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(1S,3S)-Methyl 6,7-dimethoxy-1-phenyl-1,2,3,4-tetrahydroisoquinoline-3-carboxylate
In the title compound, C(19)H(21)NO(4), an organocatalyst with a tetrahydroisoquinoline backbone, the heterocyclic ring assumes a half-boat conformation. The dihedral angle between the aromatic rings is 82.93 (8)°. In the crystal, molecules are linked via N—H⋯O and C—H⋯O hydrogen bonds, forming a...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120575/ https://www.ncbi.nlm.nih.gov/pubmed/21754868 http://dx.doi.org/10.1107/S1600536811018782 |
| _version_ | 1782206710090301440 |
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| author | Naicker, Tricia Govender, Thavendran Kruger, Hendrik G. Maguire, Glenn E. M. |
| author_facet | Naicker, Tricia Govender, Thavendran Kruger, Hendrik G. Maguire, Glenn E. M. |
| author_sort | Naicker, Tricia |
| collection | PubMed |
| description | In the title compound, C(19)H(21)NO(4), an organocatalyst with a tetrahydroisoquinoline backbone, the heterocyclic ring assumes a half-boat conformation. The dihedral angle between the aromatic rings is 82.93 (8)°. In the crystal, molecules are linked via N—H⋯O and C—H⋯O hydrogen bonds, forming a layer parallel to (10[Image: see text]). |
| format | Online Article Text |
| id | pubmed-3120575 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-31205752011-07-13 (1S,3S)-Methyl 6,7-dimethoxy-1-phenyl-1,2,3,4-tetrahydroisoquinoline-3-carboxylate Naicker, Tricia Govender, Thavendran Kruger, Hendrik G. Maguire, Glenn E. M. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(19)H(21)NO(4), an organocatalyst with a tetrahydroisoquinoline backbone, the heterocyclic ring assumes a half-boat conformation. The dihedral angle between the aromatic rings is 82.93 (8)°. In the crystal, molecules are linked via N—H⋯O and C—H⋯O hydrogen bonds, forming a layer parallel to (10[Image: see text]). International Union of Crystallography 2011-05-25 /pmc/articles/PMC3120575/ /pubmed/21754868 http://dx.doi.org/10.1107/S1600536811018782 Text en © Naicker et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Organic Papers Naicker, Tricia Govender, Thavendran Kruger, Hendrik G. Maguire, Glenn E. M. (1S,3S)-Methyl 6,7-dimethoxy-1-phenyl-1,2,3,4-tetrahydroisoquinoline-3-carboxylate |
| title | (1S,3S)-Methyl 6,7-dimethoxy-1-phenyl-1,2,3,4-tetrahydroisoquinoline-3-carboxylate |
| title_full | (1S,3S)-Methyl 6,7-dimethoxy-1-phenyl-1,2,3,4-tetrahydroisoquinoline-3-carboxylate |
| title_fullStr | (1S,3S)-Methyl 6,7-dimethoxy-1-phenyl-1,2,3,4-tetrahydroisoquinoline-3-carboxylate |
| title_full_unstemmed | (1S,3S)-Methyl 6,7-dimethoxy-1-phenyl-1,2,3,4-tetrahydroisoquinoline-3-carboxylate |
| title_short | (1S,3S)-Methyl 6,7-dimethoxy-1-phenyl-1,2,3,4-tetrahydroisoquinoline-3-carboxylate |
| title_sort | (1s,3s)-methyl 6,7-dimethoxy-1-phenyl-1,2,3,4-tetrahydroisoquinoline-3-carboxylate |
| topic | Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120575/ https://www.ncbi.nlm.nih.gov/pubmed/21754868 http://dx.doi.org/10.1107/S1600536811018782 |
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