Cargando…
catena-Poly[[cobalt(II)-μ-aqua-di-μ-butanoato-κ(2) O:O′;κ(2) O:O] 0.7-hydrate]
In the title coordination polymer, {[Co(C(3)H(7)COO)(2)(H(2)O)]·0.7H(2)O}(n), the Co(2+) cation is coordinated by four bridging butanoate anions and two bridging water molecules in a severely distorted octahedral geometry. The Co(2+) cations are linked by means of bridging ligands into polymeric...
| Autores principales: | , , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120566/ https://www.ncbi.nlm.nih.gov/pubmed/21754682 http://dx.doi.org/10.1107/S1600536811019271 |
| _version_ | 1782206708094861312 |
|---|---|
| author | Fischer, A. I. Gurzhiy, V. V. Belyaev, A. N. |
| author_facet | Fischer, A. I. Gurzhiy, V. V. Belyaev, A. N. |
| author_sort | Fischer, A. I. |
| collection | PubMed |
| description | In the title coordination polymer, {[Co(C(3)H(7)COO)(2)(H(2)O)]·0.7H(2)O}(n), the Co(2+) cation is coordinated by four bridging butanoate anions and two bridging water molecules in a severely distorted octahedral geometry. The Co(2+) cations are linked by means of bridging ligands into polymeric chains along [010]. These chains are further connected to each other through hydrogen bonds involving partially occupied disordered water molecules; thus, sheets parallel to (001) are formed. One of the positions of disordered water O atom lies on a twofold axis. Two atoms of the aliphatic chain of one of the butanoate anions are disordered over two positions each. |
| format | Online Article Text |
| id | pubmed-3120566 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-31205662011-07-13 catena-Poly[[cobalt(II)-μ-aqua-di-μ-butanoato-κ(2) O:O′;κ(2) O:O] 0.7-hydrate] Fischer, A. I. Gurzhiy, V. V. Belyaev, A. N. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title coordination polymer, {[Co(C(3)H(7)COO)(2)(H(2)O)]·0.7H(2)O}(n), the Co(2+) cation is coordinated by four bridging butanoate anions and two bridging water molecules in a severely distorted octahedral geometry. The Co(2+) cations are linked by means of bridging ligands into polymeric chains along [010]. These chains are further connected to each other through hydrogen bonds involving partially occupied disordered water molecules; thus, sheets parallel to (001) are formed. One of the positions of disordered water O atom lies on a twofold axis. Two atoms of the aliphatic chain of one of the butanoate anions are disordered over two positions each. International Union of Crystallography 2011-05-28 /pmc/articles/PMC3120566/ /pubmed/21754682 http://dx.doi.org/10.1107/S1600536811019271 Text en © Fischer et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Fischer, A. I. Gurzhiy, V. V. Belyaev, A. N. catena-Poly[[cobalt(II)-μ-aqua-di-μ-butanoato-κ(2) O:O′;κ(2) O:O] 0.7-hydrate] |
| title |
catena-Poly[[cobalt(II)-μ-aqua-di-μ-butanoato-κ(2)
O:O′;κ(2)
O:O] 0.7-hydrate] |
| title_full |
catena-Poly[[cobalt(II)-μ-aqua-di-μ-butanoato-κ(2)
O:O′;κ(2)
O:O] 0.7-hydrate] |
| title_fullStr |
catena-Poly[[cobalt(II)-μ-aqua-di-μ-butanoato-κ(2)
O:O′;κ(2)
O:O] 0.7-hydrate] |
| title_full_unstemmed |
catena-Poly[[cobalt(II)-μ-aqua-di-μ-butanoato-κ(2)
O:O′;κ(2)
O:O] 0.7-hydrate] |
| title_short |
catena-Poly[[cobalt(II)-μ-aqua-di-μ-butanoato-κ(2)
O:O′;κ(2)
O:O] 0.7-hydrate] |
| title_sort | catena-poly[[cobalt(ii)-μ-aqua-di-μ-butanoato-κ(2)
o:o′;κ(2)
o:o] 0.7-hydrate] |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120566/ https://www.ncbi.nlm.nih.gov/pubmed/21754682 http://dx.doi.org/10.1107/S1600536811019271 |
| work_keys_str_mv | AT fischerai catenapolycobaltiimaquadimbutanoatok2ook2oo07hydrate AT gurzhiyvv catenapolycobaltiimaquadimbutanoatok2ook2oo07hydrate AT belyaevan catenapolycobaltiimaquadimbutanoatok2ook2oo07hydrate |