Bis(3,5,7-triaza-1-azoniatricyclo­[3.3.1.1(3,7)]deca­ne) bis­(1,2-dicyano­ethene-1,2-dithiol­ato)nickelate(II)

The asymmetric unit of the title complex, (C(6)H(13)N(4))(2)[Ni(C(4)N(2)S(2))(2)], comprises one 1-azonia-3,5,7-triaza­tricyclo­[3.3.1.1(3,7)]decane cation and one half of an [Ni(mnt)(2)](2−) (mnt(2−) is maleonitrile­dithiol­ate or 1,2-dicyano­ethene-1,2-dithiol­ate) dianion. The Ni(2+) ion is locat...

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Detalles Bibliográficos
Autores principales: Pan, Chen, Cai, Bin, Pei, Wen-Bo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120553/
https://www.ncbi.nlm.nih.gov/pubmed/21754626
http://dx.doi.org/10.1107/S160053681101645X
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author Pan, Chen
Cai, Bin
Pei, Wen-Bo
author_facet Pan, Chen
Cai, Bin
Pei, Wen-Bo
author_sort Pan, Chen
collection PubMed
description The asymmetric unit of the title complex, (C(6)H(13)N(4))(2)[Ni(C(4)N(2)S(2))(2)], comprises one 1-azonia-3,5,7-triaza­tricyclo­[3.3.1.1(3,7)]decane cation and one half of an [Ni(mnt)(2)](2−) (mnt(2−) is maleonitrile­dithiol­ate or 1,2-dicyano­ethene-1,2-dithiol­ate) dianion. The Ni(2+) ion is located on a center of inversion and is coordinated by four S atoms from two mnt(2−) ligands in a square-planar coordination mode. Inter­molecular N—H⋯N hydrogen-bond inter­actions link one anion and two cations in the crystal structure.
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spelling pubmed-31205532011-07-13 Bis(3,5,7-triaza-1-azoniatricyclo­[3.3.1.1(3,7)]deca­ne) bis­(1,2-dicyano­ethene-1,2-dithiol­ato)nickelate(II) Pan, Chen Cai, Bin Pei, Wen-Bo Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title complex, (C(6)H(13)N(4))(2)[Ni(C(4)N(2)S(2))(2)], comprises one 1-azonia-3,5,7-triaza­tricyclo­[3.3.1.1(3,7)]decane cation and one half of an [Ni(mnt)(2)](2−) (mnt(2−) is maleonitrile­dithiol­ate or 1,2-dicyano­ethene-1,2-dithiol­ate) dianion. The Ni(2+) ion is located on a center of inversion and is coordinated by four S atoms from two mnt(2−) ligands in a square-planar coordination mode. Inter­molecular N—H⋯N hydrogen-bond inter­actions link one anion and two cations in the crystal structure. International Union of Crystallography 2011-05-07 /pmc/articles/PMC3120553/ /pubmed/21754626 http://dx.doi.org/10.1107/S160053681101645X Text en © Pan et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Pan, Chen
Cai, Bin
Pei, Wen-Bo
Bis(3,5,7-triaza-1-azoniatricyclo­[3.3.1.1(3,7)]deca­ne) bis­(1,2-dicyano­ethene-1,2-dithiol­ato)nickelate(II)
title Bis(3,5,7-triaza-1-azoniatricyclo­[3.3.1.1(3,7)]deca­ne) bis­(1,2-dicyano­ethene-1,2-dithiol­ato)nickelate(II)
title_full Bis(3,5,7-triaza-1-azoniatricyclo­[3.3.1.1(3,7)]deca­ne) bis­(1,2-dicyano­ethene-1,2-dithiol­ato)nickelate(II)
title_fullStr Bis(3,5,7-triaza-1-azoniatricyclo­[3.3.1.1(3,7)]deca­ne) bis­(1,2-dicyano­ethene-1,2-dithiol­ato)nickelate(II)
title_full_unstemmed Bis(3,5,7-triaza-1-azoniatricyclo­[3.3.1.1(3,7)]deca­ne) bis­(1,2-dicyano­ethene-1,2-dithiol­ato)nickelate(II)
title_short Bis(3,5,7-triaza-1-azoniatricyclo­[3.3.1.1(3,7)]deca­ne) bis­(1,2-dicyano­ethene-1,2-dithiol­ato)nickelate(II)
title_sort bis(3,5,7-triaza-1-azoniatricyclo­[3.3.1.1(3,7)]deca­ne) bis­(1,2-dicyano­ethene-1,2-dithiol­ato)nickelate(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120553/
https://www.ncbi.nlm.nih.gov/pubmed/21754626
http://dx.doi.org/10.1107/S160053681101645X
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AT caibin bis357triaza1azoniatricyclo331137decanebis12dicyanoethene12dithiolatonickelateii
AT peiwenbo bis357triaza1azoniatricyclo331137decanebis12dicyanoethene12dithiolatonickelateii

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