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Poly[(μ(3)-benzene-1,3,5-tricarboxyl­ato-κ(3) O (1):O (3):O (5))(μ(2)-2-methyl­imidazolato-κ(2) N:N′)tris­(2-methyl­imidazole-κN)dizinc(II)]

Hydro­thermal reaction involving zinc nitrate hexa­hydrate, tris­odium benzene-1,3,5-tricarboxyl­ate (Na(3)BTC) and 2-methyl­imidazole (2-MeImH) yielded the title compound, [Zn(2)(C(9)H(3)O(6))(C(4)H(5)N(2))(C(4)H(6)N(2))(3)]. In this mixed-ligand metal-organic compound, Zn(2+) ions are coordinated...

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Detalles Bibliográficos
Autores principales: Maniam, Palanikumar, Stock, Norbert
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120569/
https://www.ncbi.nlm.nih.gov/pubmed/21754580
http://dx.doi.org/10.1107/S1600536811015844
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author Maniam, Palanikumar
Stock, Norbert
author_facet Maniam, Palanikumar
Stock, Norbert
author_sort Maniam, Palanikumar
collection PubMed
description Hydro­thermal reaction involving zinc nitrate hexa­hydrate, tris­odium benzene-1,3,5-tricarboxyl­ate (Na(3)BTC) and 2-methyl­imidazole (2-MeImH) yielded the title compound, [Zn(2)(C(9)H(3)O(6))(C(4)H(5)N(2))(C(4)H(6)N(2))(3)]. In this mixed-ligand metal-organic compound, Zn(2+) ions are coordinated by N atoms from 2-MeImH mol­ecules and (2-MeIm)(−) ions, as well as by O atoms from (BTC)(3−) ions. This results in two different distorted tetra­hedra, viz. ZnN(3)O and ZnN(2)O(2). These tetra­hedra are inter­connected via (BTC)(3−) ions and N:N′-bridging (2-MeIm)(−) ions, thus forming a layered structure in the bc plane. Hydrogen bonds between the O atoms of carboxyl­ate ions and NH groups of 2-MeImH ligands link the layers into a three-dimensional structure.
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spelling pubmed-31205692011-07-13 Poly[(μ(3)-benzene-1,3,5-tricarboxyl­ato-κ(3) O (1):O (3):O (5))(μ(2)-2-methyl­imidazolato-κ(2) N:N′)tris­(2-methyl­imidazole-κN)dizinc(II)] Maniam, Palanikumar Stock, Norbert Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers Hydro­thermal reaction involving zinc nitrate hexa­hydrate, tris­odium benzene-1,3,5-tricarboxyl­ate (Na(3)BTC) and 2-methyl­imidazole (2-MeImH) yielded the title compound, [Zn(2)(C(9)H(3)O(6))(C(4)H(5)N(2))(C(4)H(6)N(2))(3)]. In this mixed-ligand metal-organic compound, Zn(2+) ions are coordinated by N atoms from 2-MeImH mol­ecules and (2-MeIm)(−) ions, as well as by O atoms from (BTC)(3−) ions. This results in two different distorted tetra­hedra, viz. ZnN(3)O and ZnN(2)O(2). These tetra­hedra are inter­connected via (BTC)(3−) ions and N:N′-bridging (2-MeIm)(−) ions, thus forming a layered structure in the bc plane. Hydrogen bonds between the O atoms of carboxyl­ate ions and NH groups of 2-MeImH ligands link the layers into a three-dimensional structure. International Union of Crystallography 2011-05-07 /pmc/articles/PMC3120569/ /pubmed/21754580 http://dx.doi.org/10.1107/S1600536811015844 Text en © Maniam and Stock 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Maniam, Palanikumar
Stock, Norbert
Poly[(μ(3)-benzene-1,3,5-tricarboxyl­ato-κ(3) O (1):O (3):O (5))(μ(2)-2-methyl­imidazolato-κ(2) N:N′)tris­(2-methyl­imidazole-κN)dizinc(II)]
title Poly[(μ(3)-benzene-1,3,5-tricarboxyl­ato-κ(3) O (1):O (3):O (5))(μ(2)-2-methyl­imidazolato-κ(2) N:N′)tris­(2-methyl­imidazole-κN)dizinc(II)]
title_full Poly[(μ(3)-benzene-1,3,5-tricarboxyl­ato-κ(3) O (1):O (3):O (5))(μ(2)-2-methyl­imidazolato-κ(2) N:N′)tris­(2-methyl­imidazole-κN)dizinc(II)]
title_fullStr Poly[(μ(3)-benzene-1,3,5-tricarboxyl­ato-κ(3) O (1):O (3):O (5))(μ(2)-2-methyl­imidazolato-κ(2) N:N′)tris­(2-methyl­imidazole-κN)dizinc(II)]
title_full_unstemmed Poly[(μ(3)-benzene-1,3,5-tricarboxyl­ato-κ(3) O (1):O (3):O (5))(μ(2)-2-methyl­imidazolato-κ(2) N:N′)tris­(2-methyl­imidazole-κN)dizinc(II)]
title_short Poly[(μ(3)-benzene-1,3,5-tricarboxyl­ato-κ(3) O (1):O (3):O (5))(μ(2)-2-methyl­imidazolato-κ(2) N:N′)tris­(2-methyl­imidazole-κN)dizinc(II)]
title_sort poly[(μ(3)-benzene-1,3,5-tricarboxyl­ato-κ(3) o (1):o (3):o (5))(μ(2)-2-methyl­imidazolato-κ(2) n:n′)tris­(2-methyl­imidazole-κn)dizinc(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120569/
https://www.ncbi.nlm.nih.gov/pubmed/21754580
http://dx.doi.org/10.1107/S1600536811015844
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