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Aqua(2,2′-diamino-4,4′-bi-1,3-thiazole-κ(2) N (3),N (3′))(thiodiacetato-κ(3) O,S,O′)nickel(II) monohydrate
In the title compound, [Ni(C(4)H(4)O(4)S)(C(6)H(6)N(4)S(2))(H(2)O)]·H(2)O, the Ni(II) cation assumes a distorted octahedral coordination geometry formed by a diaminobithiazole (DABT) ligand, a thiodiacetate (TDA) dianion and a coordinated water molecule. The tridentate TDA chelates to the Ni ca...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120560/ https://www.ncbi.nlm.nih.gov/pubmed/21754589 http://dx.doi.org/10.1107/S1600536811015157 |
| _version_ | 1782206706742198272 |
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| author | Wang, Yan-Li Chang, Guang-Jun Liu, Bing-Xin |
| author_facet | Wang, Yan-Li Chang, Guang-Jun Liu, Bing-Xin |
| author_sort | Wang, Yan-Li |
| collection | PubMed |
| description | In the title compound, [Ni(C(4)H(4)O(4)S)(C(6)H(6)N(4)S(2))(H(2)O)]·H(2)O, the Ni(II) cation assumes a distorted octahedral coordination geometry formed by a diaminobithiazole (DABT) ligand, a thiodiacetate (TDA) dianion and a coordinated water molecule. The tridentate TDA chelates to the Ni cation in a facial configuration, and both chelating rings display the envelope conformations. The two thiazole rings of the DABT ligand are twisted with respect to each other, making a dihedral angle of 9.96 (9)°. Extensive O—H⋯O, N—H⋯O and weak C—H⋯O hydrogen bonding is present in the crystal structure. |
| format | Online Article Text |
| id | pubmed-3120560 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-31205602011-07-13 Aqua(2,2′-diamino-4,4′-bi-1,3-thiazole-κ(2) N (3),N (3′))(thiodiacetato-κ(3) O,S,O′)nickel(II) monohydrate Wang, Yan-Li Chang, Guang-Jun Liu, Bing-Xin Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ni(C(4)H(4)O(4)S)(C(6)H(6)N(4)S(2))(H(2)O)]·H(2)O, the Ni(II) cation assumes a distorted octahedral coordination geometry formed by a diaminobithiazole (DABT) ligand, a thiodiacetate (TDA) dianion and a coordinated water molecule. The tridentate TDA chelates to the Ni cation in a facial configuration, and both chelating rings display the envelope conformations. The two thiazole rings of the DABT ligand are twisted with respect to each other, making a dihedral angle of 9.96 (9)°. Extensive O—H⋯O, N—H⋯O and weak C—H⋯O hydrogen bonding is present in the crystal structure. International Union of Crystallography 2011-05-07 /pmc/articles/PMC3120560/ /pubmed/21754589 http://dx.doi.org/10.1107/S1600536811015157 Text en © Wang et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Wang, Yan-Li Chang, Guang-Jun Liu, Bing-Xin Aqua(2,2′-diamino-4,4′-bi-1,3-thiazole-κ(2) N (3),N (3′))(thiodiacetato-κ(3) O,S,O′)nickel(II) monohydrate |
| title | Aqua(2,2′-diamino-4,4′-bi-1,3-thiazole-κ(2)
N
(3),N
(3′))(thiodiacetato-κ(3)
O,S,O′)nickel(II) monohydrate |
| title_full | Aqua(2,2′-diamino-4,4′-bi-1,3-thiazole-κ(2)
N
(3),N
(3′))(thiodiacetato-κ(3)
O,S,O′)nickel(II) monohydrate |
| title_fullStr | Aqua(2,2′-diamino-4,4′-bi-1,3-thiazole-κ(2)
N
(3),N
(3′))(thiodiacetato-κ(3)
O,S,O′)nickel(II) monohydrate |
| title_full_unstemmed | Aqua(2,2′-diamino-4,4′-bi-1,3-thiazole-κ(2)
N
(3),N
(3′))(thiodiacetato-κ(3)
O,S,O′)nickel(II) monohydrate |
| title_short | Aqua(2,2′-diamino-4,4′-bi-1,3-thiazole-κ(2)
N
(3),N
(3′))(thiodiacetato-κ(3)
O,S,O′)nickel(II) monohydrate |
| title_sort | aqua(2,2′-diamino-4,4′-bi-1,3-thiazole-κ(2)
n
(3),n
(3′))(thiodiacetato-κ(3)
o,s,o′)nickel(ii) monohydrate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120560/ https://www.ncbi.nlm.nih.gov/pubmed/21754589 http://dx.doi.org/10.1107/S1600536811015157 |
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