8-Formyl-4-methyl-2-oxo-2H-chromen-7-yl 4-methyl­benzenesulfonate

In the title compound, C(18)H(14)O(6)S, the coumarin ring system is nearly planar, with a maximum out-of-plane deviation of 0.032 (2) Å. The dihedral angle between the benzene ring and the coumarin ring system is 32.41 (8)°. The crystal packing is stabilized by inter­molecular C—H⋯O inter­actions, g...

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Autores principales: Yuvaraj, H., Gayathri, D., Kalkhambkar, Rajesh G., Kulkarni, Geeta M., Bapset, Rajendra M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120547/
https://www.ncbi.nlm.nih.gov/pubmed/21754878
http://dx.doi.org/10.1107/S1600536811018927
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author Yuvaraj, H.
Gayathri, D.
Kalkhambkar, Rajesh G.
Kulkarni, Geeta M.
Bapset, Rajendra M.
author_facet Yuvaraj, H.
Gayathri, D.
Kalkhambkar, Rajesh G.
Kulkarni, Geeta M.
Bapset, Rajendra M.
author_sort Yuvaraj, H.
collection PubMed
description In the title compound, C(18)H(14)O(6)S, the coumarin ring system is nearly planar, with a maximum out-of-plane deviation of 0.032 (2) Å. The dihedral angle between the benzene ring and the coumarin ring system is 32.41 (8)°. The crystal packing is stabilized by inter­molecular C—H⋯O inter­actions, generating C(8), C(10) and C(11) chains and an R (2) (2)(10) ring. The formyl group is disordered over two sets of sites, with occupancies of 0.548 (5) and 0.452 (5).
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spelling pubmed-31205472011-07-13 8-Formyl-4-methyl-2-oxo-2H-chromen-7-yl 4-methyl­benzenesulfonate Yuvaraj, H. Gayathri, D. Kalkhambkar, Rajesh G. Kulkarni, Geeta M. Bapset, Rajendra M. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(18)H(14)O(6)S, the coumarin ring system is nearly planar, with a maximum out-of-plane deviation of 0.032 (2) Å. The dihedral angle between the benzene ring and the coumarin ring system is 32.41 (8)°. The crystal packing is stabilized by inter­molecular C—H⋯O inter­actions, generating C(8), C(10) and C(11) chains and an R (2) (2)(10) ring. The formyl group is disordered over two sets of sites, with occupancies of 0.548 (5) and 0.452 (5). International Union of Crystallography 2011-05-25 /pmc/articles/PMC3120547/ /pubmed/21754878 http://dx.doi.org/10.1107/S1600536811018927 Text en © Yuvaraj et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Yuvaraj, H.
Gayathri, D.
Kalkhambkar, Rajesh G.
Kulkarni, Geeta M.
Bapset, Rajendra M.
8-Formyl-4-methyl-2-oxo-2H-chromen-7-yl 4-methyl­benzenesulfonate
title 8-Formyl-4-methyl-2-oxo-2H-chromen-7-yl 4-methyl­benzenesulfonate
title_full 8-Formyl-4-methyl-2-oxo-2H-chromen-7-yl 4-methyl­benzenesulfonate
title_fullStr 8-Formyl-4-methyl-2-oxo-2H-chromen-7-yl 4-methyl­benzenesulfonate
title_full_unstemmed 8-Formyl-4-methyl-2-oxo-2H-chromen-7-yl 4-methyl­benzenesulfonate
title_short 8-Formyl-4-methyl-2-oxo-2H-chromen-7-yl 4-methyl­benzenesulfonate
title_sort 8-formyl-4-methyl-2-oxo-2h-chromen-7-yl 4-methyl­benzenesulfonate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120547/
https://www.ncbi.nlm.nih.gov/pubmed/21754878
http://dx.doi.org/10.1107/S1600536811018927
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