poly[diaqua(μ(4)-benzene-1,2,4,5-tetracarboxylato)[μ(2)-1,4-bis(3-pyridylmethyl)piperazine]dizinc(II)] |
title_full | Poly[diaqua(μ(4)-benzene-1,2,4,5-tetracarboxylato)[μ(2)-1,4-bis(3-pyridylmethyl)piperazine]dizinc(II)] |
title_fullStr | Poly[diaqua(μ(4)-benzene-1,2,4,5-tetracarboxylato)[μ(2)-1,4-bis(3-pyridylmethyl)piperazine]dizinc(II)] |
title_full_unstemmed | Poly[diaqua(μ(4)-benzene-1,2,4,5-tetracarboxylato)[μ(2)-1,4-bis(3-pyridylmethyl)piperazine]dizinc(II)] |
title_short | Poly[diaqua(μ(4)-benzene-1,2,4,5-tetracarboxylato)[μ(2)-1,4-bis(3-pyridylmethyl)piperazine]dizinc(II)] |
title_sort | poly[diaqua(μ(4)-benzene-1,2,4,5-tetracarboxylato)[μ(2)-1,4-bis(3-pyridylmethyl)piperazine]dizinc(ii)] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120526/ https://www.ncbi.nlm.nih.gov/pubmed/21754666 http://dx.doi.org/10.1107/S1600536811018721 |
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