Poly[(μ(2)-nitrato-κ(2) O:O′)(μ(2)-pyrimidin­ium-2-carboxyl­ato-κ(2) O:O′)lithium(I)]

In the structure of the title compound, [Li(C(5)H(4)N(2)O(2))(NO(3))](n), the Li(I) ion is coordinated by two carboxyl­ate O atoms donated by two ligands and two nitrate O atoms in a distorted tetrahedral geometry. Li(I) ions, bridged by carboxyl­ate O atoms, form mol­ecular ribbons composed of dime...

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Detalles Bibliográficos
Autores principales: Starosta, Wojciech, Leciejewicz, Janusz
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120533/
https://www.ncbi.nlm.nih.gov/pubmed/21754689
http://dx.doi.org/10.1107/S1600536811019520
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author Starosta, Wojciech
Leciejewicz, Janusz
author_facet Starosta, Wojciech
Leciejewicz, Janusz
author_sort Starosta, Wojciech
collection PubMed
description In the structure of the title compound, [Li(C(5)H(4)N(2)O(2))(NO(3))](n), the Li(I) ion is coordinated by two carboxyl­ate O atoms donated by two ligands and two nitrate O atoms in a distorted tetrahedral geometry. Li(I) ions, bridged by carboxyl­ate O atoms, form mol­ecular ribbons composed of dimeric units. Two nitrate O atoms link the ribbons into mol­ecular layers parallel to (001). Hydrogen bonds are active between protonated heterocyclic N atoms as donors and carboxyl­ate O atoms as acceptors. The layers are held together by van der Waals inter­actions.
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spelling pubmed-31205332011-07-13 Poly[(μ(2)-nitrato-κ(2) O:O′)(μ(2)-pyrimidin­ium-2-carboxyl­ato-κ(2) O:O′)lithium(I)] Starosta, Wojciech Leciejewicz, Janusz Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the structure of the title compound, [Li(C(5)H(4)N(2)O(2))(NO(3))](n), the Li(I) ion is coordinated by two carboxyl­ate O atoms donated by two ligands and two nitrate O atoms in a distorted tetrahedral geometry. Li(I) ions, bridged by carboxyl­ate O atoms, form mol­ecular ribbons composed of dimeric units. Two nitrate O atoms link the ribbons into mol­ecular layers parallel to (001). Hydrogen bonds are active between protonated heterocyclic N atoms as donors and carboxyl­ate O atoms as acceptors. The layers are held together by van der Waals inter­actions. International Union of Crystallography 2011-05-28 /pmc/articles/PMC3120533/ /pubmed/21754689 http://dx.doi.org/10.1107/S1600536811019520 Text en © Starosta and Leciejewicz 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Starosta, Wojciech
Leciejewicz, Janusz
Poly[(μ(2)-nitrato-κ(2) O:O′)(μ(2)-pyrimidin­ium-2-carboxyl­ato-κ(2) O:O′)lithium(I)]
title Poly[(μ(2)-nitrato-κ(2) O:O′)(μ(2)-pyrimidin­ium-2-carboxyl­ato-κ(2) O:O′)lithium(I)]
title_full Poly[(μ(2)-nitrato-κ(2) O:O′)(μ(2)-pyrimidin­ium-2-carboxyl­ato-κ(2) O:O′)lithium(I)]
title_fullStr Poly[(μ(2)-nitrato-κ(2) O:O′)(μ(2)-pyrimidin­ium-2-carboxyl­ato-κ(2) O:O′)lithium(I)]
title_full_unstemmed Poly[(μ(2)-nitrato-κ(2) O:O′)(μ(2)-pyrimidin­ium-2-carboxyl­ato-κ(2) O:O′)lithium(I)]
title_short Poly[(μ(2)-nitrato-κ(2) O:O′)(μ(2)-pyrimidin­ium-2-carboxyl­ato-κ(2) O:O′)lithium(I)]
title_sort poly[(μ(2)-nitrato-κ(2) o:o′)(μ(2)-pyrimidin­ium-2-carboxyl­ato-κ(2) o:o′)lithium(i)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120533/
https://www.ncbi.nlm.nih.gov/pubmed/21754689
http://dx.doi.org/10.1107/S1600536811019520
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AT leciejewiczjanusz polym2nitratok2oom2pyrimidinium2carboxylatok2oolithiumi

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