Cargando…
catena-Poly[[tribenzyltin(IV)]-μ-4-formyl-2-methoxy-6-nitrophenolato-κ(2) O (1):O (4)]
The formylmethoxynitrophenoxide ions in the polymeric title compound, [Sn(C(7)H(7))(3)(C(8)H(6)NO(5))](n), link adjacent triorganotin(IV) cations into linear chains lying close to (101) [Sn—O = 2.1227 (12) Å and Sn← O = 2.4936 (13) Å]. The Sn(IV) atom is displaced out of the C(3)Sn girdle of the...
| Autores principales: | , , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120579/ https://www.ncbi.nlm.nih.gov/pubmed/21754610 http://dx.doi.org/10.1107/S1600536811016436 |
| _version_ | 1782206711001513984 |
|---|---|
| author | Keng, Thy Chun Lo, Kong Mun Ng, Seik Weng |
| author_facet | Keng, Thy Chun Lo, Kong Mun Ng, Seik Weng |
| author_sort | Keng, Thy Chun |
| collection | PubMed |
| description | The formylmethoxynitrophenoxide ions in the polymeric title compound, [Sn(C(7)H(7))(3)(C(8)H(6)NO(5))](n), link adjacent triorganotin(IV) cations into linear chains lying close to (101) [Sn—O = 2.1227 (12) Å and Sn← O = 2.4936 (13) Å]. The Sn(IV) atom is displaced out of the C(3)Sn girdle of the trans-C(3)SnO(2) trigonal-bipyramidal polyhedron in the direction of the covalently-bonded O atom [Sn—O—C = 137.63 (11)°] by 0.247 (1) Å; the geometry is distorted towards an octahedron by a remote O atom of the methoxy subsituent [Sn⋯O = 3.019 (1) Å] |
| format | Online Article Text |
| id | pubmed-3120579 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-31205792011-07-13 catena-Poly[[tribenzyltin(IV)]-μ-4-formyl-2-methoxy-6-nitrophenolato-κ(2) O (1):O (4)] Keng, Thy Chun Lo, Kong Mun Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The formylmethoxynitrophenoxide ions in the polymeric title compound, [Sn(C(7)H(7))(3)(C(8)H(6)NO(5))](n), link adjacent triorganotin(IV) cations into linear chains lying close to (101) [Sn—O = 2.1227 (12) Å and Sn← O = 2.4936 (13) Å]. The Sn(IV) atom is displaced out of the C(3)Sn girdle of the trans-C(3)SnO(2) trigonal-bipyramidal polyhedron in the direction of the covalently-bonded O atom [Sn—O—C = 137.63 (11)°] by 0.247 (1) Å; the geometry is distorted towards an octahedron by a remote O atom of the methoxy subsituent [Sn⋯O = 3.019 (1) Å] International Union of Crystallography 2011-05-07 /pmc/articles/PMC3120579/ /pubmed/21754610 http://dx.doi.org/10.1107/S1600536811016436 Text en © Keng et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Keng, Thy Chun Lo, Kong Mun Ng, Seik Weng catena-Poly[[tribenzyltin(IV)]-μ-4-formyl-2-methoxy-6-nitrophenolato-κ(2) O (1):O (4)] |
| title |
catena-Poly[[tribenzyltin(IV)]-μ-4-formyl-2-methoxy-6-nitrophenolato-κ(2)
O
(1):O
(4)] |
| title_full |
catena-Poly[[tribenzyltin(IV)]-μ-4-formyl-2-methoxy-6-nitrophenolato-κ(2)
O
(1):O
(4)] |
| title_fullStr |
catena-Poly[[tribenzyltin(IV)]-μ-4-formyl-2-methoxy-6-nitrophenolato-κ(2)
O
(1):O
(4)] |
| title_full_unstemmed |
catena-Poly[[tribenzyltin(IV)]-μ-4-formyl-2-methoxy-6-nitrophenolato-κ(2)
O
(1):O
(4)] |
| title_short |
catena-Poly[[tribenzyltin(IV)]-μ-4-formyl-2-methoxy-6-nitrophenolato-κ(2)
O
(1):O
(4)] |
| title_sort | catena-poly[[tribenzyltin(iv)]-μ-4-formyl-2-methoxy-6-nitrophenolato-κ(2)
o
(1):o
(4)] |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120579/ https://www.ncbi.nlm.nih.gov/pubmed/21754610 http://dx.doi.org/10.1107/S1600536811016436 |
| work_keys_str_mv | AT kengthychun catenapolytribenzyltinivm4formyl2methoxy6nitrophenolatok2o1o4 AT lokongmun catenapolytribenzyltinivm4formyl2methoxy6nitrophenolatok2o1o4 AT ngseikweng catenapolytribenzyltinivm4formyl2methoxy6nitrophenolatok2o1o4 |