Cargando…

Bis(nitrato-κO)(3-oxapentane-1,5-diamine-κ(3) N,O,N′)zinc(II)

In the title compound, [Zn(NO(3))(2)(C(4)H(12)N(2)O)], the Zn(II) atom is N,O,N′-chelated by a 3-oxapentane-1,5-diamine ligand and is further coordinated by two nitrate anions in a distorted trigonal–bipyramidal geometry. Inter­molecular N—H⋯O hydrogen bonding is present in the crystal structure. A...

Descripción completa

Detalles Bibliográficos
Autores principales: Jia, Fei, Kou, Fan, Liu, Bin, Jia, Bei-Bei, Wu, Hui-Lu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120581/
https://www.ncbi.nlm.nih.gov/pubmed/21754650
http://dx.doi.org/10.1107/S1600536811018010
_version_ 1782206711453450240
author Jia, Fei
Kou, Fan
Liu, Bin
Jia, Bei-Bei
Wu, Hui-Lu
author_facet Jia, Fei
Kou, Fan
Liu, Bin
Jia, Bei-Bei
Wu, Hui-Lu
author_sort Jia, Fei
collection PubMed
description In the title compound, [Zn(NO(3))(2)(C(4)H(12)N(2)O)], the Zn(II) atom is N,O,N′-chelated by a 3-oxapentane-1,5-diamine ligand and is further coordinated by two nitrate anions in a distorted trigonal–bipyramidal geometry. Inter­molecular N—H⋯O hydrogen bonding is present in the crystal structure. A short O⋯O contact of 2.816 (8) Å is observed between the nitrate anions of adjacent mol­ecules.
format Online
Article
Text
id pubmed-3120581
institution National Center for Biotechnology Information
language English
publishDate 2011
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-31205812011-07-13 Bis(nitrato-κO)(3-oxapentane-1,5-diamine-κ(3) N,O,N′)zinc(II) Jia, Fei Kou, Fan Liu, Bin Jia, Bei-Bei Wu, Hui-Lu Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Zn(NO(3))(2)(C(4)H(12)N(2)O)], the Zn(II) atom is N,O,N′-chelated by a 3-oxapentane-1,5-diamine ligand and is further coordinated by two nitrate anions in a distorted trigonal–bipyramidal geometry. Inter­molecular N—H⋯O hydrogen bonding is present in the crystal structure. A short O⋯O contact of 2.816 (8) Å is observed between the nitrate anions of adjacent mol­ecules. International Union of Crystallography 2011-05-20 /pmc/articles/PMC3120581/ /pubmed/21754650 http://dx.doi.org/10.1107/S1600536811018010 Text en © Jia et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Jia, Fei
Kou, Fan
Liu, Bin
Jia, Bei-Bei
Wu, Hui-Lu
Bis(nitrato-κO)(3-oxapentane-1,5-diamine-κ(3) N,O,N′)zinc(II)
title Bis(nitrato-κO)(3-oxapentane-1,5-diamine-κ(3) N,O,N′)zinc(II)
title_full Bis(nitrato-κO)(3-oxapentane-1,5-diamine-κ(3) N,O,N′)zinc(II)
title_fullStr Bis(nitrato-κO)(3-oxapentane-1,5-diamine-κ(3) N,O,N′)zinc(II)
title_full_unstemmed Bis(nitrato-κO)(3-oxapentane-1,5-diamine-κ(3) N,O,N′)zinc(II)
title_short Bis(nitrato-κO)(3-oxapentane-1,5-diamine-κ(3) N,O,N′)zinc(II)
title_sort bis(nitrato-κo)(3-oxapentane-1,5-diamine-κ(3) n,o,n′)zinc(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120581/
https://www.ncbi.nlm.nih.gov/pubmed/21754650
http://dx.doi.org/10.1107/S1600536811018010
work_keys_str_mv AT jiafei bisnitratoko3oxapentane15diaminek3nonzincii
AT koufan bisnitratoko3oxapentane15diaminek3nonzincii
AT liubin bisnitratoko3oxapentane15diaminek3nonzincii
AT jiabeibei bisnitratoko3oxapentane15diaminek3nonzincii
AT wuhuilu bisnitratoko3oxapentane15diaminek3nonzincii