N,N′-Bis(4-chloro­benzyl­idene)-3,3′-dimeth­oxy­biphenyl-4,4′-diamine

The title compound, C(28)H(22)Cl(2)N(2)O(2), crystallized with two independent mol­ecules (A and B) in the asymmetric unit. The two mol­ecules differ essentially in the orientation of the outer aromatic rings. These dihedral angles are 56.07 (13) and 27.62 (15) Å for mol­ecules A and B, respectively...

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Autores principales: Subashini, Ashokkumar, Ramamurthi, Kandasamy, Stoeckli-Evans, Helen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120541/
https://www.ncbi.nlm.nih.gov/pubmed/21754702
http://dx.doi.org/10.1107/S1600536811015467
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author Subashini, Ashokkumar
Ramamurthi, Kandasamy
Stoeckli-Evans, Helen
author_facet Subashini, Ashokkumar
Ramamurthi, Kandasamy
Stoeckli-Evans, Helen
author_sort Subashini, Ashokkumar
collection PubMed
description The title compound, C(28)H(22)Cl(2)N(2)O(2), crystallized with two independent mol­ecules (A and B) in the asymmetric unit. The two mol­ecules differ essentially in the orientation of the outer aromatic rings. These dihedral angles are 56.07 (13) and 27.62 (15) Å for mol­ecules A and B, respectively. In the crystal, A mol­ecules are related as centrosymmetric pairs through a weak π–π inter­action [centroid–centroid distance = 3.6959 (15) Å]. There are also a number of inter­molecular C—H⋯O, C—H⋯N and C—H⋯π inter­actions present.
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spelling pubmed-31205412011-07-13 N,N′-Bis(4-chloro­benzyl­idene)-3,3′-dimeth­oxy­biphenyl-4,4′-diamine Subashini, Ashokkumar Ramamurthi, Kandasamy Stoeckli-Evans, Helen Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(28)H(22)Cl(2)N(2)O(2), crystallized with two independent mol­ecules (A and B) in the asymmetric unit. The two mol­ecules differ essentially in the orientation of the outer aromatic rings. These dihedral angles are 56.07 (13) and 27.62 (15) Å for mol­ecules A and B, respectively. In the crystal, A mol­ecules are related as centrosymmetric pairs through a weak π–π inter­action [centroid–centroid distance = 3.6959 (15) Å]. There are also a number of inter­molecular C—H⋯O, C—H⋯N and C—H⋯π inter­actions present. International Union of Crystallography 2011-05-07 /pmc/articles/PMC3120541/ /pubmed/21754702 http://dx.doi.org/10.1107/S1600536811015467 Text en © Subashini et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Subashini, Ashokkumar
Ramamurthi, Kandasamy
Stoeckli-Evans, Helen
N,N′-Bis(4-chloro­benzyl­idene)-3,3′-dimeth­oxy­biphenyl-4,4′-diamine
title N,N′-Bis(4-chloro­benzyl­idene)-3,3′-dimeth­oxy­biphenyl-4,4′-diamine
title_full N,N′-Bis(4-chloro­benzyl­idene)-3,3′-dimeth­oxy­biphenyl-4,4′-diamine
title_fullStr N,N′-Bis(4-chloro­benzyl­idene)-3,3′-dimeth­oxy­biphenyl-4,4′-diamine
title_full_unstemmed N,N′-Bis(4-chloro­benzyl­idene)-3,3′-dimeth­oxy­biphenyl-4,4′-diamine
title_short N,N′-Bis(4-chloro­benzyl­idene)-3,3′-dimeth­oxy­biphenyl-4,4′-diamine
title_sort n,n′-bis(4-chloro­benzyl­idene)-3,3′-dimeth­oxy­biphenyl-4,4′-diamine
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120541/
https://www.ncbi.nlm.nih.gov/pubmed/21754702
http://dx.doi.org/10.1107/S1600536811015467
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AT ramamurthikandasamy nnbis4chlorobenzylidene33dimethoxybiphenyl44diamine
AT stoecklievanshelen nnbis4chlorobenzylidene33dimethoxybiphenyl44diamine

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