Cargando…
Poly[(μ(3)-benzene-1,3,5-tricarboxylato-κ(3) O (1):O (3):O (5))(μ(2)-2-methylimidazolato-κ(2) N:N′)tris(2-methylimidazole-κN)dizinc(II)]
Hydrothermal reaction involving zinc nitrate hexahydrate, trisodium benzene-1,3,5-tricarboxylate (Na(3)BTC) and 2-methylimidazole (2-MeImH) yielded the title compound, [Zn(2)(C(9)H(3)O(6))(C(4)H(5)N(2))(C(4)H(6)N(2))(3)]. In this mixed-ligand metal-organic compound, Zn(2+) ions are coordinated...
Autores principales: | , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120569/ https://www.ncbi.nlm.nih.gov/pubmed/21754580 http://dx.doi.org/10.1107/S1600536811015844 |
Sumario: | Hydrothermal reaction involving zinc nitrate hexahydrate, trisodium benzene-1,3,5-tricarboxylate (Na(3)BTC) and 2-methylimidazole (2-MeImH) yielded the title compound, [Zn(2)(C(9)H(3)O(6))(C(4)H(5)N(2))(C(4)H(6)N(2))(3)]. In this mixed-ligand metal-organic compound, Zn(2+) ions are coordinated by N atoms from 2-MeImH molecules and (2-MeIm)(−) ions, as well as by O atoms from (BTC)(3−) ions. This results in two different distorted tetrahedra, viz. ZnN(3)O and ZnN(2)O(2). These tetrahedra are interconnected via (BTC)(3−) ions and N:N′-bridging (2-MeIm)(−) ions, thus forming a layered structure in the bc plane. Hydrogen bonds between the O atoms of carboxylate ions and NH groups of 2-MeImH ligands link the layers into a three-dimensional structure. |
---|