5-Chloro-2-hy­droxy­benzaldehyde 4-ethyl­thio­semicarbazone

In the title compound, C(10)H(12)ClN(3)OS, the –C=N–N–C– chain bridging the ethyl­imino group and the benzene ring adopts an extended conformation with a C—N—N—C torsion angle of −171.98 (11)°. The imino H atom of the chain is a hydrogen-bond donor to the S atom of an inversion-related mol­ecule, fo...

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Detalles Bibliográficos
Autores principales: Lo, Kong Mun, Ng, Seik Weng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120593/
https://www.ncbi.nlm.nih.gov/pubmed/21754827
http://dx.doi.org/10.1107/S160053681101796X
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author Lo, Kong Mun
Ng, Seik Weng
author_facet Lo, Kong Mun
Ng, Seik Weng
author_sort Lo, Kong Mun
collection PubMed
description In the title compound, C(10)H(12)ClN(3)OS, the –C=N–N–C– chain bridging the ethyl­imino group and the benzene ring adopts an extended conformation with a C—N—N—C torsion angle of −171.98 (11)°. The imino H atom of the chain is a hydrogen-bond donor to the S atom of an inversion-related mol­ecule, forming a supra­molecular dimer. The hy­droxy H atom is intra­molecularly hydrogen bonded to the azomethine N atom.
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spelling pubmed-31205932011-07-13 5-Chloro-2-hy­droxy­benzaldehyde 4-ethyl­thio­semicarbazone Lo, Kong Mun Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(10)H(12)ClN(3)OS, the –C=N–N–C– chain bridging the ethyl­imino group and the benzene ring adopts an extended conformation with a C—N—N—C torsion angle of −171.98 (11)°. The imino H atom of the chain is a hydrogen-bond donor to the S atom of an inversion-related mol­ecule, forming a supra­molecular dimer. The hy­droxy H atom is intra­molecularly hydrogen bonded to the azomethine N atom. International Union of Crystallography 2011-05-20 /pmc/articles/PMC3120593/ /pubmed/21754827 http://dx.doi.org/10.1107/S160053681101796X Text en © Lo and Ng 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Lo, Kong Mun
Ng, Seik Weng
5-Chloro-2-hy­droxy­benzaldehyde 4-ethyl­thio­semicarbazone
title 5-Chloro-2-hy­droxy­benzaldehyde 4-ethyl­thio­semicarbazone
title_full 5-Chloro-2-hy­droxy­benzaldehyde 4-ethyl­thio­semicarbazone
title_fullStr 5-Chloro-2-hy­droxy­benzaldehyde 4-ethyl­thio­semicarbazone
title_full_unstemmed 5-Chloro-2-hy­droxy­benzaldehyde 4-ethyl­thio­semicarbazone
title_short 5-Chloro-2-hy­droxy­benzaldehyde 4-ethyl­thio­semicarbazone
title_sort 5-chloro-2-hy­droxy­benzaldehyde 4-ethyl­thio­semicarbazone
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120593/
https://www.ncbi.nlm.nih.gov/pubmed/21754827
http://dx.doi.org/10.1107/S160053681101796X
work_keys_str_mv AT lokongmun 5chloro2hydroxybenzaldehyde4ethylthiosemicarbazone
AT ngseikweng 5chloro2hydroxybenzaldehyde4ethylthiosemicarbazone

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