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Bis{2-[4-(methylsulfanyl)phenyl]-1H-benzimidazol-3-ium} tetrabromidocadmate(II) ethanol monosolvate
In the anion of the title compound, (C(14)H(13)N(2)S)(2)[CdBr(4)]·C(2)H(5)OH, the Cd(II) atom is in a distorted tetrahedral environment and one of the Br atoms is disordered over three sites with site-occupancy factors of 0.828 (5), 0.106 (3) and 0.068 (4). In the crystal, intermolecular N—H⋯O, C—...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120599/ https://www.ncbi.nlm.nih.gov/pubmed/21754655 http://dx.doi.org/10.1107/S1600536811018058 |
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author | Manjunatha, M. N. Ziaulla, Mohamed Begum, Noor Shahina Nagasundara, K. R. |
author_facet | Manjunatha, M. N. Ziaulla, Mohamed Begum, Noor Shahina Nagasundara, K. R. |
author_sort | Manjunatha, M. N. |
collection | PubMed |
description | In the anion of the title compound, (C(14)H(13)N(2)S)(2)[CdBr(4)]·C(2)H(5)OH, the Cd(II) atom is in a distorted tetrahedral environment and one of the Br atoms is disordered over three sites with site-occupancy factors of 0.828 (5), 0.106 (3) and 0.068 (4). In the crystal, intermolecular N—H⋯O, C—H⋯O and N—H⋯Br interactions result in a two-dimensional polymeric network extending parallel to (010). |
format | Online Article Text |
id | pubmed-3120599 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-31205992011-07-13 Bis{2-[4-(methylsulfanyl)phenyl]-1H-benzimidazol-3-ium} tetrabromidocadmate(II) ethanol monosolvate Manjunatha, M. N. Ziaulla, Mohamed Begum, Noor Shahina Nagasundara, K. R. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the anion of the title compound, (C(14)H(13)N(2)S)(2)[CdBr(4)]·C(2)H(5)OH, the Cd(II) atom is in a distorted tetrahedral environment and one of the Br atoms is disordered over three sites with site-occupancy factors of 0.828 (5), 0.106 (3) and 0.068 (4). In the crystal, intermolecular N—H⋯O, C—H⋯O and N—H⋯Br interactions result in a two-dimensional polymeric network extending parallel to (010). International Union of Crystallography 2011-05-20 /pmc/articles/PMC3120599/ /pubmed/21754655 http://dx.doi.org/10.1107/S1600536811018058 Text en © Manjunatha et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Manjunatha, M. N. Ziaulla, Mohamed Begum, Noor Shahina Nagasundara, K. R. Bis{2-[4-(methylsulfanyl)phenyl]-1H-benzimidazol-3-ium} tetrabromidocadmate(II) ethanol monosolvate |
title | Bis{2-[4-(methylsulfanyl)phenyl]-1H-benzimidazol-3-ium} tetrabromidocadmate(II) ethanol monosolvate |
title_full | Bis{2-[4-(methylsulfanyl)phenyl]-1H-benzimidazol-3-ium} tetrabromidocadmate(II) ethanol monosolvate |
title_fullStr | Bis{2-[4-(methylsulfanyl)phenyl]-1H-benzimidazol-3-ium} tetrabromidocadmate(II) ethanol monosolvate |
title_full_unstemmed | Bis{2-[4-(methylsulfanyl)phenyl]-1H-benzimidazol-3-ium} tetrabromidocadmate(II) ethanol monosolvate |
title_short | Bis{2-[4-(methylsulfanyl)phenyl]-1H-benzimidazol-3-ium} tetrabromidocadmate(II) ethanol monosolvate |
title_sort | bis{2-[4-(methylsulfanyl)phenyl]-1h-benzimidazol-3-ium} tetrabromidocadmate(ii) ethanol monosolvate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3120599/ https://www.ncbi.nlm.nih.gov/pubmed/21754655 http://dx.doi.org/10.1107/S1600536811018058 |
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