LiYbCl(4)(THF)(4)

The title compound, di-μ-chlorido-dichlorido-1κ(2) Cl-tetra­kis­(tetra­hydro­furan)-1κ(2) O,2κ(2) O-lithiumytterbium(III), [LiYbCl(4)(C(4)H(8)O)(4)], was prepared by the reaction of YbCl(3)(THF)(3) with LiCl in THF (THF is tetra­hydro­furan). The central motif of the structure is a Yb(μ-Cl)(2)Li rin...

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Detalles Bibliográficos
Autores principales: Richtera, Lukas, Jancik, Vojtech, Hermanova, Sona, Krpoun, Karel, Thompson-Montero, Kimberly
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120567/
https://www.ncbi.nlm.nih.gov/pubmed/21754604
http://dx.doi.org/10.1107/S1600536811014395
Descripción
Sumario:The title compound, di-μ-chlorido-dichlorido-1κ(2) Cl-tetra­kis­(tetra­hydro­furan)-1κ(2) O,2κ(2) O-lithiumytterbium(III), [LiYbCl(4)(C(4)H(8)O)(4)], was prepared by the reaction of YbCl(3)(THF)(3) with LiCl in THF (THF is tetra­hydro­furan). The central motif of the structure is a Yb(μ-Cl)(2)Li ring. The Yb atom is hexa­coordinated to four Cl atoms and two THF mol­ecules oriented in a trans fashion. The Li atom has a tetra­hedral environment and is coordinated to two Cl atoms and two THF mol­ecules. No inter­molecular inter­actions other than van der Waals forces were observed. Two of the THF mol­ecules are disordered over two positions.

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