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(μ-2,3-Dibromo­succinato-κ(2) O (1):O (4))bis­[methano­lato-κO)triphenyl­anti­mony(V)]

In the title mol­ecule, [Sb(2)(C(6)H(5))(6)(C(4)H(4)Br(2)O(4))(CH(3)O)(2)], two [Sb(CH(3)O)Ph(3)](+) units are linked by the two carboxyl­ate O atoms of a meso-2,3-dibromo­succinate bridging ligand, forming a dinuclear compound. The Sb(IV) atom is five-coordinated in a slightly distorted trigonal–bi...

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Detalles Bibliográficos
Autores principales: Quan, Li, Yin, Handong, Fu, Wenfu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120583/
https://www.ncbi.nlm.nih.gov/pubmed/21754613
http://dx.doi.org/10.1107/S1600536811016114
Descripción
Sumario:In the title mol­ecule, [Sb(2)(C(6)H(5))(6)(C(4)H(4)Br(2)O(4))(CH(3)O)(2)], two [Sb(CH(3)O)Ph(3)](+) units are linked by the two carboxyl­ate O atoms of a meso-2,3-dibromo­succinate bridging ligand, forming a dinuclear compound. The Sb(IV) atom is five-coordinated in a slightly distorted trigonal–bipyramid geometry by phenyl C atoms in the equatorial positions and two O atoms in the axial positions. C—H⋯O inter­actions link the mol­ecules into a two-dimensional network parallel to (010). The —CH— group of the centrosymmetric 2,3-dibromosuccinate anion is disordered over two sites in a 0.6:0.4 ratio.