Propan-1-aminium 3,4,5,6-tetra­bromo-2-(meth­oxy­carbon­yl)benzoate N,N-dimethyl­formamide monosolvate

In the anion of the title solvated molecular salt, C(3)H(10)N(+)·C(9)H(3)Br(4)O(4) (−)·C(3)H(7)NO, the dihedral angles formed by the aromatic ring and the mean planes of the carboxyl­ate and meth­oxy­carbonyl groups are 64.3 (3) and 75.2 (3)°, respectively. The C atoms of the propan-1-aminium cation...

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Detalles Bibliográficos
Autor principal: Li, Jian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120559/
https://www.ncbi.nlm.nih.gov/pubmed/21754750
http://dx.doi.org/10.1107/S1600536811016850
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author Li, Jian
author_facet Li, Jian
author_sort Li, Jian
collection PubMed
description In the anion of the title solvated molecular salt, C(3)H(10)N(+)·C(9)H(3)Br(4)O(4) (−)·C(3)H(7)NO, the dihedral angles formed by the aromatic ring and the mean planes of the carboxyl­ate and meth­oxy­carbonyl groups are 64.3 (3) and 75.2 (3)°, respectively. The C atoms of the propan-1-aminium cation are disordered over two sets of sites in a 0.65 (3):0.35 (3) ratio. The crystal structure is stabilized by N—H⋯O hydrogen bonds.
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spelling pubmed-31205592011-07-13 Propan-1-aminium 3,4,5,6-tetra­bromo-2-(meth­oxy­carbon­yl)benzoate N,N-dimethyl­formamide monosolvate Li, Jian Acta Crystallogr Sect E Struct Rep Online Organic Papers In the anion of the title solvated molecular salt, C(3)H(10)N(+)·C(9)H(3)Br(4)O(4) (−)·C(3)H(7)NO, the dihedral angles formed by the aromatic ring and the mean planes of the carboxyl­ate and meth­oxy­carbonyl groups are 64.3 (3) and 75.2 (3)°, respectively. The C atoms of the propan-1-aminium cation are disordered over two sets of sites in a 0.65 (3):0.35 (3) ratio. The crystal structure is stabilized by N—H⋯O hydrogen bonds. International Union of Crystallography 2011-05-07 /pmc/articles/PMC3120559/ /pubmed/21754750 http://dx.doi.org/10.1107/S1600536811016850 Text en © Jian Li 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Li, Jian
Propan-1-aminium 3,4,5,6-tetra­bromo-2-(meth­oxy­carbon­yl)benzoate N,N-dimethyl­formamide monosolvate
title Propan-1-aminium 3,4,5,6-tetra­bromo-2-(meth­oxy­carbon­yl)benzoate N,N-dimethyl­formamide monosolvate
title_full Propan-1-aminium 3,4,5,6-tetra­bromo-2-(meth­oxy­carbon­yl)benzoate N,N-dimethyl­formamide monosolvate
title_fullStr Propan-1-aminium 3,4,5,6-tetra­bromo-2-(meth­oxy­carbon­yl)benzoate N,N-dimethyl­formamide monosolvate
title_full_unstemmed Propan-1-aminium 3,4,5,6-tetra­bromo-2-(meth­oxy­carbon­yl)benzoate N,N-dimethyl­formamide monosolvate
title_short Propan-1-aminium 3,4,5,6-tetra­bromo-2-(meth­oxy­carbon­yl)benzoate N,N-dimethyl­formamide monosolvate
title_sort propan-1-aminium 3,4,5,6-tetra­bromo-2-(meth­oxy­carbon­yl)benzoate n,n-dimethyl­formamide monosolvate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120559/
https://www.ncbi.nlm.nih.gov/pubmed/21754750
http://dx.doi.org/10.1107/S1600536811016850
work_keys_str_mv AT lijian propan1aminium3456tetrabromo2methoxycarbonylbenzoatenndimethylformamidemonosolvate

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