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catena-Poly[[cobalt(II)-μ-aqua-di-μ-butanoato-κ(2) O:O′;κ(2) O:O] 0.7-hydrate]
In the title coordination polymer, {[Co(C(3)H(7)COO)(2)(H(2)O)]·0.7H(2)O}(n), the Co(2+) cation is coordinated by four bridging butanoate anions and two bridging water molecules in a severely distorted octahedral geometry. The Co(2+) cations are linked by means of bridging ligands into polymeric...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120566/ https://www.ncbi.nlm.nih.gov/pubmed/21754682 http://dx.doi.org/10.1107/S1600536811019271 |
Sumario: | In the title coordination polymer, {[Co(C(3)H(7)COO)(2)(H(2)O)]·0.7H(2)O}(n), the Co(2+) cation is coordinated by four bridging butanoate anions and two bridging water molecules in a severely distorted octahedral geometry. The Co(2+) cations are linked by means of bridging ligands into polymeric chains along [010]. These chains are further connected to each other through hydrogen bonds involving partially occupied disordered water molecules; thus, sheets parallel to (001) are formed. One of the positions of disordered water O atom lies on a twofold axis. Two atoms of the aliphatic chain of one of the butanoate anions are disordered over two positions each. |
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