Cargando…
Bis(nitrato-κO)(3-oxapentane-1,5-diamine-κ(3) N,O,N′)zinc(II)
In the title compound, [Zn(NO(3))(2)(C(4)H(12)N(2)O)], the Zn(II) atom is N,O,N′-chelated by a 3-oxapentane-1,5-diamine ligand and is further coordinated by two nitrate anions in a distorted trigonal–bipyramidal geometry. Intermolecular N—H⋯O hydrogen bonding is present in the crystal structure. A...
Autores principales: | , , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120581/ https://www.ncbi.nlm.nih.gov/pubmed/21754650 http://dx.doi.org/10.1107/S1600536811018010 |
_version_ | 1782206711453450240 |
---|---|
author | Jia, Fei Kou, Fan Liu, Bin Jia, Bei-Bei Wu, Hui-Lu |
author_facet | Jia, Fei Kou, Fan Liu, Bin Jia, Bei-Bei Wu, Hui-Lu |
author_sort | Jia, Fei |
collection | PubMed |
description | In the title compound, [Zn(NO(3))(2)(C(4)H(12)N(2)O)], the Zn(II) atom is N,O,N′-chelated by a 3-oxapentane-1,5-diamine ligand and is further coordinated by two nitrate anions in a distorted trigonal–bipyramidal geometry. Intermolecular N—H⋯O hydrogen bonding is present in the crystal structure. A short O⋯O contact of 2.816 (8) Å is observed between the nitrate anions of adjacent molecules. |
format | Online Article Text |
id | pubmed-3120581 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-31205812011-07-13 Bis(nitrato-κO)(3-oxapentane-1,5-diamine-κ(3) N,O,N′)zinc(II) Jia, Fei Kou, Fan Liu, Bin Jia, Bei-Bei Wu, Hui-Lu Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Zn(NO(3))(2)(C(4)H(12)N(2)O)], the Zn(II) atom is N,O,N′-chelated by a 3-oxapentane-1,5-diamine ligand and is further coordinated by two nitrate anions in a distorted trigonal–bipyramidal geometry. Intermolecular N—H⋯O hydrogen bonding is present in the crystal structure. A short O⋯O contact of 2.816 (8) Å is observed between the nitrate anions of adjacent molecules. International Union of Crystallography 2011-05-20 /pmc/articles/PMC3120581/ /pubmed/21754650 http://dx.doi.org/10.1107/S1600536811018010 Text en © Jia et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Jia, Fei Kou, Fan Liu, Bin Jia, Bei-Bei Wu, Hui-Lu Bis(nitrato-κO)(3-oxapentane-1,5-diamine-κ(3) N,O,N′)zinc(II) |
title | Bis(nitrato-κO)(3-oxapentane-1,5-diamine-κ(3)
N,O,N′)zinc(II) |
title_full | Bis(nitrato-κO)(3-oxapentane-1,5-diamine-κ(3)
N,O,N′)zinc(II) |
title_fullStr | Bis(nitrato-κO)(3-oxapentane-1,5-diamine-κ(3)
N,O,N′)zinc(II) |
title_full_unstemmed | Bis(nitrato-κO)(3-oxapentane-1,5-diamine-κ(3)
N,O,N′)zinc(II) |
title_short | Bis(nitrato-κO)(3-oxapentane-1,5-diamine-κ(3)
N,O,N′)zinc(II) |
title_sort | bis(nitrato-κo)(3-oxapentane-1,5-diamine-κ(3)
n,o,n′)zinc(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120581/ https://www.ncbi.nlm.nih.gov/pubmed/21754650 http://dx.doi.org/10.1107/S1600536811018010 |
work_keys_str_mv | AT jiafei bisnitratoko3oxapentane15diaminek3nonzincii AT koufan bisnitratoko3oxapentane15diaminek3nonzincii AT liubin bisnitratoko3oxapentane15diaminek3nonzincii AT jiabeibei bisnitratoko3oxapentane15diaminek3nonzincii AT wuhuilu bisnitratoko3oxapentane15diaminek3nonzincii |