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(μ-2,3-Dibromosuccinato-κ(2) O (1):O (4))bis[methanolato-κO)triphenylantimony(V)]
In the title molecule, [Sb(2)(C(6)H(5))(6)(C(4)H(4)Br(2)O(4))(CH(3)O)(2)], two [Sb(CH(3)O)Ph(3)](+) units are linked by the two carboxylate O atoms of a meso-2,3-dibromosuccinate bridging ligand, forming a dinuclear compound. The Sb(IV) atom is five-coordinated in a slightly distorted trigonal–bi...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120583/ https://www.ncbi.nlm.nih.gov/pubmed/21754613 http://dx.doi.org/10.1107/S1600536811016114 |
Sumario: | In the title molecule, [Sb(2)(C(6)H(5))(6)(C(4)H(4)Br(2)O(4))(CH(3)O)(2)], two [Sb(CH(3)O)Ph(3)](+) units are linked by the two carboxylate O atoms of a meso-2,3-dibromosuccinate bridging ligand, forming a dinuclear compound. The Sb(IV) atom is five-coordinated in a slightly distorted trigonal–bipyramid geometry by phenyl C atoms in the equatorial positions and two O atoms in the axial positions. C—H⋯O interactions link the molecules into a two-dimensional network parallel to (010). The —CH— group of the centrosymmetric 2,3-dibromosuccinate anion is disordered over two sites in a 0.6:0.4 ratio. |
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