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Poly[(μ(3)-benzene-1,3,5-tricarboxylato-κ(3) O (1):O (3):O (5))(μ(2)-2-methylimidazolato-κ(2) N:N′)tris(2-methylimidazole-κN)dizinc(II)]
Hydrothermal reaction involving zinc nitrate hexahydrate, trisodium benzene-1,3,5-tricarboxylate (Na(3)BTC) and 2-methylimidazole (2-MeImH) yielded the title compound, [Zn(2)(C(9)H(3)O(6))(C(4)H(5)N(2))(C(4)H(6)N(2))(3)]. In this mixed-ligand metal-organic compound, Zn(2+) ions are coordinated...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120569/ https://www.ncbi.nlm.nih.gov/pubmed/21754580 http://dx.doi.org/10.1107/S1600536811015844 |
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author | Maniam, Palanikumar Stock, Norbert |
author_facet | Maniam, Palanikumar Stock, Norbert |
author_sort | Maniam, Palanikumar |
collection | PubMed |
description | Hydrothermal reaction involving zinc nitrate hexahydrate, trisodium benzene-1,3,5-tricarboxylate (Na(3)BTC) and 2-methylimidazole (2-MeImH) yielded the title compound, [Zn(2)(C(9)H(3)O(6))(C(4)H(5)N(2))(C(4)H(6)N(2))(3)]. In this mixed-ligand metal-organic compound, Zn(2+) ions are coordinated by N atoms from 2-MeImH molecules and (2-MeIm)(−) ions, as well as by O atoms from (BTC)(3−) ions. This results in two different distorted tetrahedra, viz. ZnN(3)O and ZnN(2)O(2). These tetrahedra are interconnected via (BTC)(3−) ions and N:N′-bridging (2-MeIm)(−) ions, thus forming a layered structure in the bc plane. Hydrogen bonds between the O atoms of carboxylate ions and NH groups of 2-MeImH ligands link the layers into a three-dimensional structure. |
format | Online Article Text |
id | pubmed-3120569 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-31205692011-07-13 Poly[(μ(3)-benzene-1,3,5-tricarboxylato-κ(3) O (1):O (3):O (5))(μ(2)-2-methylimidazolato-κ(2) N:N′)tris(2-methylimidazole-κN)dizinc(II)] Maniam, Palanikumar Stock, Norbert Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers Hydrothermal reaction involving zinc nitrate hexahydrate, trisodium benzene-1,3,5-tricarboxylate (Na(3)BTC) and 2-methylimidazole (2-MeImH) yielded the title compound, [Zn(2)(C(9)H(3)O(6))(C(4)H(5)N(2))(C(4)H(6)N(2))(3)]. In this mixed-ligand metal-organic compound, Zn(2+) ions are coordinated by N atoms from 2-MeImH molecules and (2-MeIm)(−) ions, as well as by O atoms from (BTC)(3−) ions. This results in two different distorted tetrahedra, viz. ZnN(3)O and ZnN(2)O(2). These tetrahedra are interconnected via (BTC)(3−) ions and N:N′-bridging (2-MeIm)(−) ions, thus forming a layered structure in the bc plane. Hydrogen bonds between the O atoms of carboxylate ions and NH groups of 2-MeImH ligands link the layers into a three-dimensional structure. International Union of Crystallography 2011-05-07 /pmc/articles/PMC3120569/ /pubmed/21754580 http://dx.doi.org/10.1107/S1600536811015844 Text en © Maniam and Stock 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Maniam, Palanikumar Stock, Norbert Poly[(μ(3)-benzene-1,3,5-tricarboxylato-κ(3) O (1):O (3):O (5))(μ(2)-2-methylimidazolato-κ(2) N:N′)tris(2-methylimidazole-κN)dizinc(II)] |
title | Poly[(μ(3)-benzene-1,3,5-tricarboxylato-κ(3)
O
(1):O
(3):O
(5))(μ(2)-2-methylimidazolato-κ(2)
N:N′)tris(2-methylimidazole-κN)dizinc(II)] |
title_full | Poly[(μ(3)-benzene-1,3,5-tricarboxylato-κ(3)
O
(1):O
(3):O
(5))(μ(2)-2-methylimidazolato-κ(2)
N:N′)tris(2-methylimidazole-κN)dizinc(II)] |
title_fullStr | Poly[(μ(3)-benzene-1,3,5-tricarboxylato-κ(3)
O
(1):O
(3):O
(5))(μ(2)-2-methylimidazolato-κ(2)
N:N′)tris(2-methylimidazole-κN)dizinc(II)] |
title_full_unstemmed | Poly[(μ(3)-benzene-1,3,5-tricarboxylato-κ(3)
O
(1):O
(3):O
(5))(μ(2)-2-methylimidazolato-κ(2)
N:N′)tris(2-methylimidazole-κN)dizinc(II)] |
title_short | Poly[(μ(3)-benzene-1,3,5-tricarboxylato-κ(3)
O
(1):O
(3):O
(5))(μ(2)-2-methylimidazolato-κ(2)
N:N′)tris(2-methylimidazole-κN)dizinc(II)] |
title_sort | poly[(μ(3)-benzene-1,3,5-tricarboxylato-κ(3)
o
(1):o
(3):o
(5))(μ(2)-2-methylimidazolato-κ(2)
n:n′)tris(2-methylimidazole-κn)dizinc(ii)] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120569/ https://www.ncbi.nlm.nih.gov/pubmed/21754580 http://dx.doi.org/10.1107/S1600536811015844 |
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