Methyl c-1-cyano-t-2-methyl­sulfonyl-3-phenyl­cyclo­propane­carboxyl­ate

The title compound, C(13)H(13)NO(4)S, is a racemic mixture of enanti­omers. Short intra­molecular contacts between sulfonyl O and ester carbonyl C atoms are observed [C⋯O = 2.881 (1), 2.882 (1) and 2.686 (1) Å], indicating the possibility of donor—acceptor inter­actions between these groups. The dih...

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Autores principales: Vasin, Victor A., Bolusheva, Irina Yu., Neverov, Vyacheslav A., Somov, Nikolai V.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120552/
https://www.ncbi.nlm.nih.gov/pubmed/21754871
http://dx.doi.org/10.1107/S1600536811016370
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author Vasin, Victor A.
Bolusheva, Irina Yu.
Neverov, Vyacheslav A.
Somov, Nikolai V.
author_facet Vasin, Victor A.
Bolusheva, Irina Yu.
Neverov, Vyacheslav A.
Somov, Nikolai V.
author_sort Vasin, Victor A.
collection PubMed
description The title compound, C(13)H(13)NO(4)S, is a racemic mixture of enanti­omers. Short intra­molecular contacts between sulfonyl O and ester carbonyl C atoms are observed [C⋯O = 2.881 (1), 2.882 (1) and 2.686 (1) Å], indicating the possibility of donor—acceptor inter­actions between these groups. The dihedral angle between the phenyl and cyclopropyl rings is 79.3 (1)°.
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spelling pubmed-31205522011-07-13 Methyl c-1-cyano-t-2-methyl­sulfonyl-3-phenyl­cyclo­propane­carboxyl­ate Vasin, Victor A. Bolusheva, Irina Yu. Neverov, Vyacheslav A. Somov, Nikolai V. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(13)H(13)NO(4)S, is a racemic mixture of enanti­omers. Short intra­molecular contacts between sulfonyl O and ester carbonyl C atoms are observed [C⋯O = 2.881 (1), 2.882 (1) and 2.686 (1) Å], indicating the possibility of donor—acceptor inter­actions between these groups. The dihedral angle between the phenyl and cyclopropyl rings is 79.3 (1)°. International Union of Crystallography 2011-05-25 /pmc/articles/PMC3120552/ /pubmed/21754871 http://dx.doi.org/10.1107/S1600536811016370 Text en © Vasin et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Vasin, Victor A.
Bolusheva, Irina Yu.
Neverov, Vyacheslav A.
Somov, Nikolai V.
Methyl c-1-cyano-t-2-methyl­sulfonyl-3-phenyl­cyclo­propane­carboxyl­ate
title Methyl c-1-cyano-t-2-methyl­sulfonyl-3-phenyl­cyclo­propane­carboxyl­ate
title_full Methyl c-1-cyano-t-2-methyl­sulfonyl-3-phenyl­cyclo­propane­carboxyl­ate
title_fullStr Methyl c-1-cyano-t-2-methyl­sulfonyl-3-phenyl­cyclo­propane­carboxyl­ate
title_full_unstemmed Methyl c-1-cyano-t-2-methyl­sulfonyl-3-phenyl­cyclo­propane­carboxyl­ate
title_short Methyl c-1-cyano-t-2-methyl­sulfonyl-3-phenyl­cyclo­propane­carboxyl­ate
title_sort methyl c-1-cyano-t-2-methyl­sulfonyl-3-phenyl­cyclo­propane­carboxyl­ate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120552/
https://www.ncbi.nlm.nih.gov/pubmed/21754871
http://dx.doi.org/10.1107/S1600536811016370
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