Dimethyl 2-(3-chloro­phen­yl)-6-hy­droxy-6-methyl-4-(methyl­amino)­cyclo­hex-3-ene-1,3-dicarboxyl­ate

In the title compound, C(18)H(22)ClNO(5), the cyclo­hexene ring adopts a distorted half-chair conformation. The mol­ecular structure is stabilized by pairs of intra­molecular N—H⋯O and O—H⋯O inter­actions, generating S(6) motifs. In the crystal, the mol­ecules are linked by inter­molecular C—H⋯O int...

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Detalles Bibliográficos
Autores principales: Amirthaganesan, S., Sundaramoorthy, S., Velmurugan, D., Jeong, Y. T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120530/
https://www.ncbi.nlm.nih.gov/pubmed/21754804
http://dx.doi.org/10.1107/S1600536811017089
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author Amirthaganesan, S.
Sundaramoorthy, S.
Velmurugan, D.
Jeong, Y. T.
author_facet Amirthaganesan, S.
Sundaramoorthy, S.
Velmurugan, D.
Jeong, Y. T.
author_sort Amirthaganesan, S.
collection PubMed
description In the title compound, C(18)H(22)ClNO(5), the cyclo­hexene ring adopts a distorted half-chair conformation. The mol­ecular structure is stabilized by pairs of intra­molecular N—H⋯O and O—H⋯O inter­actions, generating S(6) motifs. In the crystal, the mol­ecules are linked by inter­molecular C—H⋯O inter­actions, forming centrosymmetric dimers.
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spelling pubmed-31205302011-07-13 Dimethyl 2-(3-chloro­phen­yl)-6-hy­droxy-6-methyl-4-(methyl­amino)­cyclo­hex-3-ene-1,3-dicarboxyl­ate Amirthaganesan, S. Sundaramoorthy, S. Velmurugan, D. Jeong, Y. T. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(18)H(22)ClNO(5), the cyclo­hexene ring adopts a distorted half-chair conformation. The mol­ecular structure is stabilized by pairs of intra­molecular N—H⋯O and O—H⋯O inter­actions, generating S(6) motifs. In the crystal, the mol­ecules are linked by inter­molecular C—H⋯O inter­actions, forming centrosymmetric dimers. International Union of Crystallography 2011-05-14 /pmc/articles/PMC3120530/ /pubmed/21754804 http://dx.doi.org/10.1107/S1600536811017089 Text en © Amirthaganesan et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Amirthaganesan, S.
Sundaramoorthy, S.
Velmurugan, D.
Jeong, Y. T.
Dimethyl 2-(3-chloro­phen­yl)-6-hy­droxy-6-methyl-4-(methyl­amino)­cyclo­hex-3-ene-1,3-dicarboxyl­ate
title Dimethyl 2-(3-chloro­phen­yl)-6-hy­droxy-6-methyl-4-(methyl­amino)­cyclo­hex-3-ene-1,3-dicarboxyl­ate
title_full Dimethyl 2-(3-chloro­phen­yl)-6-hy­droxy-6-methyl-4-(methyl­amino)­cyclo­hex-3-ene-1,3-dicarboxyl­ate
title_fullStr Dimethyl 2-(3-chloro­phen­yl)-6-hy­droxy-6-methyl-4-(methyl­amino)­cyclo­hex-3-ene-1,3-dicarboxyl­ate
title_full_unstemmed Dimethyl 2-(3-chloro­phen­yl)-6-hy­droxy-6-methyl-4-(methyl­amino)­cyclo­hex-3-ene-1,3-dicarboxyl­ate
title_short Dimethyl 2-(3-chloro­phen­yl)-6-hy­droxy-6-methyl-4-(methyl­amino)­cyclo­hex-3-ene-1,3-dicarboxyl­ate
title_sort dimethyl 2-(3-chloro­phen­yl)-6-hy­droxy-6-methyl-4-(methyl­amino)­cyclo­hex-3-ene-1,3-dicarboxyl­ate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120530/
https://www.ncbi.nlm.nih.gov/pubmed/21754804
http://dx.doi.org/10.1107/S1600536811017089
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