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Aqua(2,2′-diamino-4,4′-bi-1,3-thiazole-κ(2) N (3),N (3′))(thiodiacetato-κ(3) O,S,O′)nickel(II) monohydrate
In the title compound, [Ni(C(4)H(4)O(4)S)(C(6)H(6)N(4)S(2))(H(2)O)]·H(2)O, the Ni(II) cation assumes a distorted octahedral coordination geometry formed by a diaminobithiazole (DABT) ligand, a thiodiacetate (TDA) dianion and a coordinated water molecule. The tridentate TDA chelates to the Ni ca...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120560/ https://www.ncbi.nlm.nih.gov/pubmed/21754589 http://dx.doi.org/10.1107/S1600536811015157 |
Sumario: | In the title compound, [Ni(C(4)H(4)O(4)S)(C(6)H(6)N(4)S(2))(H(2)O)]·H(2)O, the Ni(II) cation assumes a distorted octahedral coordination geometry formed by a diaminobithiazole (DABT) ligand, a thiodiacetate (TDA) dianion and a coordinated water molecule. The tridentate TDA chelates to the Ni cation in a facial configuration, and both chelating rings display the envelope conformations. The two thiazole rings of the DABT ligand are twisted with respect to each other, making a dihedral angle of 9.96 (9)°. Extensive O—H⋯O, N—H⋯O and weak C—H⋯O hydrogen bonding is present in the crystal structure. |
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