catena-Poly[[tribenzyl­tin(IV)]-μ-(E)-3-phenyl­prop-2-enoato-κ(2) O:O′]

The Sn(IV) atom in the title carboxyl­ate-bridged polymer, [Sn(C(7)H(7))(3)(C(9)H(7)O(2))](n), exists in a trans-C(3)SnO(2) trigonal–bipyramidal geometry (average covalent Sn—O = 2.167 Å, average dative Sn—O = 2.361 Å and average O—Sn—O = 169.6°). The polymer propagates as a helical chain along the...

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Detalles Bibliográficos
Autores principales: Lo, Kong Mun, Ng, Seik Weng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120586/
https://www.ncbi.nlm.nih.gov/pubmed/21754636
http://dx.doi.org/10.1107/S1600536811017247
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author Lo, Kong Mun
Ng, Seik Weng
author_facet Lo, Kong Mun
Ng, Seik Weng
author_sort Lo, Kong Mun
collection PubMed
description The Sn(IV) atom in the title carboxyl­ate-bridged polymer, [Sn(C(7)H(7))(3)(C(9)H(7)O(2))](n), exists in a trans-C(3)SnO(2) trigonal–bipyramidal geometry (average covalent Sn—O = 2.167 Å, average dative Sn—O = 2.361 Å and average O—Sn—O = 169.6°). The polymer propagates as a helical chain along the b axis with a repeat distance that is half the b-axial length. There are four independent formula units in the asymmetric unit; two are disposed about a false center of inversion with respect to the other two so that the space group emulates a centric space group.
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spelling pubmed-31205862011-07-13 catena-Poly[[tribenzyl­tin(IV)]-μ-(E)-3-phenyl­prop-2-enoato-κ(2) O:O′] Lo, Kong Mun Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Sn(IV) atom in the title carboxyl­ate-bridged polymer, [Sn(C(7)H(7))(3)(C(9)H(7)O(2))](n), exists in a trans-C(3)SnO(2) trigonal–bipyramidal geometry (average covalent Sn—O = 2.167 Å, average dative Sn—O = 2.361 Å and average O—Sn—O = 169.6°). The polymer propagates as a helical chain along the b axis with a repeat distance that is half the b-axial length. There are four independent formula units in the asymmetric unit; two are disposed about a false center of inversion with respect to the other two so that the space group emulates a centric space group. International Union of Crystallography 2011-05-14 /pmc/articles/PMC3120586/ /pubmed/21754636 http://dx.doi.org/10.1107/S1600536811017247 Text en © Lo and Ng 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Lo, Kong Mun
Ng, Seik Weng
catena-Poly[[tribenzyl­tin(IV)]-μ-(E)-3-phenyl­prop-2-enoato-κ(2) O:O′]
title catena-Poly[[tribenzyl­tin(IV)]-μ-(E)-3-phenyl­prop-2-enoato-κ(2) O:O′]
title_full catena-Poly[[tribenzyl­tin(IV)]-μ-(E)-3-phenyl­prop-2-enoato-κ(2) O:O′]
title_fullStr catena-Poly[[tribenzyl­tin(IV)]-μ-(E)-3-phenyl­prop-2-enoato-κ(2) O:O′]
title_full_unstemmed catena-Poly[[tribenzyl­tin(IV)]-μ-(E)-3-phenyl­prop-2-enoato-κ(2) O:O′]
title_short catena-Poly[[tribenzyl­tin(IV)]-μ-(E)-3-phenyl­prop-2-enoato-κ(2) O:O′]
title_sort catena-poly[[tribenzyl­tin(iv)]-μ-(e)-3-phenyl­prop-2-enoato-κ(2) o:o′]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120586/
https://www.ncbi.nlm.nih.gov/pubmed/21754636
http://dx.doi.org/10.1107/S1600536811017247
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