{2,2′-[(Benzyl­aza­nedi­yl)dimethylene]diphenolato}(methano­lato)boron

The title compound, C(22)H(22)BNO(3), was unintentionally obtained from salicyl­aldehyde benzyl­amine and sodium borohydride. The B—O bond lengths lie in the range 1.425 (2)–1.463 (2) Å, and B—N = 1.641 (2) Å. In the crystal, weak inter­molecular C—H⋯O hydrogen bonds link the mol­ecules into chains...

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Detalles Bibliográficos
Autores principales: Geng, Yanxia, Wu, Wangsuo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120563/
https://www.ncbi.nlm.nih.gov/pubmed/21754770
http://dx.doi.org/10.1107/S1600536811016990
Descripción
Sumario:The title compound, C(22)H(22)BNO(3), was unintentionally obtained from salicyl­aldehyde benzyl­amine and sodium borohydride. The B—O bond lengths lie in the range 1.425 (2)–1.463 (2) Å, and B—N = 1.641 (2) Å. In the crystal, weak inter­molecular C—H⋯O hydrogen bonds link the mol­ecules into chains in the [010] direction.

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