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Bis(3,5,7-triaza-1-azoniatricyclo[3.3.1.1(3,7)]decane) bis(1,2-dicyanoethene-1,2-dithiolato)nickelate(II)
The asymmetric unit of the title complex, (C(6)H(13)N(4))(2)[Ni(C(4)N(2)S(2))(2)], comprises one 1-azonia-3,5,7-triazatricyclo[3.3.1.1(3,7)]decane cation and one half of an [Ni(mnt)(2)](2−) (mnt(2−) is maleonitriledithiolate or 1,2-dicyanoethene-1,2-dithiolate) dianion. The Ni(2+) ion is locat...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120553/ https://www.ncbi.nlm.nih.gov/pubmed/21754626 http://dx.doi.org/10.1107/S160053681101645X |
Sumario: | The asymmetric unit of the title complex, (C(6)H(13)N(4))(2)[Ni(C(4)N(2)S(2))(2)], comprises one 1-azonia-3,5,7-triazatricyclo[3.3.1.1(3,7)]decane cation and one half of an [Ni(mnt)(2)](2−) (mnt(2−) is maleonitriledithiolate or 1,2-dicyanoethene-1,2-dithiolate) dianion. The Ni(2+) ion is located on a center of inversion and is coordinated by four S atoms from two mnt(2−) ligands in a square-planar coordination mode. Intermolecular N—H⋯N hydrogen-bond interactions link one anion and two cations in the crystal structure. |
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