2-[4-(Methyl­sulfan­yl)phen­yl]naphtho[1,8-de][1,3,2]diaza­borinane

The title compound, C(17)H(15)BN(2)S, is one member in a series of diaza­borinanes featuring substitution at the 1-, 2- and 3-positions in the nitro­gen–boron heterocycle. The dihedral angle between the mean planes of the naphthalene and phenyl ring systems is 19.86 (6)°. In the crystal structure, t...

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Detalles Bibliográficos
Autores principales: Slabber, Cathryn A., Akerman, Matthew P., Robinson, Ross S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120534/
https://www.ncbi.nlm.nih.gov/pubmed/21754734
http://dx.doi.org/10.1107/S1600536811014693
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author Slabber, Cathryn A.
Akerman, Matthew P.
Robinson, Ross S.
author_facet Slabber, Cathryn A.
Akerman, Matthew P.
Robinson, Ross S.
author_sort Slabber, Cathryn A.
collection PubMed
description The title compound, C(17)H(15)BN(2)S, is one member in a series of diaza­borinanes featuring substitution at the 1-, 2- and 3-positions in the nitro­gen–boron heterocycle. The dihedral angle between the mean planes of the naphthalene and phenyl ring systems is 19.86 (6)°. In the crystal structure, two C—H⋯π inter­actions link the mol­ecules into sheets which lie parallel to the bc plane. There is a π–π inter­action between each pair of centrosymmetrically related sheets [centroid–centroid distance = 3.5922 (8) Å].
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spelling pubmed-31205342011-07-13 2-[4-(Methyl­sulfan­yl)phen­yl]naphtho[1,8-de][1,3,2]diaza­borinane Slabber, Cathryn A. Akerman, Matthew P. Robinson, Ross S. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(17)H(15)BN(2)S, is one member in a series of diaza­borinanes featuring substitution at the 1-, 2- and 3-positions in the nitro­gen–boron heterocycle. The dihedral angle between the mean planes of the naphthalene and phenyl ring systems is 19.86 (6)°. In the crystal structure, two C—H⋯π inter­actions link the mol­ecules into sheets which lie parallel to the bc plane. There is a π–π inter­action between each pair of centrosymmetrically related sheets [centroid–centroid distance = 3.5922 (8) Å]. International Union of Crystallography 2011-05-07 /pmc/articles/PMC3120534/ /pubmed/21754734 http://dx.doi.org/10.1107/S1600536811014693 Text en © Slabber et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Slabber, Cathryn A.
Akerman, Matthew P.
Robinson, Ross S.
2-[4-(Methyl­sulfan­yl)phen­yl]naphtho[1,8-de][1,3,2]diaza­borinane
title 2-[4-(Methyl­sulfan­yl)phen­yl]naphtho[1,8-de][1,3,2]diaza­borinane
title_full 2-[4-(Methyl­sulfan­yl)phen­yl]naphtho[1,8-de][1,3,2]diaza­borinane
title_fullStr 2-[4-(Methyl­sulfan­yl)phen­yl]naphtho[1,8-de][1,3,2]diaza­borinane
title_full_unstemmed 2-[4-(Methyl­sulfan­yl)phen­yl]naphtho[1,8-de][1,3,2]diaza­borinane
title_short 2-[4-(Methyl­sulfan­yl)phen­yl]naphtho[1,8-de][1,3,2]diaza­borinane
title_sort 2-[4-(methyl­sulfan­yl)phen­yl]naphtho[1,8-de][1,3,2]diaza­borinane
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120534/
https://www.ncbi.nlm.nih.gov/pubmed/21754734
http://dx.doi.org/10.1107/S1600536811014693
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