LiYbCl(4)(THF)(4)

The title compound, di-μ-chlorido-dichlorido-1κ(2) Cl-tetra­kis­(tetra­hydro­furan)-1κ(2) O,2κ(2) O-lithiumytterbium(III), [LiYbCl(4)(C(4)H(8)O)(4)], was prepared by the reaction of YbCl(3)(THF)(3) with LiCl in THF (THF is tetra­hydro­furan). The central motif of the structure is a Yb(μ-Cl)(2)Li rin...

Descripción completa

Detalles Bibliográficos
Autores principales: Richtera, Lukas, Jancik, Vojtech, Hermanova, Sona, Krpoun, Karel, Thompson-Montero, Kimberly
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120567/
https://www.ncbi.nlm.nih.gov/pubmed/21754604
http://dx.doi.org/10.1107/S1600536811014395
_version_ 1782206708312965120
author Richtera, Lukas
Jancik, Vojtech
Hermanova, Sona
Krpoun, Karel
Thompson-Montero, Kimberly
author_facet Richtera, Lukas
Jancik, Vojtech
Hermanova, Sona
Krpoun, Karel
Thompson-Montero, Kimberly
author_sort Richtera, Lukas
collection PubMed
description The title compound, di-μ-chlorido-dichlorido-1κ(2) Cl-tetra­kis­(tetra­hydro­furan)-1κ(2) O,2κ(2) O-lithiumytterbium(III), [LiYbCl(4)(C(4)H(8)O)(4)], was prepared by the reaction of YbCl(3)(THF)(3) with LiCl in THF (THF is tetra­hydro­furan). The central motif of the structure is a Yb(μ-Cl)(2)Li ring. The Yb atom is hexa­coordinated to four Cl atoms and two THF mol­ecules oriented in a trans fashion. The Li atom has a tetra­hedral environment and is coordinated to two Cl atoms and two THF mol­ecules. No inter­molecular inter­actions other than van der Waals forces were observed. Two of the THF mol­ecules are disordered over two positions.
format Online
Article
Text
id pubmed-3120567
institution National Center for Biotechnology Information
language English
publishDate 2011
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-31205672011-07-13 LiYbCl(4)(THF)(4) Richtera, Lukas Jancik, Vojtech Hermanova, Sona Krpoun, Karel Thompson-Montero, Kimberly Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, di-μ-chlorido-dichlorido-1κ(2) Cl-tetra­kis­(tetra­hydro­furan)-1κ(2) O,2κ(2) O-lithiumytterbium(III), [LiYbCl(4)(C(4)H(8)O)(4)], was prepared by the reaction of YbCl(3)(THF)(3) with LiCl in THF (THF is tetra­hydro­furan). The central motif of the structure is a Yb(μ-Cl)(2)Li ring. The Yb atom is hexa­coordinated to four Cl atoms and two THF mol­ecules oriented in a trans fashion. The Li atom has a tetra­hedral environment and is coordinated to two Cl atoms and two THF mol­ecules. No inter­molecular inter­actions other than van der Waals forces were observed. Two of the THF mol­ecules are disordered over two positions. International Union of Crystallography 2011-05-07 /pmc/articles/PMC3120567/ /pubmed/21754604 http://dx.doi.org/10.1107/S1600536811014395 Text en © Richtera et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Richtera, Lukas
Jancik, Vojtech
Hermanova, Sona
Krpoun, Karel
Thompson-Montero, Kimberly
LiYbCl(4)(THF)(4)
title LiYbCl(4)(THF)(4)
title_full LiYbCl(4)(THF)(4)
title_fullStr LiYbCl(4)(THF)(4)
title_full_unstemmed LiYbCl(4)(THF)(4)
title_short LiYbCl(4)(THF)(4)
title_sort liybcl(4)(thf)(4)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120567/
https://www.ncbi.nlm.nih.gov/pubmed/21754604
http://dx.doi.org/10.1107/S1600536811014395
work_keys_str_mv AT richteralukas liybcl4thf4
AT jancikvojtech liybcl4thf4
AT hermanovasona liybcl4thf4
AT krpounkarel liybcl4thf4
AT thompsonmonterokimberly liybcl4thf4

Ejemplares similares